Citation: Tong Yongli, Liu Hengqi, Dai Meizhen, Xiao Li, Wu Xiang. Metal-organic framework derived Co₃O₄/PPy bifunctional electrocatalysts for efficient overall water splitting[J]. Chinese Chemical Letters, ;2020, 31(9): 2295-2299. doi: 10.1016/j.cclet.2020.03.029 shu

Metal-organic framework derived Co₃O₄/PPy bifunctional electrocatalysts for efficient overall water splitting

Tong Yongli ^a,b ,
Liu Hengqi ^a ,
Dai Meizhen ^a ,
Xiao Li ^a,*, ,
Wu Xiang ^a,*,

a.
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
b.
School of Science, Shenyang Ligong University, Shenyang 110159, China

xiao.li@sut.edu.cn

wuxiang05@sut.edu.cn

Received Date: 17 December 2019
Revised Date: 5 February 2020
Accepted Date: 10 March 2020
Available Online: 10 June 2020

Figures(5)

In this work, we report Co₃O₄@PPy hybrid structured electrode materials for overall water splitting. The as-synthesized Co₃O₄/PPy-120 samples present excellent electrocatalytic performances for OER and HER and long durability. It only requires an operating potential of 1.67 V to deliver a current density of 10 mA/cm² with a remarkable durability for 28 h. The superior electrocatalytic performances mainly can be attributed to the unique heterostructures and the synergistic effects between PPy and Co₃O₄ electrode materials.
- Metal-organic framework,
- Co₃O₄/PPy,
- Bi-functionality,
- Electrocatalyst,
- OER and HER
1. [1]
  S.J. Guo, Y. Yu, Q. Zhang, Chin. Chem. Lett. 28(2017) 2169-2170. doi: 10.1016/j.cclet.2017.11.047
2. [2]
  D. Zhao, H. Liu, X. Wu, Nano Energy 57(2019) 363-370. doi: 10.1016/j.nanoen.2018.12.066
3. [3]
  H. Liu, D. Zhao, P. Hu, et al., Chem. Eng. J. 373(2019) 485-492. doi: 10.1016/j.cej.2019.05.066
4. [4]
  X. Du, X. Zhang, Int. J. Hydrogen Energy 44(2019) 24705-24711. doi: 10.1016/j.ijhydene.2019.07.228
5. [5]
  W.Q. Yang, J.R. Zeng, Y.X. Hua, et al., J. Power Sources 436(2019) 226887. doi: 10.1016/j.jpowsour.2019.226887
6. [6]
  Y.Q. Feng, H.Y. Cheng, J. Han, et al., Chin. Chem. Lett. 28(2017) 2254-2258. doi: 10.1016/j.cclet.2017.10.025
7. [7]
  M. Li, Y. Zhu, H. Wang, et al., Adv. Energy Mater. 9(2019) 1803185. doi: 10.1002/aenm.201803185
8. [8]
  K. Wang, H. Wang, R. Bi, et al., Inorg. Chem. Front. 6(2019) 2873-2884. doi: 10.1039/C9QI00596J
9. [9]
  X. Yang, Y. Wang, Y. Hu, et al., ChemElectroChem. 6(2019) 3657-3666. doi: 10.1002/celc.201900915
10. [10]
  M. Mofarahi, F. Gholipour, Microporous Mesoporous Mater. 200(2014) 1-10. doi: 10.1016/j.micromeso.2014.08.022
11. [11]
  Y.L. Tong, D.L. Qi, B.Q. Chi, W.Q. Zhang, Sci. Adv. Mater. 11(2019) 338-344. doi: 10.1166/sam.2019.3446
12. [12]
  K. Shrestha, S.H. Lee, H. Ahn, S.H. Han, Microporous Mesoporous Mater. 153(2012) 163-165. doi: 10.1016/j.micromeso.2011.12.040
13. [13]
  M. Ding, J. Zhou, H. Yang, et al., Chin. Chem. Lett. 31(2020) 71-76. doi: 10.1016/j.cclet.2019.05.029
14. [14]
  S.H. Ye, G.R. Li, Front. Chem. Sci. Eng. 12(2018) 473-480. doi: 10.1007/s11705-018-1724-9
15. [15]
  Y. Xu, D. Guo, T. Li, et al., J. Colloid Interfaces. Sci. 565(2020) 23-34. doi: 10.1016/j.jcis.2020.01.004
16. [16]
  J.L. Liu, W.W. Zhou, L.F. Lai, et al., Nano Energy 2(2013) 726-732. doi: 10.1016/j.nanoen.2012.12.008
17. [17]
  J. Feng, W. Song, L. Sun, L. Xu, RSC Adv. 6(2016) 110337-110343. doi: 10.1039/C6RA22728G
18. [18]
  S. Bao, S. Luo, S. Yan, et al., Electrochim. Acta 307(2019) 293-301. doi: 10.1016/j.electacta.2019.03.216
19. [19]
  X. Wei, Y.H. Zhang, H.C. He, et al., Chem. Commun. 55(2019) 6515. doi: 10.1039/C9CC02037C
20. [20]
  H. Mao, X. Guo, Y.L. Fu, et al., Appl. Surf. Sci. 485(2019) 554-563. doi: 10.1016/j.apsusc.2019.04.195
21. [21]
  J.K. Zhu, W.M. Tu, Z.Y. Bai, et al., Electrochim. Acta 323(2019) 134821. doi: 10.1016/j.electacta.2019.134821
22. [22]
  J. Shen, J. Gao, L.D. Ji, X.R. Chen, C. Wu, Appl. Surf. Sci. 497(2019) 143818. doi: 10.1016/j.apsusc.2019.143818
23. [23]
  D. Xiong, Q. Zhang, W. Li, et al., Nanoscale 9(2017) 2711-2717. doi: 10.1039/C7NR00140A
24. [24]
  J. Yang, L. Wei, T. Zhao, et al., Electrochim. Acta 318(2019) 949-956. doi: 10.1016/j.electacta.2019.06.105
25. [25]
  D. Zhao, M. Dai, H. Liu, et al., Adv. Mater. Interfaces 6(2019) 1901308. doi: 10.1002/admi.201901308
26. [26]
  H. Liu, X. Ma, Y. Rao, et al., ACS Appl. Mater. Interfaces 10(2018) 108907.
27. [27]
  H. Mao, X. Guo, Y. Fu, et al., Appl. Surf. Sci. 485(2019) 554-563. doi: 10.1016/j.apsusc.2019.04.195
28. [28]
  Y.L. Tong, B.Q. Chi, D.L. Qi, X.Y. Liu, Sci. Adv. Mater. 11(2019) 1087-1092. doi: 10.1166/sam.2019.3514
29. [29]
  H. Liu, S. Luo, S. Yan, et al., J. Electroanal. Chem. 850(2019) 113434. doi: 10.1016/j.jelechem.2019.113434
30. [30]
  J. Li, S. Luo, X. Ding, et al., ACS Appl. Mater. Interfaces 10(2018) 10786-10795. doi: 10.1021/acsami.7b17597
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Metal-organic framework derived Co3O4/PPy bifunctional electrocatalysts for efficient overall water splitting

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通讯作者: 陈斌, bchen63@163.com

Metal-organic framework derived Co₃O₄/PPy bifunctional electrocatalysts for efficient overall water splitting