Citation: Xu Jianguang, Zhu Jiale, Gong Chen, Guan Zexin, Yang Dan, Shen Zhihan, Yao Wei, Wu Haijiang. Achieving high yield of Ti₃C₂T_x MXene few-layer flakes with enhanced pseudocapacior performance by decreasing precursor size[J]. Chinese Chemical Letters, ;2020, 31(4): 1039-1043. doi: 10.1016/j.cclet.2020.02.050 shu

Achieving high yield of Ti₃C₂T_x MXene few-layer flakes with enhanced pseudocapacior performance by decreasing precursor size

Xu Jianguang ^a,*, ,
Zhu Jiale ^a,b ,
Gong Chen ^a,b ,
Guan Zexin ^a ,
Yang Dan ^a ,
Shen Zhihan ^a ,
Yao Wei ^a,*, ,
Wu Haijiang ^b,*,

a.
School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China
b.
Key Laboratory of Hunan Province for Efficient Power System and Intelligent Manufacturing, Shaoyang University, Shaoyang 422000, China

jgxu@163.com

xiaoniu1981@126.com

hjwu@hnsyu.edu.cn

Received Date: 31 January 2020
Revised Date: 19 February 2020
Accepted Date: 19 February 2020
Available Online: 27 February 2020

Figures(4)

