Citation: Su Kongzhao, Du Shunfu, Wang Wenjing, Yuan Daqiang. Control of random self-assembly of pyrogallol[4] arene-based nanocapsule or framework[J]. Chinese Chemical Letters, ;2020, 31(7): 2023-2026. doi: 10.1016/j.cclet.2019.11.047 shu

Control of random self-assembly of pyrogallol[4] arene-based nanocapsule or framework

Su Kongzhao ^a,b ,
Du Shunfu ^a,c ,
Wang Wenjing ^a,b ,
Yuan Daqiang ^a,b,*,

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of the Chinese Academy of Sciences, Beijing 100049, China
c.
College of Chemistry, Fuzhou University, Fuzhou 350116, China

ydq@fjirsm.ac.cn

Received Date: 25 October 2019
Revised Date: 26 November 2019
Accepted Date: 28 November 2019
Available Online: 29 November 2019

Figures(5)

The controlled self-assembly of discrete metal-organic nanocapsules (MONCs), and metal-organic frameworks (MOFs) based on the MONCs are achieved. Specifically, the solvothermal reaction of nickel nitrate hexahydrate and C-methylpyrogallol[4]arene in mixed DMF/MeOH solution leads to the unexpected form of discrete nickel-seamed hexameric pyrogallol[4]arene MONCs, and MONC-based three-dimensional (3D) MOF. Notably, the latter MOF is constructed from the aforementioned nickelseamed MONC building blocks and formate linkers in-situ generated from the hydrolysis of DMF solvent. Interestingly, introducing pyridine and formic acid in the reaction conditions leads to the controlled assemblies of the discrete MONC and MONC-based 3D MOF structures. Moreover, the variabletemperature magnetic susceptibilities of both the abovementioned compounds have been investigated, indicating typical antiferromagnetic interactions between the metal centers.
- Controlled assembly,
- Pyrogallol[4]arene,
- Metal-organic nanocapsule,
- Metal-organic framework,
- Magnetism
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