Citation: Ni Jiawei, Zhao Tao, Tang Lei, Qiu Pengpeng, Jiang Wan, Wang Lianjun, Xu Pengcheng, Luo Wei. Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H₂S detection[J]. Chinese Chemical Letters, ;2020, 31(6): 1680-1685. doi: 10.1016/j.cclet.2019.11.025 shu

Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H₂S detection

Ni Jiawei ^a,1 ,
Zhao Tao ^a,1 ,
Tang Lei ^b,c ,
Qiu Pengpeng ^a ,
Jiang Wan ^a ,
Wang Lianjun ^a ,
Xu Pengcheng ^b,d,**, ,
Luo Wei ^a,*,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Institute of Functional Materials, Donghua University, Shanghai 201620, China
b.
State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
c.
College of Life and Environmental Sciences, Shanghai Normal University, Shanghai 200234, China
d.
University of Chinese Academy of Sciences, Beijing 100049, China

^**

xpc@mail.sim.ac.cn

wluo@dhu.edu.cn

Received Date: 2 October 2019
Revised Date: 6 November 2019
Accepted Date: 15 November 2019
Available Online: 16 November 2019

Figures(4)

H₂S can cause multiple diseases and poses a great threat to human health. However, the precise detection of extremely toxic H₂S at room temperature is still a great challenge. Here, a facile solvent evaporation induced aggregating assembly (EIAA) method has been applied for the production of ordered mesoporous carbon (OMCs) in an acidic THF/H₂O solution with high-molecular-weight poly(ethylene oxide)-b-polystyrene (PEO-b-PS) copolymers as the structure-directing agent, formaldehyde and resorcinol as carbon precursors. Along with the continuous evaporation of THF from the mixed solution, cylindrical micelles are formed in the solution and further assemble into highly ordered mesostructure. The obtained OMCs possesses a two-dimensional (2D) hexagonal mesostructure with uniform and large pore diameter (~19.2 nm), high surface area (599 m²/g), and large pore volume (0.92 cm₃/g). When being used as the resonant cantilever gas sensor for room-temperature H₂S detection, the OMCs has delivered not only a superior gas sensing performance with ultrafast response (14 s) and recovery (21 s) even at low concentration (2 ppm) but also an excellent selectivity toward H₂S among various common interfering gases. Moreover, the limit of detection is better than 0.2 ppm, indicating its potential application in environmental monitoring and health protection.
- Mesoporous materials,
- Carbon,
- Self-assembly,
- Resonant cantilever gas sensor,
- H₂S
1. [1]
  Y.H. Li, W. Luo, N. Qin, et al., Angew. Chem. Int. Ed. 53(2014) 9035-9040. doi: 10.1002/anie.201403817
2. [2]
  A. Mirzaei, S.S. Kim, H.W. Kim, et al., J. Hazard. Mater. 357(2018) 314-331. doi: 10.1016/j.jhazmat.2018.06.015
3. [3]
  S. Moon, N.M. Vuong, Lee D, et al., Sens. Actuator. B:Chem. 222(2016) 166-172. doi: 10.1016/j.snb.2015.08.072
4. [4]
  H. Tajizadegan, M. Rashidzadeh, M. Jafari, et al., Chin. Chem. Lett. 24(2013) 167-169. doi: 10.1016/j.cclet.2013.01.027
5. [5]
  M.A.H. Khan, M.V. Rao, Q. Li, et al., Sensors 19(2019) 905. doi: 10.3390/s19040905
6. [6]
  J. Zhang, R. Sokolovvskij, G.H. Chen, et al., Sens. Actuator. B:Chem. 280(2019) 138-143. doi: 10.1016/j.snb.2018.10.052
7. [7]
  H.R. Zhang, L.Y. Niu, Y.Z. Chen, et al., Chin. Chem. Lett. 27(2016) 1793-1796. doi: 10.1016/j.cclet.2016.04.023
8. [8]
  Y.H. Li, X.R. Zhou, W. Luo, et al., Adv. Mater. Interfaces 6(2019) 1801269. doi: 10.1002/admi.201801269
