Citation: Han Pengyu, Tan Tan, Wu Fei, Cai Ping, Cheng Gongzhen, Wei Luo. Nickel-iron borate coated nickel-iron boride hybrid for highly stable and active oxygen evolution electrocatalysis[J]. Chinese Chemical Letters, ;2020, 31(9): 2469-2472. doi: 10.1016/j.cclet.2020.03.009 shu

Nickel-iron borate coated nickel-iron boride hybrid for highly stable and active oxygen evolution electrocatalysis

Han Pengyu ^a,1 ,
Tan Tan ^a,1 ,
Wu Fei ^b,1 ,
Cai Ping ^a,**, ,
Cheng Gongzhen ^a ,
Wei Luo ^a,c,*,

1.
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
2.
Department of Orthopaedic Surgery, Renmin Hospital of Wuhan University, Wuhan 430060, China
c.
Suzhou Institute of Wuhan University, Suzhou 215123, China

^**

caiping@whu.edu.cn

wluo@whu.edu.cn

Received Date: 20 January 2020
Revised Date: 16 February 2020
Accepted Date: 3 March 2020
Available Online: 4 March 2020

Figures(4)

The development of efficient and cost-effective electrocatalysts toward anodic oxygen evolution reaction (OER) is crucial for the commercial application of electrochemical water splitting. As the most promising electrocatalysts, the OER performances of nickel-iron-based materials can be further improved by introducing metalloid elements to modify their electron structures. Herein, we developed an efficient hybrid electrocatalyst with nickel-iron boride (NiFeB) as core and amorphous nickel-iron borate (NiFeB_i) as shell (NiFeB@NiFeB_i) via a simple aqueous reduction. The obtained NiFeB@NiFeB_i exhibits a small overpotential of 237 mV at 10 mA/cm² and Tafel slope of 57.65 mV/dec in 1.0 mol/L KOH, outperforming most of the documented precious-metal-free based electrocatalysts. Benefiting from the in situ formed amorphous NiFeB_i layer, it shows excellent stability toward the oxygen evolution reaction (OER). These findings might provide a new way to design advanced precious-metal-free electrocatalysts for OER and the application of electrochemical water splitting.
- Oxygen evolution reaction,
- Metal boride,
- Metal borate,
- Core-shell
1. [1]
  C.C. McCrory, S. Jung, J.C. Peters, T.F. Jaramillo, J. Am. Chem. Soc. 135(2013) 16977-16987. doi: 10.1021/ja407115p
2. [2]
  B. Wang, X. Cui, J. Huang, R. Cao, Q. Zhang, Chin. Chem. Lett. 29(2018) 1757-1767. doi: 10.1016/j.cclet.2018.11.021
3. [3]
  Z. Li, H. He, H. Cao, et al., Appl. Catal. B:Environ. 240(2019) 112-121. doi: 10.1016/j.apcatb.2018.08.074
4. [4]
  N. Yao, P. Li, Z. Zhou, et al., Adv. Energy Mater. 9(2019) 1902449. doi: 10.1002/aenm.201902449
5. [5]
  H. Yuan, L. Kong, T. Li, Q. Zhang, Chin. Chem. Lett. 28(2017) 2180-2194. doi: 10.1016/j.cclet.2017.11.038
6. [6]
  Y. Zheng, Y. Jiao, A. Vasileff, S.Z. Qiao, Angew. Chem. Int. Ed. 57(2018) 7568-7579. doi: 10.1002/anie.201710556
7. [7]
  Y. Men, P. Li, J. Zhou, et al., ACS Catal. 9(2019) 3744-3752. doi: 10.1021/acscatal.9b00407
8. [8]
  D. He, X. Wu, W. Liu, et al., Chin. Chem. Lett. 30(2019) 229-233.
9. [9]
  R. Subbaraman, D. Tripkovic, K.C. Chang, et al., Nat. Mater. 11(2012) 550-557. doi: 10.1038/nmat3313
10. [10]
  M. Wang, M. Wang, Y. Fu, S. Shen, Chin. Chem. Lett. 28(2017) 2207-2211. doi: 10.1016/j.cclet.2017.11.037
11. [11]
  C. Du, L. Yang, F. Yang, G. Cheng, W. Luo, ACS Catal. 7(2017) 4131-4137. doi: 10.1021/acscatal.7b00662
12. [12]
  N. Yao, P. Li, Z. Zhou, et al., Small 15(2019) 1901993. doi: 10.1002/smll.201901993
