Citation: He Shuaiqi, Chen Xiaolan, Zeng Fanlin, Lu Peipei, Peng Yuyu, Qu Lingbo, Yu Bing. Visible-light-promoted oxidative decarboxylation of arylacetic acids in air: Metal-free synthesis of aldehydes and ketones at room temperature[J]. Chinese Chemical Letters, ;2020, 31(7): 1863-1867. doi: 10.1016/j.cclet.2019.12.031 shu

Visible-light-promoted oxidative decarboxylation of arylacetic acids in air: Metal-free synthesis of aldehydes and ketones at room temperature

He Shuaiqi ^a ,
Chen Xiaolan ^a,*, ,
Zeng Fanlin ^a ,
Lu Peipei ^a ,
Peng Yuyu ^c ,
Qu Lingbo ^a ,
Yu Bing ^a,b,*,

a.
College of Chemistry, Zhengzhou University, Zhengzhou 450001 China
b.
Henan Nonferrous Metals Geological Exploration Institute, Zhengzhou 450052, China
c.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China

chenxl@zzu.edu.cn

bingyu@zzu.edu.cn

Received Date: 7 November 2019
Revised Date: 15 December 2019
Accepted Date: 24 December 2019
Available Online: 24 December 2019

Figures(5)

A metal-free photocatalytic oxidative decarboxylation reaction at room temperature was developed for the synthesis of aromatic aldehydes and ketones from the corresponding arylacetic acids. The reaction was realized under blue-light irradiation by adding 1 mol% of 4CzIPN as photocatalyst and air as oxidant. This reaction represents a novel decarboxylation of a sp³-hybridized carboxylic acids without traditional heating, additional oxidants, and metal reagents under mild conditions.
- Decarboxylation,
- Metal-free,
- Photocatalysis,
- 4CzIPN,
- Arylacetic acids
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