Citation: Fu-Hua Qin, Xun-Jie Huang, Yi Liu, Hongze Liang, Qiang Li, Zhong Cao, Wen-Ting Wei, Wei-Min He. Alcohols controlled selective radical cyclization of 1, 6-dienes under mild conditions[J]. Chinese Chemical Letters, ;2020, 31(12): 3267-3270. doi: 10.1016/j.cclet.2020.04.042 shu

Alcohols controlled selective radical cyclization of 1, 6-dienes under mild conditions

Fu-Hua Qin ^a ,
Xun-Jie Huang ^a ,
Yi Liu ^a ,
Hongze Liang ^a ,
Qiang Li ^b ,
Zhong Cao ^c ,
Wen-Ting Wei ^{a, *,} ,
Wei-Min He ^{c, *,}

a.
State Key Laboratory Base of Novel Functional Materials and Preparation Science, School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
b.
Institution of Functional Organic Molecules and Materials, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China
c.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China

weiwenting@nbu.edu.cn

weiminhe2016@yeah.net

Received Date: 27 March 2020
Revised Date: 20 April 2020
Accepted Date: 20 April 2020
Available Online: 15 December 2020

Figures(6)

An efficient procedure for the selective preparation of hydroxy-, carbonyl- and acetal-containing 2-pyrrolidinones has been developed through radical cyclization of 1, 6-dienes initiated by α-C(sp³)-H functionalization of alcohols. This protocol could be conducted at catalyst-free conditions at relatively low temperature (80 ℃) by employing commercially available tert-butyl peroxybenzoate (TBPB) as the oxidant.
- Green chemistry,
- Metal free,
- Cyclization,
- Alcohol,
- Pyrrolidinone
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