13. [13]
  Q. Yin, J. Tan, C. Besson, et al., Science 328(2010) 342-345. doi: 10.1126/science.1185372
14. [14]
  J. Suntivich, K.J. May, H.A. Gasteiger, J.B. Goodenough, Y. Shao-Horn, Science 334(2011) 1383-1385. doi: 10.1126/science.1212858
15. [15]
  Y. Jiao, Y. Zheng, M. Jaroniec, S. Qiao, Chem. Soc. Rev. 44(2015) 2060-2086. doi: 10.1039/C4CS00470A
16. [16]
  L. Fu, F. Yang, C. Cheng, W. Luo, Nanoscale 10(2018) 1892-1897. doi: 10.1039/C7NR09377B
17. [17]
  K. Sardar, E. Petrucco, C.I. Hiley, et al., Angew. Chem. Int. Ed. 53(2014) 10960-10964. doi: 10.1002/anie.201406668
18. [18]
  L. Fu, C. Cheng, W. Luo, J. Mater. Chem. A 5(2017) 24836-24841. doi: 10.1039/C7TA08982A
19. [19]
  T. Liu, F. Yang, G. Cheng, W. Luo, Small 14(2018) 1703748. doi: 10.1002/smll.201703748
20. [20]
  X. Cao, X. Zang, X. Zhou, M. Chen, Y. Ding, Chin. Chem. Lett. 29(2018) 811-814. doi: 10.1016/j.cclet.2017.12.010
21. [21]
  C. Dong, T. Kou, H. Gao, Z. Peng, Z. Zhang, Adv. Energy Mater. 8(2018) 1701347. doi: 10.1002/aenm.201701347
22. [22]
  K. Fominykh, P. Chernev, I. Zaharieva, et al., ACS Nano 9(2015) 5180-5188. doi: 10.1021/acsnano.5b00520
23. [23]
  L. Zeng, L. Yang, J. Lu, W. Zhou, et al., Chin. Chem. Lett. 29(2018) 1875-1878. doi: 10.1016/j.cclet.2018.10.026
24. [24]
  M. Gong, Y. Li, H. Wang, et al., J. Am. Chem. Soc. 135(2013) 8452-8455. doi: 10.1021/ja4027715
25. [25]
  C. Liang, P. Zou, A. Nairan, et al., Energy Environ. Sci. 13(2020) 86-95. doi: 10.1039/C9EE02388G
26. [26]
  Z. Liu, G. Zhang, K. Zhang, H. Liu, J. Qu, ACS Sustain. Chem. Eng. 6(2018) 7206-7211. doi: 10.1021/acssuschemeng.8b00471
27. [27]
  B. Li, S. Zhang, C. Tang, X. Cui, Q. Zhang, Small 13(2017) 1700610. doi: 10.1002/smll.201700610
28. [28]
  J. Yu, G. Cheng, W. Luo, Nano Res. 11(2018) 2149-2158. doi: 10.1007/s12274-017-1832-8
29. [29]
  J. Masa, P. Weide, D. Peeters, et al., Adv. Energy Mater. 6(2016) 1502313. doi: 10.1002/aenm.201502313
30. [30]
  J. Masa, I. Sinev, H. Mistry, et al., Adv. Energy Mater. 7(2017) 1700381. doi: 10.1002/aenm.201700381
31. [31]
  T. Tan, P. Han, H. Cong, G. Cheng, W. Luo, ACS Sustain. Chem. Eng. 7(2019) 5620-5625. doi: 10.1021/acssuschemeng.9b00258
32. [32]
  H. Li, P. Wen, Q. Li, et al., Adv. Energy Mater. 7(2017) 1700513. doi: 10.1002/aenm.201700513
33. [33]
  Y. Lin, L. Yang, Y. Zhang, et al., Adv. Energy Mater. 8(2018) 1703623. doi: 10.1002/aenm.201703623
34. [34]
  J. Gao, B. Jiang, C. Ni, Y. Qi, X. Bi, Chem. Eng. J. 382(2020) 123034. doi: 10.1016/j.cej.2019.123034
35. [35]
  M.W. Louie, A.T. Bell, J. Am. Chem. Soc. 135(2013) 12329-12337. doi: 10.1021/ja405351s
36. [36]
  M. Gorlin, P. Chernev, J. Ferreira de Araujo, et al., J. Am. Chem. Soc. 138(2016) 5603-5614. doi: 10.1021/jacs.6b00332
37. [37]
  W. Jiang, S. Niu, T. Tang, et al., Angew. Chem. Int. Ed. 56(2017) 6572-6577. doi: 10.1002/anie.201703183
38. [38]
  J. Masa, W. Schuhmann, ChemCatChem 11(2019) 5842-5854. doi: 10.1002/cctc.201901151
39. [39]
  S. Klaus, Y. Cai, M.W. Louie, L. Trotochaud, A.T. Bell, J. Phys. Chem. C 119(2015) 7243-7254. doi: 10.1021/acs.jpcc.5b00105
40. [40]
  H. Shin, H. Xiao, W.A. Goddard, J. Am. Chem. Soc. 140(2018) 6745-6748. doi: 10.1021/jacs.8b02225
41. [41]
  Y. Liu, S. Jiang, S. Li, et al., Appl. Catal. B:Environ. 247(2019) 107-114. doi: 10.1016/j.apcatb.2019.01.094
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