Citation: Yang Yue, Wu Lili, Li Lu, Lin Shuangyan, Bai Lina, Ma Xinzhi, Shao Zhitao, Zhang Xitian. Additive-free porous assemblies of Ti₃C₂T_x by freeze-drying for high performance supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(4): 1034-1038. doi: 10.1016/j.cclet.2020.02.027 shu

Additive-free porous assemblies of Ti₃C₂T_x by freeze-drying for high performance supercapacitors

Yang Yue ^a ,
Wu Lili ^a,b,*, ,
Li Lu ^a ,
Lin Shuangyan ^a ,
Bai Lina ^a ,
Ma Xinzhi ^a ,
Shao Zhitao ^a ,
Zhang Xitian ^a,*,

a.
Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China
b.
Center for Engineering Training and Basic Experimentation, Heilongjiang University of Science and Technology, Harbin 150022, China

wll790107@hotmail.com

xtzhangzhang@hotmail.com

Received Date: 23 December 2019
Revised Date: 5 February 2020
Accepted Date: 7 March 2020
Available Online: 14 February 2020

Figures(4)

Ti₃C₂T_x has shown great potential in energy storage filed, but the restacking between Ti₃C₂T_x nanosheets seriously hampers the maximization of its capacitance. In this study, we rationally designed and synthesized porous Ti₃C₂T_x assemblies without any additive by introducing ice as spacers using a facile freeze-drying method. The porous Ti₃C₂T_x assemblies have a three-dimensional network structure, which consists of ultra large Ti₃C₂T_x lamellar walls and lots of macro- and mesopores. It has been proven that there are more-O groups on the surface of the porous Ti₃C₂T_x assemblies than the Ti₃C₂T_x film. The porous Ti₃C₂T_x assemblies deliver a maximum areal capacitance of 1668 mF/cm² when the mass loading is 8.4 mg/cm², an optimized specific capacitance of 247.2 F/g when the mass loading is 5.3 mg/cm², and 87% capacitance retention over 10000 cycles. The symmetric solid-state supercapacitors based on the porous Ti₃C₂T_x assemblies show an areal capacitance of 355.8 mF/cm², the maximum power density of 50 mW/cm² and an outstanding flexibility under different deformation.
- MXenes,
- Ti₃C₂T_x,
- Supercapacitor,
- Freeze-drying,
- Additive-free
1. [1]
  X.Y. Shan, N. Zhang, R.D. Zheng, H. Gao, X.T. Zhang, Electrochim. Acta 295(2019) 286-293. doi: 10.1016/j.electacta.2018.10.151
2. [2]
  Y. Liu, P. Zhang, N. Sun, et al., Adv. Mater. 30(2018) 1707334. doi: 10.1002/adma.201707334
3. [3]
  Q. Jin, N. Zhang, C.C. Zhu, H. Gao, X.T. Zhang, Nanoscale 10(2018) 16935. doi: 10.1039/C8NR05749D
4. [4]
  R.P. Fang, S.Y. Zhao, Z.H. Sun, et al., Adv. Mater. 29(2017) 1606823. doi: 10.1002/adma.201606823
5. [5]
  V. Strauss, K. Marsh, M.D. Kowal, M. EI-Kady, R.B. Kaner, Adv. Mater. 30(2018) 1704449. doi: 10.1002/adma.201704449
6. [6]
  L.B. Xing, J.L. Zhang, J. Zhang, et al., Electrochim. Acta 176(2015) 1288-1295. doi: 10.1016/j.electacta.2015.07.150
7. [7]
  L. Li, N. Zhang, M.Y. Zhang, et al., ACS Sustain. Chem. Eng. 6(2018) 7442-7450. doi: 10.1021/acssuschemeng.8b00047
8. [8]
  L.L. Liu, Z.Q. Niu, J. Chen, Chin. Chem. Lett. 29(2018) 571-581. doi: 10.1016/j.cclet.2018.01.013
