Citation: Liu Shuang, Zhou Meng, Ma Ting, Liu Jian, Zhang Qiu, Tao Zhanliang, Liang Jing. A symmetric aqueous redox flow battery based on viologen derivative[J]. Chinese Chemical Letters, ;2020, 31(6): 1690-1693. doi: 10.1016/j.cclet.2019.11.033 shu

A symmetric aqueous redox flow battery based on viologen derivative

Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

liangjing@nankai.edu.cn

lianggrace2001@163.com

Received Date: 24 September 2019
Revised Date: 13 November 2019
Accepted Date: 19 November 2019
Available Online: 21 November 2019

Figures(4)

Due to the diversity and feasibility of structural modification for organic molecules, organic-based redox flow batteries (ORFBs) have been widely investigated, especially in aqueous solution under neutral circumstance. In this work, a symmetric aqueous redox flow battery (SARFB) was rationally designed by employing a bipolar redox active molecule (N, N'-dimethyl-4, 4-bipyridinium diiodide, MVI₂) as both cathode and anode materials and combining with an anion exchange membrane. For one MVI₂ flow battery, MV²⁺/MV^·+ and I^-/I₃^- serve as the redox couples of anode and cathode, respectively. The MVI₂ battery with a working voltage of 1.02 V exhibited a high voltage efficiency of 90.30% and energy efficiency of 89.44% after 450 cycles, and crossover problem was prohibited. The comparable conductivity of MVI₂ water solution enabled to construct a battery even without using supporting electrolyte. Besides, the bipolar character of MVI₂ battery with/without supporting electrolyte was investigated in the voltage range between -1.2 V and 1.2 V, showing excellent stable cycling stability during the polarity-reversal test.
- Aqueous redox flow battery,
- Bipolar redox active molecule,
- Symmetric redox flow battery,
- MVI₂,
- Prohibited crossover problem,
- High coulombic efficiency
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