Citation: Zhang Xin, Miao Jiawei, Zhang Peng, Zhu Qizhen, Jiang Mingchi, Xu Bin. 3D crumbled MXene for high-performance supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(9): 2305-2308. doi: 10.1016/j.cclet.2020.03.040 shu

3D crumbled MXene for high-performance supercapacitors

State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China

zhuqz@mail.buct.edu.cn

xubin@mail.buct.edu.cn,binxumail@163.com

Received Date: 4 March 2020
Revised Date: 12 March 2020
Accepted Date: 13 March 2020
Available Online: 19 March 2020

Figures(4)

MXene materials have recently attracted considerable attention in energy storage application owing to their metallic conductivity, 2D structure and tunable surface terminations. However, the restacking of 2D MXene nanosheets hinders the ion transport and accessibility to the surface, resulting in adverse effect on their electrochemical performances. Here, with the assistance of hexamethylenetetramine (C₆H₁₂N₄), 2D Ti₃C₂T_x MXene nanosheets were fabricated into a 3D architecture with crumbled and porous structure through an electrostatic self-assembly followed by annealing. The resultant 3D structure can expose massive active sites and facilitates the ion transport, which is beneficial for sufficient utilization of the outstanding superiorities of the MXene. Therefore, as a pseudocapacitive material, the 3D crumpled and porous Ti₃C₂T_x MXene shows a gravimetric capacitance of 333 F/g at 1 A/g, and maintains 261 F/g and 132 F/g at ultrahigh current densities of 100 A/g and 1000 A/g, respectively, revealing promising potential for application in supercapacitors.
- Supercapacitors,
- MXene nanosheets,
- 3D porous structure,
- Capacitance,
- Rate performance
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