Citation: Yuan Guoqiang, Yu Shangkui, Jie Ji, Wang Chen, Li Qing, Pang Huan. Cu/Cu₂O nanostructures derived from copper oxalate as high performance electrocatalyst for glucose oxidation[J]. Chinese Chemical Letters, ;2020, 31(7): 1941-1945. doi: 10.1016/j.cclet.2019.12.034 shu

Cu/Cu₂O nanostructures derived from copper oxalate as high performance electrocatalyst for glucose oxidation

Yuan Guoqiang ^a ,
Yu Shangkui ^a ,
Jie Ji ^a ,
Wang Chen ^a ,
Li Qing ^a,b,**, ,
Pang Huan ^b,*,

a.
Guangling College, Yangzhou University, Yangzhou 225009, China
b.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

^**

lq87852976@126.com

huanpangchem@hotmail.com

panghuan@yzu.edu.cn

Received Date: 26 November 2019
Revised Date: 23 December 2019
Accepted Date: 25 December 2019
Available Online: 26 December 2019

Figures(4)

Porous nanomaterials are classified as a kind of materials with great potential for development in the field of electrocatalysis, but there is still room for further improvement as catalysts. We develop a threedimensional (3D) porous structure of Cu/Cu₂O as an electrocatalyst for the glucose oxidation reaction (GOR) using the method of calcining the precursor CuC₂O₄·2H₂O in N₂. The obtained porous Cu/Cu₂O nanostructure can provide more opportunities for effective reactions between particles, which can explain their efficient electrocatalytic performance. Additionally, the as-synthesized Cu/Cu₂O nanostructure exhibits outstanding electrocatalytic performance for the glucose, including good stability, excellent sensitivity and remarkable selectivity.
- Copper oxalate,
- Cu/Cu₂O,
- Electrocatalysis,
- Glucose,
- Porous
1. [1]
  Y. Hao, Y. Xu, W. Liu, X. Sun, Mater. Horizons 5(2018) 108-115. doi: 10.1039/C7MH00706J
2. [2]
  X. Lan, N. Huang, J. Wang, T. Wang, Chem. Commun. 54(2018) 584-587. doi: 10.1039/C7CC08244D
3. [3]
  D.H. Nam, O.S. Bushuyev, J. Li, et al., J. Am. Chem. Soc. 140(2018) 11378-11386. doi: 10.1021/jacs.8b06407
4. [4]
  C.S. Liu, Z.H. Zhang, M. Chen, et al., Chem. Commun. 53(2017) 3941-3944. doi: 10.1039/C7CC00029D
5. [5]
  X. Li, J. Wei, Q. Li, et al., Adv. Funct. Mater. 28(2018) 1800886. doi: 10.1002/adfm.201800886
6. [6]
  B. Li, B.M. Zheng, G.H. Xue, H. Pang, Inorg. Chem. Front. 3(2016) 175-202. doi: 10.1039/C5QI00187K
7. [7]
  J. Yang, F. Zhang, H. Lu, et al., Angew. Chem. Int. Ed. 54(2015) 10889-10893. doi: 10.1002/anie.201504242
8. [8]
  D.M. Chen, J.Y. Tian, Z.W. Wang, et al., Chem. Commun. 53(2017) 10668-10671. doi: 10.1039/C7CC06073D
9. [9]
  Y. Xu, B. Li, S. Zheng, et al., J. Mater. Chem. A (2018) 22070-22076.
10. [10]
  B.M. Zheng, L.L. Li, P. Gu, et al., Microchim. Acta 184(2017) 943-949. doi: 10.1007/s00604-017-2079-5
11. [11]
  Y. Sun, Y. Li, N. Wang, et al., Electroanalysis 30(2018) 474-478. doi: 10.1002/elan.201700629
12. [12]
  N. Li, Q. Li, M. Yuan, et al., Chem. Asian J. 14(2019) 2259-2265. doi: 10.1002/asia.201900361
13. [13]
  T. Adachi, S. Tsujimura, Electrochim. Acta 313(2019) 189-193. doi: 10.1016/j.electacta.2019.04.145
14. [14]
  C. Lu, Z. Li, L. Ren, et al., Sensors 19(2019) 2926. doi: 10.3390/s19132926
15. [15]
  A. Khoobi, M. Salavati-Niasari, Energy 178(2019) 50-56. doi: 10.1016/j.energy.2019.04.143
16. [16]
  J. Hao, C. Li, C. Wu, K. Wu, Carbon 148(2019) 44-51. doi: 10.1016/j.carbon.2019.03.048
