Citation: Zhang Kan, Zhang Yifan, Shi Lei. A review of linear carbon chains[J]. Chinese Chemical Letters, ;2020, 31(7): 1746-1756. doi: 10.1016/j.cclet.2020.03.019 shu

A review of linear carbon chains

Zhang Kan ¹ ,
Zhang Yifan ¹ ,
Shi Lei ^*,

State Key Laboratory of Optoelectronic Materials and Technologies, Nanotechnology Research Center, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China

shilei26@mail.sysu.edu.cn

Received Date: 11 January 2020
Revised Date: 5 March 2020
Accepted Date: 6 March 2020
Available Online: 6 March 2020

Figures(6)

Linear carbon chains (LCCs) are a one-dimensional sp¹-hybridized allotrope of carbon. LCCs are extremely unstable: The longer the LCCs, the less stable the materials. Thus, it is a big challenge to synthesize long LCCs. Although the research on the short LCCs, e.g., polyynes, can be traced back to the 18^th, LCCs are still not well-known compared to other allotropes of carbon, e.g., fullerenes, carbon nanotubes and graphene. Therefore, introducing recent progress on LCCs is of great significance to draw more attention in the community of nanocarbons as well as nanomaterials in general. Theoretically, various excellent properties have been predicted. Experimentally, LCCs with different length in many kinds of forms have been successfully synthesized. In this review, we summarized recent studies of polyynic LCCs from both theoretical and experimental aspects. Also, perspectives are highlighted to point out the further investigations of the materials.
- Linear carbon chains,
- Polyyne,
- Carbyne,
- Carbon nanotubes,
- Electronic property
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