Citation: Ding Junfan, Xu Rui, Yan Chong, Xiao Ye, Liang Yeru, Yuan Hong, Huang Jiaqi. Integrated lithium metal anode protected by composite solid electrolyte film enables stable quasi-solid-state lithium metal batteries[J]. Chinese Chemical Letters, ;2020, 31(9): 2339-2342. doi: 10.1016/j.cclet.2020.03.015 shu

Integrated lithium metal anode protected by composite solid electrolyte film enables stable quasi-solid-state lithium metal batteries

Ding Junfan ^a,b,1 ,
Xu Rui ^a,b,1 ,
Yan Chong ^a,b ,
Xiao Ye ^a,b ,
Liang Yeru ^c ,
Yuan Hong ^a,b ,
Huang Jiaqi ^a,b,*,

a.
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China
b.
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
c.
College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China

jqhuang@bit.edu.cn

Received Date: 13 January 2020
Revised Date: 27 February 2020
Accepted Date: 1 March 2020
Available Online: 7 March 2020

Figures(4)

Lithium (Li) metal, possessing an extremely high theoretical specific capacity (3860 mAh/g) and the most negative electrode potential (-3.040 V vs. standard hydrogen electrode), is one the most favorable anode materials for future high-energy-density batteries. However, the poor cyclability and safety issues induced by extremely unstable interfaces of traditional liquid Li metal batteries have limited their practical applications. Herein, a quasi-solid battery is constructed to offer superior interfacial stability as well as excellent interfacial contact by the incorporation of Li@composite solid electrolyte integrated electrode and a limited amount of liquid electrolyte (7.5 μL/cm²). By combining the inorganic garnet Aldoped Li_6.75La₃Zr_1.75Ta_0.25O₁₂ (LLZO) with high mechanical strength and ionic conductivity and the organic ethylene-vinyl acetate copolymer (EVA) with good flexibility, the composite solid electrolyte film could provide sufficient ion channels, sustained interfacial contact and good mechanical stability at the anode side, which significantly alleviates the thermodynamic corrosion and safety problems induced by liquid electrolytes. This innovative and facile quasi-solid strategy is aimed to promote the intrinsic safety and stability of working Li metal anode, shedding light on the development of next-generation high-performance Li metal batteries.
- Lithium metal anodes,
- Composite electrolyte,
- Quasi-solid-state batteries,
- Lithium dendrites,
- Lean electrolyte
1. [1]
  D.C. Lin, Y.Y. Liu, Y. Cui, Nat. Nanotechnol. 12(2017) 194-206. doi: 10.1038/nnano.2017.16
2. [2]
  X.Q. Zhang, C.Z. Zhao, J.Q. Huang, et al., Engineering 4(2018) 831-847. doi: 10.1016/j.eng.2018.10.008
3. [3]
  Y. Liang, C.Z. Zhao, H. Yuan, et al., InfoMat. 1(2019) 6-32. doi: 10.1002/inf2.12000
4. [4]
  J.W. Choi, D. Aurbach, Nat. Rev. Mater. 1(2016) 16013. doi: 10.1038/natrevmats.2016.13
5. [5]
  M. Tang, H. Li, E. Wang, et al., Chin. Chem. Lett. 29(2018) 232-244. doi: 10.1016/j.cclet.2017.09.005
6. [6]
  H.J. Peng, J.Q. Huang, X.B. Cheng, et al., Adv. Energy Mater. 7(2017) 1700260. doi: 10.1002/aenm.201700260
7. [7]
  Y.W. Chen, S.Z. Niu, W. Lv, et al., Chin. Chem. Lett. 30(2019) 521-524. doi: 10.1016/j.cclet.2018.04.019
8. [8]
  W. Chen, Y.F. Gong, J.H. Liu, Chin. Chem. Lett. 28(2017) 709-718. doi: 10.1016/j.cclet.2016.10.023
9. [9]
  J.L. Qin, H.Y. Zhao, J.Q. Huang, J. Energy Chem. 29(2019) 1-2. doi: 10.1016/j.jechem.2018.07.001
10. [10]
  M. Zhu, J. Wu, Y. Wang, et al., J. Energy Chem. 37(2019) 126-142. doi: 10.1016/j.jechem.2018.12.013
11. [11]
  X. Xu, S. Wang, H. Wang, et al., J. Energy Chem. 27(2018) 513-527. doi: 10.1016/j.jechem.2017.11.010