Ti₃C₂T_x, a most studied member of MXene family, shows promise as a candidate electrode for pseudocapacitor due to its electronic conductivity and hydrophilic surface. However, the unsatisfactory yield of Ti₃C₂T_x few-layer flakes significantly restricted it in real applications. Here, we proposed a simple solution to boost the yield of Ti₃C₂T_x few-layer flakes by decreasing precursor size. When using the small 500 mesh Ti₃AlC₂ powders as raw material, high yield of 65% was successfully achieved. Moreover, the asreceived small flakes also exhibit an enhanced pseudocapacior performance owing to their excellent electrical conductivity, expanded interlayer space and more O content on the surface. This work not only sheds light on the cost effective mass production of Ti₃C₂T_x few-layer flakes, but also provides an efficient solution for the design of MXene electrodes with high pseudocapacior performance.
- MXene,
- Ti₃C₂T_x,
- High yield,
- Pseudocapacitor,
- Precursor size,
- Flake size
1. [1]
  M. Naguib, M. Kurtoglu, V. Presser, et al., Adv. Mater. 23(2011) 4248-4253. doi: 10.1002/adma.201102306
2. [2]
  M. Naguib, J. Come, B. Dyatkin, et al., Electrochem. Commun. 16(2012) 61-64. doi: 10.1016/j.elecom.2012.01.002
3. [3]
  M.R. Lukatskaya, O. Mashtalir, C.E. Ren, et al., Science 341(2013) 1502-1505. doi: 10.1126/science.1241488
4. [4]
  M. Naguib, J. Halim, J. Lu, et al., J. Am. Chem. Soc. 135(2013) 15966-15969. doi: 10.1021/ja405735d
5. [5]
  J. Yan, C.E. Ren, K. Maleski, et al., Adv. Funct. Mater. (2017) 1701264.
6. [6]
  M.R. Lukatskaya, S. Kota, Z. Lin, et al., Nat. Energy 6(2017) 17105.
7. [7]
  Y. Liu, P. Zhang, N. Sun, et al., Adv. Mater. 30(2018) 1707334. doi: 10.1002/adma.201707334
8. [8]
  S. Li, P. Tuo, J. Xie, et al., Nano Energy 47(2018) 512-518. doi: 10.1016/j.nanoen.2018.03.022
9. [9]
  Z. Li, Y. Wu, Small (2019) 1804736.
10. [10]
  A.D. Handoko, S.N. Steinmann, Z.W. Seh, Nanoscale Horiz. 4(2019) 809-827. doi: 10.1039/C9NH00100J
11. [11]
  C. Liu, Q. Xu, Q. Zhang, et al., J. Mater. Sci. 54(2019) 2458-2471. doi: 10.1007/s10853-018-2990-0
12. [12]
  X. Xie, Z. Wu, N. Zhang, Chin. Chem. Lett. (2019), doi:https://doi.org/10.1016/j.cclet.2019.10.012. doi: 10.1016/j.cclet.2019.10.012
13. [13]
  S. Zhao, H. Zhang, J. Luo, et al., ACS Nano 12(2018) 11193-11202. doi: 10.1021/acsnano.8b05739
14. [14]
  J. Liu, H. Zhang, R. Sun, et al., Adv. Mater. (2017) 1702367.
15. [15]
  F. Shahzad, M. Alhabeb, C.B. Hatter, et al., Science 353(2016) 1137-1140. doi: 10.1126/science.aag2421
16. [16]
  K. Rasool, M. Helal, A. Ali, et al., ACS Nano 10(2016) 3674-3684. doi: 10.1021/acsnano.6b00181
17. [17]
  E.A. Mayerberger, R.M. Street, R.M. McDaniel, M.W. Barsoum, C.L. Schauer, RSC Adv. 8(2018) 35386-35394. doi: 10.1039/C8RA06274A
18. [18]
  M. Zhang, Y. Wang, F. Gao, et al., Ceram. Int. 45(2019) 19467-19472. doi: 10.1016/j.ceramint.2019.06.202
19. [19]
  Y. Chen, Y. Wang, Y. Luo, et al., IEEE Electr. Device Lett. 40(2019) 1686-1689. doi: 10.1109/LED.2019.2936261
20. [20]
  N. He, X. Liu, F. Gao, et al., Mater. Lett. 266(2020) 127413. doi: 10.1016/j.matlet.2020.127413
21. [21]
  X. Xie, C. Chen, N. Zhang, et al., Nat. Sustain. 2(2019) 856-862. doi: 10.1038/s41893-019-0373-4
22. [22]
  J. Xuan, Z. Wang, Y. Chen, et al., Angew. Chem. Int. Ed.128(2016) 14789-14794. doi: 10.1002/ange.201606643
23. [23]
  W. Wu, J. Xu, X. Tang, et al., Chem. Mater. 30(2018) 5932-5940. doi: 10.1021/acs.chemmater.8b01976
24. [24]
  S. Yang, P. Zhang, F. Wang, et al., Angew. Chem. Int. Ed. 57(2018) 15491-15495. doi: 10.1002/anie.201809662
25. [25]
  Z. Sun, M. Yuan, L. Lin, et al., ACS Mater. Lett. (2019) 628-632.
26. [26]
  T. Li, L. Yao, Q. Liu, et al., Angew. Chem. Int. Ed. 57(2018) 6115-6119. doi: 10.1002/anie.201800887
27. [27]
  F. Han, S. Luo, L. Xie, et al., ACS Appl. Mater. Interfaces 11(2019) 8443-8452. doi: 10.1021/acsami.8b22339
28. [28]
  X. Cai, Y. Luo, B. Liu, H. Cheng, Chem. Soc. Rev. 47(2018) 6224-6266. doi: 10.1039/C8CS00254A
29. [29]
  M. Ghidiu, M.R. Lukatskaya, M. Zhao, Y. Gogotsi, M.W. Barsoum, Nature 516(2014) 78-171. doi: 10.1038/nature13970
30. [30]
  E. Kayali, A. VahidMohammadi, J. Orangi, M. Beidaghi, ACS Appl. Mater. Interfaces 10(2018) 25949-25954. doi: 10.1021/acsami.8b07397
31. [31]
  K. Maleski, C.E. Ren, M. Zhao, B. Anasori, Y. Gogotsi, ACS Appl. Mater. Interfaces 10(2018) 24491-24498. doi: 10.1021/acsami.8b04662
32. [32]
  A. Qian, J.Y. Seo, H. Shi, J.Y. Lee, C. Chung, ChemSusChem 11(2018) 3719-3723. doi: 10.1002/cssc.201801759
33. [33]
  X. Chen, Y. Zhu, M. Zhang, et al., ACS Nano 13(2019) 9449-9456. doi: 10.1021/acsnano.9b04301
34. [34]
  T. Hu, M. Hu, B. Gao, W. Li, X. Wang, J. Phys. Chem. C 122(2018) 18501-18509. doi: 10.1021/acs.jpcc.8b04427
35. [35]
  R. Ibragimova, M.J. Puska, H. Komsa, ACS Nano 13(2019) 9171-9181. doi: 10.1021/acsnano.9b03511
36. [36]