9. [9]
  X.L. Xu, W.H. Shi, W.X. Liu, et al., J. Mater. Chem. A 6(2018) 24086. doi: 10.1039/C8TA06412A
10. [10]
  Z.Y. Song, D.Z. Zhu, L.C. Li, et al., J. Mater. Chem. A 7(2019) 1177-1186. doi: 10.1039/C8TA10158B
11. [11]
  L. Chen, D.P. Li, L.N. Chen, et al., Carbon 138(2018) 264-270. doi: 10.1016/j.carbon.2018.06.022
12. [12]
  S. Wang, Z.S. Wu, S.H. Zheng, et al., ACS Nano 11(2017) 4283-4291. doi: 10.1021/acsnano.7b01390
13. [13]
  P. Li, W.H. Shi, W.X. Liu, et al., Nanotechnology 29(2018) 445401. doi: 10.1088/1361-6528/aadad4
14. [14]
  J.Q. Qin, Z.S. Wu, F. Zhou, et al., Chin. Chem. Lett. 29(2018) 582-58658. doi: 10.1016/j.cclet.2017.08.007
15. [15]
  J.J. Yoo, K. Balakrishnan, J.S. Huang, Nano Lett. 11(2011) 1423-1142. doi: 10.1021/nl200225j
16. [16]
  Y. Wang, Y.Z. Zhang, D. Dubbink, et al., Nano Energy 49(2018) 481-488. doi: 10.1016/j.nanoen.2018.05.002
17. [17]
  N.R. Chodankar, D.P. Dubal, G.S. Gund, C.D. Lokhande, Electrochim. Acta 165(2015) 338-347. doi: 10.1016/j.electacta.2015.02.246
18. [18]
  M. Naguib, M. Kurtoglu, V. Presser, et al., Adv. Mater. 23(2011) 4248. doi: 10.1002/adma.201102306
19. [19]
  J.M. Luo, J.H. Zheng, J.W. Nai, et al., Adv. Funct. Mater. (2019) 1808107.
20. [20]
  H. Tang, W.L. Li, L.M. Pan, et al., Adv. Sci. (2018) 1800502.
21. [21]
  X.Y. Wang, Q.S. Fu, J. Wen, et al., Nanoscale 10(2018) 20828-20835. doi: 10.1039/C8NR06014B
22. [22]
  S.Y. Lin, X.T. Zhang, J. Power Sources 294(2015) 354-359. doi: 10.1016/j.jpowsour.2015.06.082
23. [23]
  L. Yu, L. Hu, B. Anasori, et al., ACS Energy Lett. 3(2018) 1597-1603. doi: 10.1021/acsenergylett.8b00718
24. [24]
  H.R. Wang, L. Li, C.C. Zhu, et al., J. Alloys Compd. 778(2019) 858-865. doi: 10.1016/j.jallcom.2018.11.172
25. [25]
  X.F. Zhang, Y. Liu, S.L. Dong, J.Q. Yang, X.D. Liu, Appl. Surf. Sci. 485(2019) 1-7. doi: 10.1016/j.apsusc.2019.04.197
26. [26]
  L.L. Jiang, Z. Fan, Nanoscale 6(2014) 1922-1945. doi: 10.1039/C3NR04555B
27. [27]
  L. Li, M.Y. Zhang, X.T. Zhang, Z.G. Zhang, J. Power Sources 364(2017) 234-241. doi: 10.1016/j.jpowsour.2017.08.029
28. [28]
  M.M. Hu, T. Hu, Z.J. Li, et al., ACS Nano 4(2018) 3578-3586.
29. [29]
  W.X. Liu, R.L. Yin, X.L. Xu, et al., Adv. Sci. 6(2019) 1802373. doi: 10.1002/advs.201802373
30. [30]
  F.F. Wu, X.B. Gao, X.L. Xu, et al., ChemSusChem 13(2020) 1537-1545. doi: 10.1002/cssc.201903006
31. [31]
  Q.S. Fu, J. Wen, N. Zhang, et al., RSC Adv. 7(2017) 11998-12005. doi: 10.1039/C7RA00126F
32. [32]
  W.H. Shi, J. Mao, X.L. Xu, et al., J. Mater. Chem. A 7(2019) 15654. doi: 10.1039/C9TA04900B
33. [33]
  A. Ramadoss, K.Y. Yoon, M.J. Kwak, et al., J. Power Sources 337(2017) 159-165. doi: 10.1016/j.jpowsour.2016.10.091
34. [34]
  H.H. Zhou, H.J. Zhi, G.Y. Han, et al., J.Mater. Sci.Mater. Electron.27(2016) 2773-2782. doi: 10.1007/s10854-015-4089-6
35. [35]
  C.F. Zhang, B. Anasori, A. Seral-Ascaso, et al., Adv. Mater. (2017) 1702678.
36. [36]
  C.Z. Wei, Q. Xu, Z.Q. Chen, et al., Carbohyd Polym. 169(2017) 50-57. doi: 10.1016/j.carbpol.2017.04.002