12. [12]
  B.Q. Li, X.R. Chen, X. Chen, et al., Research (2019) 4608940.
13. [13]
  W. Xu, J. Wang, F. Ding, et al., Energy Environ. Sci. 7(2014) 513-537. doi: 10.1039/C3EE40795K
14. [14]
  Z.G. Gao, S.J. Zhang, Z.G. Huang, et al., Chin. Chem. Lett. 30(2019) 525-528. doi: 10.1016/j.cclet.2018.05.016
15. [15]
  R. Xu, X.-B. Cheng, C. Yan, et al., Matter 1(2019) 317-344. doi: 10.1016/j.matt.2019.05.016
16. [16]
  K. Zhang, G.H. Lee, M. Park, et al., Adv. Energy Mater. 6(2016) 1600811. doi: 10.1002/aenm.201600811
17. [17]
  X. Shen, H. Liu, X.B. Cheng, et al., Energy Storage Mater. 12(2018) 161-175. doi: 10.1016/j.ensm.2017.12.002
18. [18]
  L.L. Li, S.Y. Li, Y.Y. Lu, Chem. Commun. 54(2018) 6648-6661. doi: 10.1039/C8CC02280A
19. [19]
  R. Xu, Y.Z. Sun, Y.F. Wang, et al., Chin. Chem. Lett. 28(2017) 2235-2238. doi: 10.1016/j.cclet.2017.09.065
20. [20]
  X.B. Cheng, C. Yan, X.Q. Zhang, et al., ACS Energy Lett. 3(2018) 1564-1570. doi: 10.1021/acsenergylett.8b00526
21. [21]
  Y. Yuan, F. Wu, G. Chen, et al., J. Energy Chem. 37(2019) 197-203. doi: 10.1016/j.jechem.2019.03.014
22. [22]
  M.D. Tikekar, S. Choudhury, Z. Tu, et al., Nat. Energy 1(2016) 16114. doi: 10.1038/nenergy.2016.114
23. [23]
  K. Xu, Chem. Rev. 114(2014) 11503-11618. doi: 10.1021/cr500003w
24. [24]
  R. Miao, J. Yang, X. Feng, et al., J. Power Sources 271(2014) 291-297. doi: 10.1016/j.jpowsour.2014.08.011
25. [25]
  X.Q. Zhang, X.B. Cheng, Q. Zhang, Adv. Mater. Interfaces 5(2018) 1701097. doi: 10.1002/admi.201701097
26. [26]
  H. Kuwata, H. Sonoki, M. Matsui, et al., Electrochemistry 84(2016) 854-860. doi: 10.5796/electrochemistry.84.854
27. [27]
  R. Xu, Y. Xiao, R. Zhang, et al., Adv. Mater. 31(2019) 1808392. doi: 10.1002/adma.201808392
28. [28]
  C. Yan, H. Yuan, H.S. Park, et al., J. Energy Chem. 47(2020) 217-220. doi: 10.1016/j.jechem.2019.09.034
29. [29]
  J. Janek, W.G. Zeier, Nat. Energy 1(2016) 16141. doi: 10.1038/nenergy.2016.141
30. [30]
  X. Shen, X.B. Cheng, P. Shi, et al., J. Energy Chem. 37(2019) 29-34. doi: 10.1016/j.jechem.2018.11.016
31. [31]
  X. Wu, K. Pan, M. Jia, et al., Green Energy Environ. 4(2019) 360-374. doi: 10.1016/j.gee.2019.05.003
32. [32]
  X.B. Cheng, Q. Zhang, J. Mater. Chem. A 3(2015) 7207-7209. doi: 10.1039/C5TA00689A
33. [33]
  R. Chen, W. Qu, X. Guo, et al., Mater. Horiz. 3(2016) 487-516. doi: 10.1039/C6MH00218H
34. [34]
  R. Murugan, V. Thangadurai, W. Weppner, Angew. Chem. Int. Ed. 46(2007) 7778-7781. doi: 10.1002/anie.200701144
1. [1]
  Qian Wang , Dong Yang , Wenxing Xin , Yongqi Wang , Wenchang Han , Wengxiang Yan , Chunman Yang , Fei Wang , Yiyong Zhang , Ziyi Zhu , Xue Li . Modulation of desolvation barriers and inhibition of lithium dendrites based on lithophilic electrolyte additives for lithium metal anode. Chinese Chemical Letters, 2025, 36(6): 110669-. doi: 10.1016/j.cclet.2024.110669
2. [2]
  Xingjie Li , Chengjun Yi , Weifei Hu , Huishan Zhang , Jiale Xia , Yuanyuan Li , Jinping Liu . Emerging sulfide-polymer composite solid electrolyte membranes. Chinese Chemical Letters, 2025, 36(6): 110215-. doi: 10.1016/j.cclet.2024.110215
3. [3]
  Zhe Wang , Li-Peng Hou , Qian-Kui Zhang , Nan Yao , Aibing Chen , Jia-Qi Huang , Xue-Qiang Zhang . High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries. Chinese Chemical Letters, 2024, 35(4): 108570-. doi: 10.1016/j.cclet.2023.108570
4. [4]
  Mengwen Wang , Qintao Sun , Yue Liu , Zhengan Yan , Qiyu Xu , Yuchen Wu , Tao Cheng . Impact of lithium nitrate additives on the solid electrolyte interphase in lithium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(2): 100203-100203. doi: 10.1016/j.cjsc.2023.100203