  M. Hu, Z. Li, T. Hu, et al., ACS Nano 10(2016) 11344-11350. doi: 10.1021/acsnano.6b06597
37. [37]
  Y. Dall'Agnese, M.R. Lukatskaya, K.M. Cook, et al., Electrochem. Commun. 48(2014) 118-122. doi: 10.1016/j.elecom.2014.09.002
38. [38]
  C.J. Zhang, S. Pinilla, N. McEvoy, et al., Chem. Mater. 29(2017) 4848-4856. doi: 10.1021/acs.chemmater.7b00745
39. [39]
  J.L. Hart, K. Hantanasirisakul, A.C. Lang, et al., Nature Commun. 10(2019) 522. doi: 10.1038/s41467-018-08169-8
40. [40]
  Y. Xie, P.R.C. Kent, Phys. Rev. B 87(2013) 235441. doi: 10.1103/PhysRevB.87.235441
41. [41]
  T. Hu, Z. Li, M. Hu, et al., J. Phys. Chem. C 121(2017) 19254-19261. doi: 10.1021/acs.jpcc.7b05675
42. [42]
  M.R. Lukatskaya, S. Bak, X. Yu, et al., Adv. Energy Mater. 5(2015) 1500589. doi: 10.1002/aenm.201500589
43. [43]
  M. Hu, T. Hu, Z. Li, et al., ACS Nano 12(2018) 3578-3586. doi: 10.1021/acsnano.8b00676
1. [1]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
2. [2]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
3. [3]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
4. [4]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
5. [5]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
6. [6]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
7. [7]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
8. [8]
  Junqi Wang , Shuai Zhang , Jingjing Ma , Xiangjun Liu , Yayun Ma , Zhimin Fan , Jingfeng Wang . Augmenting levoglucosan production through catalytic pyrolysis of biomass exploiting Ti₃C₂T_x MXene. Chinese Chemical Letters, 2024, 35(12): 109725-. doi: 10.1016/j.cclet.2024.109725
9. [9]
  Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS₂ on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717
10. [10]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305
11. [11]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
12. [12]
  Ying Zhao , Yin-Hang Chai , Tian Chen , Jie Zheng , Ting-Ting Li , Francisco Aznarez , Li-Long Dang , Lu-Fang Ma . Size-controlled synthesis and near-infrared photothermal response of Cp* Rh-based metalla[2]catenanes and rectangular metallamacrocycles. Chinese Chemical Letters, 2024, 35(6): 109298-. doi: 10.1016/j.cclet.2023.109298
13. [13]
  Mengjuan Sun , Muye Zhou , Yifang Xiao , Hailei Tang , Jinhua Chen , Ruitao Zhang , Chunjiayu Li , Qi Ya , Qian Chen , Jiasheng Tu , Qiyue Wang , Chunmeng Sun . Reversibly size-switchable polyion complex micelles for antiangiogenic cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109110-. doi: 10.1016/j.cclet.2023.109110
14. [14]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
15. [15]
  Haijiao Liu , Qiao Feng , Yu Huang , Feng Wu , Yali Liu , Minxia Shen , Xiao Guo , Wenting Dai , Weining Qi , Yifan Zhang , Lu Li , Qiyuan Wang , Bianhong Zhou , Jianjun Li . Composition and size distribution of wintertime inorganic aerosols at ground and alpine regions of northwest China. Chinese Chemical Letters, 2024, 35(11): 109636-. doi: 10.1016/j.cclet.2024.109636
16. [16]
  Xueyan Zhang , Jicong Chen , Songren Han , Shiyan Dong , Huan Zhang , Yuhong Man , Jie Yang , Ye Bi , Lesheng Teng . The size-switchable microspheres co-loaded with RANK siRNA and salmon calcitonin for osteoporosis therapy. Chinese Chemical Letters, 2024, 35(12): 109668-. doi: 10.1016/j.cclet.2024.109668
17. [17]
  Lishan Xiong , Xinyuan Li , Xiaojie Lu , Zhendong Zhang , Yan Zhang , Wen Wu , Chenhui Wang . Inhaled multilevel size-tunable, charge-reversible and mucus-traversing composite microspheres as trojan horse: Enhancing lung deposition and tumor penetration. Chinese Chemical Letters, 2024, 35(9): 109384-. doi: 10.1016/j.cclet.2023.109384
18. [18]
  Jie Yang , Xin-Yue Lou , Dihua Dai , Jingwei Shi , Ying-Wei Yang . Desymmetrized pillar[8]arenes: High-yield synthesis, functionalization, and host-guest chemistry. Chinese Chemical Letters, 2025, 36(1): 109818-. doi: 10.1016/j.cclet.2024.109818
19. [19]
  Liwen Wang , Boyang Wang , Siyu Lu , Shubo Lv , Xiaoli Qu . High quantum yield yellow emission carbon dots for the construction of blue light blocking films. Chinese Chemical Letters, 2025, 36(2): 110497-. doi: 10.1016/j.cclet.2024.110497
20. [20]
  Leichen Wang , Anqing Mei , Na Li , Xiaohong Ruan , Xu Sun , Yu Cai , Jinjun Shao , Xiaochen Dong . Aza-BODIPY dye with unexpected bromination and high singlet oxygen quantum yield for photoacoustic imaging-guided synergetic photodynamic/photothermal therapy. Chinese Chemical Letters, 2024, 35(6): 108974-. doi: 10.1016/j.cclet.2023.108974

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1199)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Achieving high yield of Ti3C2Tx MXene few-layer flakes with enhanced pseudocapacior performance by decreasing precursor size

Metrics

通讯作者: 陈斌, bchen63@163.com

Achieving high yield of Ti₃C₂T_x MXene few-layer flakes with enhanced pseudocapacior performance by decreasing precursor size