17. [17]
  Y. Zhuge, G. Fan, Y. Lin, L. Yang, F. Li, Dalton Trans. 48(2019) 9161-9172. doi: 10.1039/C9DT00985J
18. [18]
  D. Zhu, C. Xia, Z. Yang, et al., Mater. Lett. 245(2019) 49-52. doi: 10.1016/j.matlet.2019.02.095
19. [19]
  L. Li, Y. Liu, L. Ai, J. Jiang, J. Ind. Eng. Chem. 70(2019) 330-337. doi: 10.1016/j.jiec.2018.10.033
20. [20]
  D. Shi, R. Zheng, M.J. Sun, et al., Angew. Chem. Int. Ed. 56(2017) 14637-14641. doi: 10.1002/anie.201709869
21. [21]
  G. Liu, X. Li, Z. Yu, et al., J. Phys. Chem. Solids 123(2018) 344-354. doi: 10.1016/j.jpcs.2018.08.025
22. [22]
  G. Zang, W. Hao, X. Li, et al., Electrochim. Acta 277(2018) 176-184. doi: 10.1016/j.electacta.2018.05.016
23. [23]
  W. Xu, J. Lu, W. Huo, et al., Nanoscale 10(2018) 14304-14313. doi: 10.1039/C8NR04519D
24. [24]
  M. Zhang, C. Wang, C. Liu, et al., J. Mater. Chem. A 6(2018) 11226-11235. doi: 10.1039/C8TA03565B
25. [25]
  Z. Ai, L. Zhang, S. Lee, W. Ho, J. Phys. Chem. C 113(2009) 20896-20902. doi: 10.1021/jp9083647
26. [26]
  L. Martin, H. Martinez, D. Poinot, B. Pecquenard, F. Le Cras, J. Phys. Chem. C 117(2013) 4421-4443. doi: 10.1021/jp3119633
1. [1]
  Ming Yue , Yi-Rong Wang , Jia-Yong Weng , Jia-Li Zhang , Da-Yu Chi , Mingjin Shi , Xiao-Gang Hu , Yifa Chen , Shun-Li Li , Ya-Qian Lan . Multi-metal porous crystalline materials for electrocatalysis applications. Chinese Chemical Letters, 2025, 36(6): 110049-. doi: 10.1016/j.cclet.2024.110049
2. [2]
  Shanru Feng , Ling Wen , Li Zhang , Qinyu Jiang , Bozhao Zhang , Guohao Wu , Yue Wu , Jiabin Chen , Youcai Han , Chuhao Liu , Yu-Wu Zhong , Jiannian Yao . Magnetic field controlled electrocatalysis from a multidimensional catalytic perspective: Mechanisms, applications, and prospects for energy conversion. Chinese Journal of Structural Chemistry, 2025, 44(11): 100662-100662. doi: 10.1016/j.cjsc.2025.100662
3. [3]
  Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
4. [4]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
5. [5]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
6. [6]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
7. [7]
  Sumiya Akter Dristy , Md Ahasan Habib , Mehedi Hasan Joni , Md Najibullah , Rutuja Mandavkar , Shusen Lin , Jihoon Lee . Binder-free bimetallic vanadium-nickel-boride-phosphide spherical structure for highly efficient and stable industrial-level water splitting. Chinese Journal of Structural Chemistry, 2025, 44(12): 100747-100747. doi: 10.1016/j.cjsc.2025.100747
8. [8]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
9. [9]
  Hong-Rui Li , Xia Kang , Rui Gao , Miao-Miao Shi , Bo Bi , Ze-Yu Chen , Jun-Min Yan . Interfacial interactions of Cu/MnOOH enhance ammonia synthesis from electrochemical nitrate reduction. Chinese Chemical Letters, 2025, 36(2): 109958-. doi: 10.1016/j.cclet.2024.109958
10. [10]
  Fangbing Wang , Qiankun Zeng , Jing Ren , Min Zhang , Guoyue Shi . A membrane-based plasma separator coupled with ratiometric fluorescent sensor for biochemical analysis in whole blood. Chinese Chemical Letters, 2025, 36(7): 110494-. doi: 10.1016/j.cclet.2024.110494
11. [11]
  Anni Wu , Chengyi Hong , Hu Zheng , Wei Teng . Multi-site synergistic relay electrocatalysis with high-entropy nanoalloys for effective nitrate reduction to ammonia. Chinese Chemical Letters, 2025, 36(12): 111066-. doi: 10.1016/j.cclet.2025.111066
