Citation: Sun Huifang, Zeng Qi, Ye Chen, Zhu Yangguang, Chen Feiyue, Yang Mingyang, Fu Li, Du Shiyu, Yu Jinhong, Jiang Nan, Liu Jianxiong, Wu Tianzhun, Lin Cheng-Te. Pt nanodendrites with (111) crystalline facet as an efficient, stable and pH-universal catalyst for electrochemical hydrogen production[J]. Chinese Chemical Letters, ;2020, 31(9): 2478-2482. doi: 10.1016/j.cclet.2020.03.032 shu

Pt nanodendrites with (111) crystalline facet as an efficient, stable and pH-universal catalyst for electrochemical hydrogen production

Sun Huifang ^a,b,1 ,
Zeng Qi ^c,1 ,
Ye Chen ^b,d ,
Zhu Yangguang ^b,e ,
Chen Feiyue ^b,f ,
Yang Mingyang ^b,d ,
Fu Li ^g ,
Du Shiyu ^h ,
Yu Jinhong ^b,d ,
Jiang Nan ^b,d ,
Liu Jianxiong ^a,**, ,
Wu Tianzhun ^c,**, ,
Lin Cheng-Te ^b,d,*,

a.
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
b.
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering(NIMTE), Chinese Academy of Sciences, Ningbo 315201, China
c.
Shenzhen Institutes of Advanced Technology, Chinese Academy of Science, Shenzhen 518055, China
d.
Center of Material Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
e.
Laboratory of Environmental Biotechnology, School of Environmental and Civil Engineering, Jiangnan University, Wuxi 214122, China
f.
College of Science, Henan University of Technology, Zhengzhou 10463, China
g.
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
h.
Ningbo Institute of Materials Technology and Engineering(NIMTE), Chinese Academy of Sciences, Ningbo 315201, China

^**

Ljx192665@163.com

tz.wu@siat.ac.cn

linzhengde@nimte.ac.cn

Received Date: 30 December 2019
Revised Date: 28 February 2020
Accepted Date: 11 March 2020
Available Online: 12 March 2020

Figures(4)

High-performance nanomaterial catalysts for hydrogen evolution reaction via electrochemical water splitting are significant to the development of hydrogen energy. In this work, we report a robust and highly active catalyst fabricated through direct electrochemical deposition of Pt nanodendrites at the surface of activated carbon (Pt NDs). Owing to the large electrochemically active area and the exposed (111) facet of Pt, Pt NDs exhibits outstanding activity towards hydrogen evolution reaction with a low requiring overpotential of 0.027 V at 10 mA/cm² and Tafel slope of ≈ 22 mV/dec in acidic media. In addition, the hydrogen yield of Pt NDs is 30%-45% larger than that of commercial Pt/C at the same Pt loadings. Moreover, Pt NDs exhibits excellent long-term durability whose hydrogen production efficiency remains unchanged after six-hour hydrogen production, while the efficiency of commercial Pt/C catalyst decayed 9% under the same circumstance. Considering the superiority of catalytic activity and stability, this Pt NDs present great potentiality towards practical hydrogen production application.
- Platinum nanodendrites,
- Hydrogen evolution reaction,
- Electrocatalytic activity,
- Long-term durability,
- pH-universal property
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