Citation: Fu-Hua Qin, Xun-Jie Huang, Yi Liu, Hongze Liang, Qiang Li, Zhong Cao, Wen-Ting Wei, Wei-Min He. Alcohols controlled selective radical cyclization of 1, 6-dienes under mild conditions[J]. Chinese Chemical Letters, ;2020, 31(12): 3267-3270. doi: 10.1016/j.cclet.2020.04.042 shu

Alcohols controlled selective radical cyclization of 1, 6-dienes under mild conditions

    * Corresponding authors.
    E-mail addresses: weiwenting@nbu.edu.cn (W.T. Wei) weiminhe2016@yeah.net (W.M. He).
  • Received Date: 27 March 2020
    Revised Date: 20 April 2020
    Accepted Date: 20 April 2020
    Available Online: 15 December 2020

Figures(6)

  • An efficient procedure for the selective preparation of hydroxy-, carbonyl- and acetal-containing 2-pyrrolidinones has been developed through radical cyclization of 1, 6-dienes initiated by α-C(sp3)-H functionalization of alcohols. This protocol could be conducted at catalyst-free conditions at relatively low temperature (80 ℃) by employing commercially available tert-butyl peroxybenzoate (TBPB) as the oxidant.
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