5. [5]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
6. [6]
  Sheng Zhao , Junjie Lu , Bifu Sheng , Siying Zhang , Hao Li , Jizhang Chen , Xiang Han . High-performance room temperature solid-state lithium battery enabled by PP-PVDF multilayer composite electrolyte. Chinese Chemical Letters, 2025, 36(6): 110008-. doi: 10.1016/j.cclet.2024.110008
7. [7]
  Zhangran Ye , Zhixuan Yu , Jingming Yao , Lei Deng , Yunna Guo , Hantao Cui , Chongchong Ma , Chao Tai , Liqiang Zhang , Lingyun Zhu , Peng Jia . An ionically conductive and compressible sulfochloride solid-state electrolyte for stable all-solid-state lithium-based batteries. Chinese Chemical Letters, 2025, 36(8): 110272-. doi: 10.1016/j.cclet.2024.110272
8. [8]
  Jie Chen , Hannan Chen , Bingbing Tian . Enhancing moisture and electrochemical stability of the Li_5.7PS_4.7Cl_1.3 electrolyte by boron nitride coating for all-solid-state lithium metal batteries. Chinese Chemical Letters, 2025, 36(7): 109775-. doi: 10.1016/j.cclet.2024.109775
9. [9]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
10. [10]
  Haining Peng , Huijun Liu , Chengzong Li , Yingfu Li , Qizhi Chen , Tao Li . Diluent modified weakly solvating electrolyte for fast-charging high-voltage lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 109556-. doi: 10.1016/j.cclet.2024.109556
11. [11]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
12. [12]
  Ziling Jiang , Chen Liu , Jie Yang , Xia Li , Chaochao Wei , Qiyue Luo , Zhongkai Wu , Lin Li , Liping Li , Shijie Cheng , Chuang Yu . Designing F-doped Li₃InCl₆ electrolyte with enhanced stability for all-solid-state lithium batteries in a wide voltage window. Chinese Chemical Letters, 2025, 36(6): 109741-. doi: 10.1016/j.cclet.2024.109741
13. [13]
  Hongfei Li , Hao Chen , Qi Kang , Lihe Guo , Xingyi Huang , Haiping Xu . Gel polymer electrolyte for flexible and stretchable lithium metal battery: Advances and prospects. Chinese Chemical Letters, 2025, 36(9): 110325-. doi: 10.1016/j.cclet.2024.110325
14. [14]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
15. [15]
  Jing Guo . Stacking solid-state electrolyte and aluminum pellets for anode-free solid-state batteries. Chinese Chemical Letters, 2025, 36(5): 110764-. doi: 10.1016/j.cclet.2024.110764
16. [16]
  Yang Deng , Yitao Ouyang , Chao Han . Constriction-susceptible makes fast cycling of lithium metal in solid-state batteries: Silicon as an example. Chinese Journal of Structural Chemistry, 2024, 43(7): 100276-100276. doi: 10.1016/j.cjsc.2024.100276
17. [17]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
18. [18]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
19. [19]
  Benjian Xin , Rui Wang , Lili Liu , Zhiqiang Niu . Metal-organic framework derived MnO@C/CNTs composite for high-rate lithium-based semi-solid flow batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100116-100116. doi: 10.1016/j.cjsc.2023.100116
20. [20]
  Xuanyang Jin , Xincheng Guo , Siyang Dong , Shilan Li , Shengdong Jin , Peng Xia , Shengjun Lu , Yufei Zhang , Haosen Fan . Synergistic regulation of polysulfides shuttle effect and lithium dendrites from cobalt-molybdenum bimetallic carbides (Co-Mo-C) heterostructure for robust Li-S batteries. Chinese Chemical Letters, 2025, 36(7): 110604-. doi: 10.1016/j.cclet.2024.110604

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1693)
HTML views(146)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142