9. [9]
  W.C. Wang, F.Q. Liu, B. Wang, et al., Chin. Chem. Lett. 30(2018) 1261-1265.
10. [10]
  X.R. Zhou, X.W. Cheng, Y.H. Zhu, et al., Chin. Chem. Lett. 29(2018) 405-416. doi: 10.1016/j.cclet.2017.06.021
11. [11]
  Y.H. Zhu, Y. Zhao, J.H. Ma, et al., J. Am. Chem. Soc. 139(2017) 10365-10373. doi: 10.1021/jacs.7b04221
12. [12]
  X.Y. Xiao, X.R. Zhou, J.H. Ma, et al., ACS Appl. Mater. Interfaces 11(2019) 26268-26276. doi: 10.1021/acsami.9b08128
13. [13]
  G. Wang, J. Qin, X.R. Zhou, et al., Adv. Funct. Mater. 28(2018) 1806144. doi: 10.1002/adfm.201806144
14. [14]
  J.H. Hao, Y. Ren, X.R. Zhou, et al., Adv. Funct. Mater. 28(2018) 1705268. doi: 10.1002/adfm.201705268
15. [15]
  Y. Ren, X.R. Zhou, W. Luo, et al., Chem. Mater. 28(2016) 7997-8005. doi: 10.1021/acs.chemmater.6b03733
16. [16]
  Y. Zhang, Y.Y. Fu, D.F. Zhu, et al., Chin. Chem. Lett. 27(2016) 1429-1436. doi: 10.1016/j.cclet.2016.05.019
17. [17]
  J.Q. Xu, Z.G. Xue, N. Qin, et al., Sens. Actuator B:Chem. 242(2017) 148-157. doi: 10.1016/j.snb.2016.09.193
18. [18]
  F.I.M. Ali, F. Awwad, Y.E. Greish, et al., IEEE Sens. J. 19(2019) 2394-2407. doi: 10.1109/JSEN.2018.2886131
19. [19]
  C. Li, Z.S. Yu, S.M. Fang, et al., Chin. Chem. Lett. 19(2008) 599-603. doi: 10.1016/j.cclet.2008.03.032
20. [20]
  Z.R. Wang, Y.H. Zhu, W. Luo, et al., Chem. Mater. 28(2016) 7773-7780.
21. [21]
  Y.D. Zou, X.R. Zhou, Y.H. Zhu, et al., Acc. Chem. Res. 52(2019) 714-725. doi: 10.1021/acs.accounts.8b00598
22. [22]
  Y. Ren, X.Y. Yang, X.R. Zhou, et al., Chin. Chem. Lett. 30(2019) 2003-2008. doi: 10.1016/j.cclet.2019.01.019
23. [23]
  Z.J. Li, H. Li, Z.L. Wu, et al., Mater. Horiz. 6(2019) 470-506.
24. [24]
  Y.Q. Lv, H.T. Yu, P.C. Xu, et al., Sens. Actuator. B:Chem. 256(2017) 639-647.
25. [25]
  T. Xu, P.C. Xu, D. Zheng, et al., Anal. Chem. 88(2016) 12234-12240. doi: 10.1021/acs.analchem.6b03364
26. [26]
  I. Dufour, S.M. Heinrich, F. Josse, Proc. 2004 IEEE Intern. 16(2007) 44-49.
27. [27]
  S.B. Guo, P.C. Xu, H.T. Yu, et al., Sens. Actuator B:Chem. 209(2015) 943-950. doi: 10.1016/j.snb.2014.12.077
28. [28]
  S.R. Cai, W. Li, P.C. Xu, et al., Analyst 144(2019) 3729-3735. doi: 10.1039/C8AN02508H
29. [29]
  L. Peng, C.T. Hung, S.W. Wang, et al., J. Am. Chem. Soc. 141(2019) 7073-7080. doi: 10.1021/jacs.9b02091
30. [30]
  J. Zhang, J. Wang, Z.Q. Shi, et al., Chin. Chem. Lett. 29(2018) 80-83.
31. [31]
  H.B. Zhang, P.F. An, W. Zhou, et al., Sci. Adv. 4 (2018) eaao6657.
32. [32]
  F.L. Meng, Z.L. Wang, H.X. Zhong, et al., Adv. Mater. 28(2016) 7948-7955. doi: 10.1002/adma.201602490
33. [33]
  H.W. Zhang, O. Noonan, X.D. Huang, et al., ACS Nano 10(2016) 4579-4586. doi: 10.1021/acsnano.6b00723
34. [34]
  W.H. Li, Z.Z. Yang, M. Li, et al., Nano Lett. 16(2016) 1546-1553. doi: 10.1021/acs.nanolett.5b03903
35. [35]
  J. Tang, J. Liu, C.L. Li, et al., Angew. Chem. Int. Ed. 54(2015) 588-593. doi: 10.1002/anie.201407629
36. [36]
  Z.Y. Guo, D.D. Zhou, X.L. Dong, et al., Adv. Mater. 25(2013) 5668. doi: 10.1002/adma.201302459
37. [37]
  J.Schuster, G.He, B.Mandlmeier, etal., Angew.Chem.Int.Ed.51(2012)3591-3595. doi: 10.1002/anie.201107817
38. [38]
  B.K. Guo, X.Q. Wang, P.F. Lulvio, et al., Adv. Mater. 23(2011) 4661. doi: 10.1002/adma.201102032
39. [39]
  Q. Shi, R.Y. Zhang, Y.Y. Lu, et al., Carbon 84(2015) 335-346. doi: 10.1016/j.carbon.2014.12.013
40. [40]
