Citation: Chen Fang, Yang Jiayu, Cai Rong, Qi Mengfei, Ma Xiaoyan. Novel, tadpole-shaped, polyhedral oligomeric silsesquioxane containing sulfonated block copolymer for humidity sensing[J]. Chinese Chemical Letters, ;2020, 31(8): 2119-2124. doi: 10.1016/j.cclet.2020.01.020 shu

Novel, tadpole-shaped, polyhedral oligomeric silsesquioxane containing sulfonated block copolymer for humidity sensing

The Key Laboratory of Polymer Science and Technology of Shaanxi Province, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710129, China

chenfang820811@nwpu.edu.cn

m_xiao_yana@nwpu.edu.cn

Received Date: 14 October 2019
Revised Date: 1 January 2020
Accepted Date: 2 January 2020
Available Online: 21 January 2020

Figures(7)

Due to the "trade-off" effect between the high water adsorption and low stability under high Relative Humidity of polymer matrix, fabrication of resistive-type polymer-based humidity sensors with a wide impedance response and excellent stability in high relative humidity remains a great challenge. Aim at solving that, a novel polymeric humidity sensing matrix, specifically a tadpole-shaped, polyhedral oligomeric silsesquioxane (POSS) containing block copolymers (BCPs) of POSS-poly(methyl methacrylate)-polystyrene (POSS-PMMA-SPS) were proposed. This novel BCP was synthesized using atom transfer radical polymerization (ATRP) employing a two-step approach, and following post sulfonation, a series of sulfonated BCPs (POSS-PMMA-SPS) with different sulfonation degree was obtained. The subject humidity sensors were produced using different sulfonated BCPs employing a dip-coating technique, and three wide-impedance response humidity sensors were produced. Each of these sensors exhibited an excellent humidity-sensing response of more than 104 within the humidity range from 11% to 95% RH. In particular, the humidity sensor S-6 that had a proper degree of sulfonation presented a relatively fast response (t_90% of 11 s and 80 s in both the water adsorption and desorption processes), and superior repeatability for more than 30 days.
- POSS containing block copolymer,
- Tadpole-shaped,
- Humidity sensor,
- Sulfonation degree,
- Wide impedance response
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