Citation: Wang Ying, Ye Qing, Yu Menghuan, Zhang Xijun, Deng Chunhui. Sulfonic acid-based metal organic framework functionalized magnetic nanocomposite combined with gas chromatography-electron capture detector for extraction and determination of organochlorine[J]. Chinese Chemical Letters, ;2020, 31(7): 1843-1846. doi: 10.1016/j.cclet.2020.02.054 shu

Sulfonic acid-based metal organic framework functionalized magnetic nanocomposite combined with gas chromatography-electron capture detector for extraction and determination of organochlorine

Wang Ying ^a ,
Ye Qing ^a,*, ,
Yu Menghuan ^a ,
Zhang Xijun ^a ,
Deng Chunhui ^b,*,

a.
School of chemistry and Environmental Science, Shangrao Normal University, Shangrao 334001, China
b.
Department of Chemistry, Fudan University, Shanghai 200433, China

sryq6333@163.com

chdeng@fudan.edu.cn

Received Date: 3 January 2020
Revised Date: 26 February 2020
Accepted Date: 27 February 2020
Available Online: 28 February 2020

Figures(2)

The metal organic framework functionalized with sulfonic acid was combined with magnetic nanoparticles to fabricate a new nanocomposite (denoted as Fe₃O₄@PDA@Zr-SO₃H). By combining with gas chromatography-electron capture detector, the resulting Fe₃O₄@PDA@Zr-SO₃H nanocomposite was successfully used as a high-efficiency adsorbent for pre-concentrating eight organochlorine pesticides from water sample in environment. Apart from the ability of fast separation, the as-prepared Fe₃O₄@PDA@Zr-SO₃H nanocomposite also exhibited high adsorption capacity for organochlorine pesticides. With the use of optimal experimental conditions, the linear relationship can be obtained in the range of 0.05~300 μg/L, the correlation coefficient was over 0.9978, and the relative standard deviation was located in 2.5%-7.7%. Moreover, the limit of detection and quantification was between 0.005-0.016 μg/L and 0.017~0.050 μg/L. Finally, the nanocomposite was used for the determination of organochlorine pesticides from environmental water samples, and displayed the recovery of 82%-118%.
- Organochlorine pesticides,
- Metal-organic framework,
- Magnetic nanocomposite,
- Water,
- Gas chromatography-electron capture detector
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