37. [37]
  L. Kou, T.Q. Huang, B.N. Zheng, et al., Nat. Commun. 5(2014) 3754. doi: 10.1038/ncomms4754
38. [38]
  Y.L. Shao, J.M. Li, A.G. Li, et al., Mater. Horiz. 4(2017) 1145-1150. doi: 10.1039/C7MH00441A
39. [39]
  L. Zhang, D.A. Derek, N.T. Alvarez, et al., Small (2017) 1603114.
1. [1]
  Lu Dai , Yuxin Ren , Shuang Li , Meidi Wang , Chentao Hu , Ya-Pan Wu , Guangtong Hai , Dong-Sheng Li . Room-temperature synthesis of Co(OH)₂/Mo₂TiC₂T_x hetero-nanosheets with interfacial coupling for enhanced oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(4): 109774-. doi: 10.1016/j.cclet.2024.109774
2. [2]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
3. [3]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
4. [4]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
5. [5]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
6. [6]
  Junqi Wang , Shuai Zhang , Jingjing Ma , Xiangjun Liu , Yayun Ma , Zhimin Fan , Jingfeng Wang . Augmenting levoglucosan production through catalytic pyrolysis of biomass exploiting Ti₃C₂T_x MXene. Chinese Chemical Letters, 2024, 35(12): 109725-. doi: 10.1016/j.cclet.2024.109725
7. [7]
  Yanqi Wu , Yuhong Guan , Peilin Huang , Hui Chen , Liping Bai , Zhihong Jiang . Preparation of norovirus GII loop mediated isothermal amplification freeze-drying microsphere reagents and its application in an on-site integrated rapid detection platform. Chinese Chemical Letters, 2024, 35(9): 109308-. doi: 10.1016/j.cclet.2023.109308
8. [8]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
9. [9]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
10. [10]
  Jindong Hao , Yufen Lv , Shuyue Tian , Chao Ma , Wenxiu Cui , Huilan Yue , Wei Wei , Dong Yi . Additive-free synthesis of β-keto phosphorodithioates via geminal hydro-phosphorodithiolation of sulfoxonium ylides with P₄S₁₀ and alcohols. Chinese Chemical Letters, 2024, 35(9): 109513-. doi: 10.1016/j.cclet.2024.109513
11. [11]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
12. [12]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
13. [13]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
14. [14]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
15. [15]
  Xinyu Huai , Jingxuan Liu , Xiang Wu . Cobalt-Doped NiMoO4 Nanosheet for High-performance Flexible Supercapacitor. Chinese Journal of Structural Chemistry, 2023, 42(10): 100158-100158. doi: 10.1016/j.cjsc.2023.100158
16. [16]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
17. [17]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
18. [18]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
19. [19]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
20. [20]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1217)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Additive-free porous assemblies of Ti3C2Tx by freeze-drying for high performance supercapacitors

Metrics

通讯作者: 陈斌, bchen63@163.com

Additive-free porous assemblies of Ti₃C₂T_x by freeze-drying for high performance supercapacitors