12. [12]
  Lin Zhang , Jianlong Li , Maoyuan Hu , Yao Xu , Xiaoli Xiong , Zhaoyu Jin . MOF-derived beaded stream-like nitrogen and phosphorus-codoped carbon-coated Fe₃O₄ nanocomposites via lattice-oxygen-mediated mechanism for efficient water oxidation. Chinese Chemical Letters, 2025, 36(8): 111123-. doi: 10.1016/j.cclet.2025.111123
13. [13]
  Yue Zhang , Xiaoya Fan , Xun He , Tingyu Yan , Yongchao Yao , Dongdong Zheng , Jingxiang Zhao , Qinghai Cai , Qian Liu , Luming Li , Wei Chu , Shengjun Sun , Xuping Sun . Ambient electrosynthesis of urea from carbon dioxide and nitrate over Mo₂C nanosheet. Chinese Chemical Letters, 2024, 35(8): 109806-. doi: 10.1016/j.cclet.2024.109806
14. [14]
  Ting Xie , Xun He , Lang He , Kai Dong , Yongchao Yao , Zhengwei Cai , Xuwei Liu , Xiaoya Fan , Tengyue Li , Dongdong Zheng , Shengjun Sun , Luming Li , Wei Chu , Asmaa Farouk , Mohamed S. Hamdy , Chenggang Xu , Qingquan Kong , Xuping Sun . CoSe₂ nanowire array enabled highly efficient electrocatalytic reduction of nitrate for ammonia synthesis. Chinese Chemical Letters, 2024, 35(11): 110005-. doi: 10.1016/j.cclet.2024.110005
15. [15]
  Chenhao Zhang , Qian Zhang , Yezhou Hu , Hanyu Hu , Junhao Yang , Chang Yang , Ye Zhu , Zhengkai Tu , Deli Wang . N-doped carbon confined ternary Pt₂NiCo intermetallics for efficient oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(3): 110429-. doi: 10.1016/j.cclet.2024.110429
16. [16]
  Xinyu Hou , Xuelian Yu , Meng Liu , Hengxing Peng , Lijuan Wu , Libing Liao , Guocheng Lv . Ultrafast synthesis of Mo₂N with highly dispersed Ru for efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2025, 36(4): 109845-. doi: 10.1016/j.cclet.2024.109845
17. [17]
  Qi Zhang , Bin Han , Yucheng Jin , Mingrun Li , Enhui Zhang , Jianzhuang Jiang . 2D and 3D phthalocyanine covalent organic frameworks for electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2025, 36(9): 110330-. doi: 10.1016/j.cclet.2024.110330
18. [18]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
19. [19]
  Kezhen Qi , Zhidong Wei , Haibin Wang , Hongyan Liang , Dandan Ma , Jian-Wen Shi , Yifeng Li , Xuepeng Xiang , Yan Chen , Bo Yu , Chunchun Wang , Zhuo Xing , Claudio Imparato , Aurelio Bifulco , Daniil A. Lukyanov , Elena V. Alekseeva , Oleg V. Levin , M.I. Chebanenko , V.I. Popkov , Tan Zhang , Jinping Li , Guang Liu , Wei Li , Linlin Song , Rongzheng Ren , Zhenhua Wang , Jianmin Ma . Gas-involved photo- and electro-catalysis roadmap towards 2030. Chinese Chemical Letters, 2026, 37(1): 111661-. doi: 10.1016/j.cclet.2025.111661
20. [20]
  Shengkai Li , Yuqin Zou , Chen Chen , Shuangyin Wang , Zhao-Qing Liu . Defect engineered electrocatalysts for C–N coupling reactions toward urea synthesis. Chinese Chemical Letters, 2024, 35(8): 109147-. doi: 10.1016/j.cclet.2023.109147

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1993)
HTML views(175)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cu/Cu2O nanostructures derived from copper oxalate as high performance electrocatalyst for glucose oxidation

Metrics

通讯作者: 陈斌, bchen63@163.com

Cu/Cu₂O nanostructures derived from copper oxalate as high performance electrocatalyst for glucose oxidation