Citation: Shuangzhe Zhang, Haidong Li, Qichao Yao, Sahar Ghazali, Jiangli Fan, Jianjun Du, Jingyun Wang, Fengli Gao, Miao Li, Haibo Wang, Chengyong Dong, Xiaojun Peng. A unique two-photon fluorescent probe based on ICT mechanism for imaging palladium in living cells and mice[J]. Chinese Chemical Letters, ;2020, 31(11): 2913-2916. doi: 10.1016/j.cclet.2020.01.006 shu

A unique two-photon fluorescent probe based on ICT mechanism for imaging palladium in living cells and mice

Shuangzhe Zhang ^a ,
Haidong Li ^{a, b} ,
Qichao Yao ^a ,
Sahar Ghazali ^a ,
Jiangli Fan ^{a, d} ,
Jianjun Du ^{a, d} ,
Jingyun Wang ^c ,
Fengli Gao ^a ,
Miao Li ^a ,
Haibo Wang ^e ,
Chengyong Dong ^e ,
Xiaojun Peng ^{a, d, *,}

a.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
b.
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul 03760, Korea
c.
School of Life Science and Biotechnology, Dalian University of Technology, Dalian 116024, China
d.
Research Institute of Dalian University of Technology in Shenzhen, Shenzhen 518057, China
e.
Division of Hepatobiliary and Pancreatic Surgery, Department of General Surgery, The Second Affiliated Hospital of Dalian Medical University, Dalian 116000, China

pengxj@dlut.edu.cn

Received Date: 16 November 2019
Revised Date: 1 January 2020
Accepted Date: 3 January 2020
Available Online: 3 January 2020

Figures(6)

Palladium(0) as one of the vital transition metals, is employed in numerous industries, such as drug synthesis, aerospace high-tech field and automobile industry. When the Pd(0) enter into the body, it will bind with thiol-containing amino acids, DNA, RNA, and other biomolecules damaging to human health. Thus, developing a novel tool for monitoring and imaging of Pd(0) in vivo is very urgent. In the work, based on a intramolecular charge transfer (ICT) mechanism a two-photon fluorescent probe NIPd had been designed and synthesized for the recognition Pd(0). In vitro experiments data displayed that probe NIPd exhibited a 13-fold fluorescent increase for Pd(0) in 30 min in the aqueous solution with a detection limit of 16 nmol/L. It also showed the outstanding selectivity and antijamming performance. More importantly, NIPd could be served as a two-photon fluorescent probe for real-time monitoring Pd(0) in living cells and mice.
- Two-photon,
- Fluorescent probe,
- Imaging,
- Living cells,
- Palladium
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