Citation: Yingsong Xue, Zhixu Zhang, Pingping Shi, Wanying Zhang, Qiong Ye, Dawei Fu. High-temperature dielectric switch and second harmonic generation integrated in a stimulus responsive material[J]. Chinese Chemical Letters, ;2021, 32(1): 539-542. doi: 10.1016/j.cclet.2020.02.005 shu

High-temperature dielectric switch and second harmonic generation integrated in a stimulus responsive material

Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China

yeqiong@seu.edu.cn

dawei@seu.edu.cn

Received Date: 10 December 2019
Revised Date: 31 January 2020
Accepted Date: 5 February 2020
Available Online: 6 February 2020

Figures(4)

Stimulus responsive materials can provide a variety of desirable properties in one equipment unit, such as optoelectronic devices, data communications, actuators, memories, sensors and capacitors. However, it remains a large challenge to design such stimulus responsive materials, especially functional materials having both dielectric switch and second harmonic generation (SHG). Here, a new stimuli-responsive switchable material [(CH₃)₃N(CH₂)₂Cl]₂[Mn(SCN)₄(H₂O)₂] was discovered as a potential second-harmonic generation (SHG) dielectric switch. It is worth noting that it has SHG characteristics before and after undergoing reversible high-temperature phase transitions. In this work, we successfully refined the tetramethylammonium cation to obtain a quasi-spherical cation, which is tetramethylchloroethyl-amine (TMCEM) cation. By substituting H with a halogen, the increased steric hindrance of the molecular makes energy barrier increased, resulting in the reversible high-temperature phase transition. At the same time, the interactions of quasi-spherical cations and [Mn(SCN)₄(H₂O)₂]^2- anions affect a non-centrosymmetric structure to induce the SHG effect. These findings provide a new approach to design novel functional switch materials.
- Dielectric switch,
- Second harmonic generation,
- High-temperature,
- Phase transition,
- Stimulus responsive material
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