Citation: Song Dengmeng, Gao Xuyun, Li Bo, Li Jun, Sun Xuzhuo, Li Chengbo, Zhao Jiale, Chen Lin, Wang Ning. Synthesis, structure and electrocatalytic H₂-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases[J]. Chinese Chemical Letters, ;2020, 31(9): 2483-2486. doi: 10.1016/j.cclet.2020.01.033 shu

Synthesis, structure and electrocatalytic H₂-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases

Song Dengmeng ^a,1 ,
Gao Xuyun ^a,1 ,
Li Bo ^b ,
Li Jun ^a ,
Sun Xuzhuo ^b,*, ,
Li Chengbo ^a ,
Zhao Jiale ^a ,
Chen Lin ^c,*, ,
Wang Ning ^a,*,

a.
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China
b.
College of Chemistry, Chemical and Environmental Engineering, Henan University of Technology, Zhengzhou 450001, China
c.
State Key Laboratory of Environment-Friendly Energy Material, Southwest University of Science and Technology, Mianyang 621010, China

sunxuzhuo@haut.edu.cn

chenlin101101@aliyun.com

ningwang@nwu.edu.cn

Received Date: 24 December 2019
Revised Date: 13 January 2020
Accepted Date: 16 January 2020
Available Online: 16 January 2020

Figures(4)

Structural and functional biomimicking of the active site of [NiFe]-hydrogenases can provide helpful hints for designing bioinspired catalysts to replace the expensive noble metal catalysts for H₂ generation and uptake. Treatment of dianion [Ni(phma)]^2- [H₄phma = N, N'-1, 2-phenylenebis(2-mercaptoacetamide)] with [NiCl₂(dppp)] (dppp = bis(diphenylphosphino)propane) yielded a dinickel product [Ni(phma)(μ-S, S')Ni(dppp)] (1) as the model complex relevant to the active site of [NiFe]-H₂ases. The structure of complex 1 has been characterized by single-crystal X-ray analysis. From cyclic voltammetry and controlled potential electrolysis studies, complex 1 was found to be a moderate electrocatalyst for the H₂-evoluting reaction using ClCH₂COOH as the proton source.
- Hydrogenase,
- Electrocatalysis,
- Hydrogen evolution,
- Nickel complex,
- Metallothiolate ligand
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Synthesis, structure and electrocatalytic H2-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases

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通讯作者: 陈斌, bchen63@163.com

Synthesis, structure and electrocatalytic H₂-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases