Citation: Yang Juan, Xu Dan, Hou Ruilin, Lang Junwei, Wang Zhaoli, Dong Zhengping, Ma Jiantai. Nitrogen-doped carbon nanotubes by multistep pyrolysis process as a promising anode material for lithium ion hybrid capacitors[J]. Chinese Chemical Letters, ;2020, 31(9): 2239-2244. doi: 10.1016/j.cclet.2019.11.044 shu

Nitrogen-doped carbon nanotubes by multistep pyrolysis process as a promising anode material for lithium ion hybrid capacitors

Yang Juan ^a,b ,
Xu Dan ^a ,
Hou Ruilin ^b ,
Lang Junwei ^b ,
Wang Zhaoli ^c ,
Dong Zhengping ^a ,
Ma Jiantai ^a,*,

a.
College of Chemistry and Chemical Engineering, Gansu Provincial Engineering Laboratory for Chemical Catalysis, Laboratory of Special Function Materials and Structure Design of the Ministry of Education, Lanzhou University, Lanzhou 730000, China
b.
Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
c.
College of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China

majiantai@lzu.edu.cn

Received Date: 23 October 2019
Revised Date: 19 November 2019
Accepted Date: 20 November 2019
Available Online: 29 November 2019

Figures(5)

Lithium-ion hybrid capacitors (LIHCs) is a promising electrochemical energy storage devices which combines the advantages of lithium-ion batteries and capacitors. Herein, we developed a facile multistep pyrolysis method, prepared an amorphous structure and a high-level N-doping carbon nanotubes (NCNTs), and by removing the Co catalyst, opening the port of NCNTs, and using NCNTs as anode material. It is shows good performance due to the electrolyte ions enter into the electrode materials and facilitate the charge transfer. Furthermore, we employ the porous carbon material (APDC) as the cathode to couple with anodes of NCNTs, building a LIHCs, it shows a high energy density of 173 Wh/kg at 200 W/kg and still retains 53 Wh/kg at a high power density of 10 kW/kg within the voltage window of 0-4.0 V, as well as outstanding cyclic life keep 80% capacity after 5000 cycles. This work provides an opportunity for the preparation of NCNTs, that is as a promising high-performance anode for LIHCs.
- N-doping carbon nanotubes,
- Multistep pyrolysis,
- Anode,
- Porous carbon,
- Lithium ion hybrid capacitors
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