Citation: Ni Jiawei, Zhao Tao, Tang Lei, Qiu Pengpeng, Jiang Wan, Wang Lianjun, Xu Pengcheng, Luo Wei. Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H₂S detection[J]. Chinese Chemical Letters, ;2020, 31(6): 1680-1685. doi: 10.1016/j.cclet.2019.11.025 shu

Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H₂S detection

Ni Jiawei ^a,1 ,
Zhao Tao ^a,1 ,
Tang Lei ^b,c ,
Qiu Pengpeng ^a ,
Jiang Wan ^a ,
Wang Lianjun ^a ,
Xu Pengcheng ^b,d,**, ,
Luo Wei ^a,*,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Institute of Functional Materials, Donghua University, Shanghai 201620, China
b.
State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
c.
College of Life and Environmental Sciences, Shanghai Normal University, Shanghai 200234, China
d.
University of Chinese Academy of Sciences, Beijing 100049, China

^**

xpc@mail.sim.ac.cn

wluo@dhu.edu.cn

Received Date: 2 October 2019
Revised Date: 6 November 2019
Accepted Date: 15 November 2019
Available Online: 16 November 2019

Figures(4)

H₂S can cause multiple diseases and poses a great threat to human health. However, the precise detection of extremely toxic H₂S at room temperature is still a great challenge. Here, a facile solvent evaporation induced aggregating assembly (EIAA) method has been applied for the production of ordered mesoporous carbon (OMCs) in an acidic THF/H₂O solution with high-molecular-weight poly(ethylene oxide)-b-polystyrene (PEO-b-PS) copolymers as the structure-directing agent, formaldehyde and resorcinol as carbon precursors. Along with the continuous evaporation of THF from the mixed solution, cylindrical micelles are formed in the solution and further assemble into highly ordered mesostructure. The obtained OMCs possesses a two-dimensional (2D) hexagonal mesostructure with uniform and large pore diameter (~19.2 nm), high surface area (599 m²/g), and large pore volume (0.92 cm₃/g). When being used as the resonant cantilever gas sensor for room-temperature H₂S detection, the OMCs has delivered not only a superior gas sensing performance with ultrafast response (14 s) and recovery (21 s) even at low concentration (2 ppm) but also an excellent selectivity toward H₂S among various common interfering gases. Moreover, the limit of detection is better than 0.2 ppm, indicating its potential application in environmental monitoring and health protection.
- Mesoporous materials,
- Carbon,
- Self-assembly,
- Resonant cantilever gas sensor,
- H₂S
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沈阳化工大学材料科学与工程学院沈阳 110142

Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H2S detection

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通讯作者: 陈斌, bchen63@163.com

Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H₂S detection