  Y. Fang, Y.Y. Lv, F. Gong, et al., Adv. Mater. 28(2016) 9385. doi: 10.1002/adma.201602210
41. [41]
  R.L. Liu, L. Wan, S.Q. Liu, et al., Adv. Funct. Mater. 25(2015) 526-533. doi: 10.1002/adfm.201403280
42. [42]
  S. Li, C. Cheng, A. Sagaltchik, et al., Adv. Funct. Mater. 29(2019) 1807419. doi: 10.1002/adfm.201807419
43. [43]
  M. Zhang, L. He, T. Shi, et al., Chem. Mater. 30(2018) 7391-7412. doi: 10.1021/acs.chemmater.8b03345
44. [44]
  Y. Liu, Z.R. Wang, W. Teng, et al., J. Mater. Chem. A 6(2018) 3162-3170. doi: 10.1039/C7TA10106F
45. [45]
  H. Xie, Y.J. Zhao, Y. Tian, et al., Carbon 152(2019) 295-304. doi: 10.1016/j.carbon.2019.06.029
46. [46]
  Y. Deng, A.F. Xu, W.T. Wu, et al., New J. Chem. 42(2018) 7043-7048. doi: 10.1039/C7NJ03923A
47. [47]
  W.J. Gao, Y. Wan, Y.Q. Dou, et al., Adv. Energy Mater. 1(2011) 115-123. doi: 10.1002/aenm.201000009
48. [48]
  L.N. Han, X. Wei, Q.C. Zhu, et al., J. Mater. Chem. A 4(2016) 16698-1605. doi: 10.1039/C6TA05607E
49. [49]
  C. Gunathilake, R.S. Dassanayake, N. Abidi, et al., J. Mater. Chem. A 4(2016) 4808-4819. doi: 10.1039/C6TA00261G
50. [50]
  Z.F. Tian, M.J. Xie, Y. Shen, et al., Chin. Chem. Lett. 28(2017) 863-867. doi: 10.1016/j.cclet.2016.12.004
51. [51]
  W. Luo, Y.H. Li, J. Dong, et al., Angew. Chem. Int. Ed. 125(2013) 10699-10704. doi: 10.1002/ange.201303353
52. [52]
  Y.H. Deng, T. Yu, Y. Wan, et al., J. Am. Chem. Soc. 129(2007) 1690-1697. doi: 10.1021/ja067379v
53. [53]
  L. Yin, H.B. Wang, L. Li, et al., Appl. Surf. Sci. 476(2019) 107-114.
54. [54]
  D.Y. Fu, C.L. Zhu, X.T. Zhang, et al., J. Mater. Chem. A 4(2016) 1390-1398.
55. [55]
  H. kheel, G.J. Sun, J.K. Lee, et al., Ceram. Int. 42(2016) 18597-18604. doi: 10.1016/j.ceramint.2016.08.203
56. [56]
  S. Touba, S. Kimiagar, Mater. Sci. Semicon. Proc. 102(2019) 104603. doi: 10.1016/j.mssp.2019.104603
57. [57]
  Y.R. Wang, B. Liu, S.H. Xiao, et al., ACS Appl. Mater. Interfaces 8(2016) 9674-9683. doi: 10.1021/acsami.5b12857
58. [58]
  N.S. Ramgir, C.P. Goyal, P.K. Sharma, et al., Sens. Actuator B:Chem. 188(2013) 525-532. doi: 10.1016/j.snb.2013.07.052
59. [59]
  H.S. Woo, C.H. Kwak, I.D. Kim, et al., J. Mater. Chem. A 2(2014) 6412-6418. doi: 10.1039/C4TA00387J
60. [60]
  N.M. Vuong, D. Kim, H. Kim, Sci. Rep. 5 (2015) 11040.
61. [61]
  F.E. Annanouch, Z. Haddi, S. Vallejos, et al., ACS Appl. Mater. Interfaces 7(2015) 6842-6851.
62. [62]
  C.S. Rout, M. Hegde, C.N.R. Rao, Sens. Actuator. B:Chem. 128(2008) 488-493. doi: 10.1016/j.snb.2007.07.013
63. [63]
  A. Kamalianfar, M.G. Naseri, S.P. Jahromi, Chem. Phys. Lett. 732 (2019) 136648.
64. [64]
  V. Najafi, S. Zolghadr, S. Kimiagar, Optik 182(2019) 249-256. doi: 10.1016/j.ijleo.2019.01.015
65. [65]
  L.W. Wang, Y.F. Kang, Y. Wang, et al., Mater. Sci. Eng. C 32(2012) 2079-2085. doi: 10.1016/j.msec.2012.05.042
66. [66]
  H.Y. Jung, Y.L. Kim, S. Park, et al., Analyst 138(2013) 7206-7211. doi: 10.1039/c3an01762a
67. [67]
  S. Keshtkar, A. Rashidi, M. Kooti, et al., Talanta 188(2018) 531-539. doi: 10.1016/j.talanta.2018.05.099
68. [68]
  A. Bagreev, F. Adib, T.J. Bandosz, Carbon 39(2001) 1897-1905. doi: 10.1016/S0008-6223(00)00317-1
69. [69]
  T.J. Bandosz, Carbon 37(1999) 483-491. doi: 10.1016/S0008-6223(98)00217-6
70. [70]
  V. Meeyoo, D.L. Trimm, N.W. Cant, J. Chem. Technol. Biotechnol. 68(1997) 411-416. doi: 10.1002/(SICI)1097-4660(199704)68:4<411::AID-JCTB644>3.0.CO;2-9
