Citation: Sun Li, Wang Kai, Li Ningning, Zhang Jun, Guo Xiangxin, Liu Xianghong. Multilayered structure of N-carbonenvelopediron oxide/graphene nanocomposites as an improved anode for Li-ion battery[J]. Chinese Chemical Letters, ;2020, 31(9): 2333-2338. doi: 10.1016/j.cclet.2020.02.006 shu

Multilayered structure of N-carbonenvelopediron oxide/graphene nanocomposites as an improved anode for Li-ion battery

Sun Li ^a ,
Wang Kai ^a ,
Li Ningning ^a ,
Zhang Jun ^a,b ,
Guo Xiangxin ^a ,
Liu Xianghong ^a,b,*,

a.
College of Physics, Qingdao University, Qingdao 266071, China
b.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China

xianghong.liu@qdu.edu.cn

Received Date: 8 January 2020
Revised Date: 20 January 2020
Accepted Date: 1 February 2020
Available Online: 6 February 2020

Figures(4)

Transition metal oxides with high capacity are considered a promising electrode material for lithium-ion batteries (LIBs). Nevertheless, the huge volume expansion and poor conductivity severely hamper their practical application. In this work, a carbon riveting method is reported to address the above issues by designing multilayered N-doped carbon (N-carbon) enveloped Fe₃O₄/graphene nanosheets. When evaluated as a negative electrode, the N-carbon/Fe₃O₄/graphene nanocomposites demonstrate greatly enhanced electrochemical properties compared with Fe₃O₄/graphene. The N-carbon/Fe₃O₄/graphene presents a superior reversible capacity (807 mAh/g) over Fe₃O₄/graphene (540 mAh/g). Furthermore, it affords a considerable capacity of 550 mAh/g at 1 A/g over 700 cycles, indicating superb cycling stability. The structure-property correlation studies reveal that the carbon riveting layer is essential for enhancing the lithium diffusion kinetics. The good electrochemical properties and effective structure design make the carbon riveting strategy quite general and reliable to manipulate high performance electrodes for future LIBs.
- Fe₃O₄,
- Nanosheet,
- N-doped carbon,
- Anode,
- Lithium-ion batteries
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