Citation: Xu Bingqian, Jiang Wan, Wang Lianjun, Thokchom Binota, Qiu Pengpeng, Luo Wei. Yolk-shell structured Fe@void@mesoporous silica with high magnetization for activating peroxymonosulfate[J]. Chinese Chemical Letters, ;2020, 31(7): 2003-2006. doi: 10.1016/j.cclet.2019.12.035 shu

Yolk-shell structured Fe@void@mesoporous silica with high magnetization for activating peroxymonosulfate

Xu Bingqian ^a ,
Jiang Wan ^a ,
Wang Lianjun ^a ,
Thokchom Binota ^b ,
Qiu Pengpeng ^a,*, ,
Luo Wei ^a,*,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
b.
Indian Institute of Technology Guwahati, Guwahati 781039, India

qiupengpeng@dhu.edu.cn

wluo@dhu.edu.cn

Received Date: 20 November 2019
Revised Date: 19 December 2019
Accepted Date: 26 December 2019
Available Online: 26 December 2019

Figures(4)

Sulfate radical anion (SO₄^·-) based Fenton-like reaction have recently received a large quantity of attention owing to their strong oxidative capacity and high selectivity toward organic pollutants. However, the development of a high-efficient catalyst for activation of peroxymonosulfate (PMS) with a fast separation is still challengeable. Herein, magnetic mesoporous silica composites with a yolk-shell structure (Fe@void@mSiO₂) have been prepared via a successive coating strategy, followed by a hightemperature in-situ treatment and demonstrated as a high-efficient and fast magnetic separable catalyst for the activation of PMS. The resultant material possesses a well-defined yolk-shell structure with high specific surface area (~495.0 m²/g), uniform pore size (~6.9 nm) and super large magnetic susceptibility (~105 emu/g). Owing to the unique properties, the material possesses an excellent degradation activity for tetracyclines (TC), which is much higher than the commercialized Zero Valent Iron (ZVI) nanoparticles. Additionally, the catalyst is able to work over a broad pH range and be quickly recycled by using an external magnetic field. This research provides a promising strategy for the synthesis and design of multifunctional catalyst for the Fenton-like process.
- Yolk-shell,
- Magnetic mesoporous silica,
- Fenton-like process,
- PMS activation,
- Tetracyclines
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