1. [1]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
2. [2]
  Jichun Li , Zhengren Wang , Yu Deng , Hongxiu Yu , Yonghui Deng , Xiaowei Cheng , Kaiping Yuan . Construction of mesoporous silica-implanted tungsten oxides for selective acetone gas sensing. Chinese Chemical Letters, 2024, 35(11): 110111-. doi: 10.1016/j.cclet.2024.110111
3. [3]
  Shangqian Zhang , Jiaxuan Li , Xuan Hu , Zelong Chen , Junliang Dong , Chenhao Hu , Shuang Chao , Yinghua Lv , Yuxin Pei , Zhichao Pei . H₂S and NIR light-driven nanomotors induce disulfidptosis for targeted anticancer therapy by enhancing disruption of tumor metabolic symbiosis. Chinese Chemical Letters, 2025, 36(1): 110314-. doi: 10.1016/j.cclet.2024.110314
4. [4]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
5. [5]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
6. [6]
  Feng Cao , Chunxiang Xian , Tianqi Yang , Yue Zhang , Haifeng Chen , Xinping He , Xukun Qian , Shenghui Shen , Yang Xia , Wenkui Zhang , Xinhui Xia . Gelation-pyrolysis strategy for fabrication of advanced carbon/sulfur cathodes for lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110575-. doi: 10.1016/j.cclet.2024.110575
7. [7]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
8. [8]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
9. [9]
  Jingqi Xin , Shupeng Han , Meichen Zheng , Chenfeng Xu , Zhongxi Huang , Bin Wang , Changmin Yu , Feifei An , Yu Ren . A nitroreductase-responsive nanoprobe with homogeneous composition and high loading for preoperative non-invasive tumor imaging and intraoperative guidance. Chinese Chemical Letters, 2024, 35(7): 109165-. doi: 10.1016/j.cclet.2023.109165
10. [10]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
11. [11]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
12. [12]
  Xian Yan , Huawei Xie , Gao Wu , Fang-Xing Xiao . Boosted solar water oxidation steered by atomically precise alloy nanocluster. Chinese Chemical Letters, 2025, 36(1): 110279-. doi: 10.1016/j.cclet.2024.110279
13. [13]
  Jia-Mei Qin , Xue Li , Wei Lang , Fu-Hao Zhang , Qian-Yong Cao . An AIEgen nano-assembly for simultaneous detection of ATP and H₂S. Chinese Chemical Letters, 2024, 35(6): 108925-. doi: 10.1016/j.cclet.2023.108925
14. [14]
  Yi Zhou , Wei Zhang , Rong Fu , Jiaxin Dong , Yuxuan Liu , Zihang Song , Han Han , Kang Cai . Self-assembly of two pairs of homochiral M₂L₄ coordination capsules with varied confined space using Tröger's base ligands. Chinese Chemical Letters, 2025, 36(2): 109865-. doi: 10.1016/j.cclet.2024.109865
15. [15]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
16. [16]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
17. [17]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
18. [18]
  Yudi Cheng , Xiao Wang , Jiao Chen , Zihan Zhang , Jiadong Ou , Mengyao She , Fulin Chen , Jianli Li . A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H₂S and its applications in living system. Chinese Chemical Letters, 2024, 35(5): 109156-. doi: 10.1016/j.cclet.2023.109156
19. [19]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
20. [20]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1138)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H2S detection

Metrics

通讯作者: 陈斌, bchen63@163.com

Solution-phase synthesis of ordered mesoporous carbon as resonant-gravimetric sensing material for room-temperature H₂S detection