Citation: Jiang Shifang, Huang Shuo, Yao Minjie, Zhu Jiacai, Liu Lili, Niu Zhiqiang. Bimetal-organic frameworks derived Co/N-doped carbons for lithium-sulfur batteries[J]. Chinese Chemical Letters, ;2020, 31(9): 2347-2352. doi: 10.1016/j.cclet.2020.04.014 shu

Bimetal-organic frameworks derived Co/N-doped carbons for lithium-sulfur batteries

Jiang Shifang ^a ,
Huang Shuo ^a ,
Yao Minjie ^a ,
Zhu Jiacai ^a ,
Liu Lili ^b,*, ,
Niu Zhiqiang ^a,*,

a.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin 300071, China
b.
Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

lililiuhappy@163.com

zqniu@nankai.edu.cn

Received Date: 20 January 2020
Revised Date: 23 March 2020
Accepted Date: 7 April 2020
Available Online: 14 April 2020

Figures(4)

Lithium-sulfur (Li-S) batteries have received extensive attention due to their high theoretical specific energy density. However, the utilization of sulfur is seriously reduced by the shuttle effect of lithium polysulfides and the low conductivity of sulfur and lithium sulfide (Li₂S). Herein, we introduced bimetalorganic frameworks (Co/Zn-ZIF) derived cobalt and nitrogen-doped carbons (Co/N-C) into Li-S batteries through host design and separator modification. The Co/N-C in Li-S batteries effectively limits the shuttle effect through simultaneously serving as polysulfide traps and chemical catalyst. As a result, the Li-S batteries deliver a high reversible capacity of 1614.5 mAh/g and superior long-term cycling stability with a negligible capacity decay of only 0.04% per cycle after 1000 cycles. Furthermore, they have a high area capacity of 5.5 mAh/cm².
- Lithium sulfur battery,
- Co/Zn-ZIF,
- Nitrogen-doped carbons,
- Catalyst,
- Separator modification
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