Citation: Sun Shuxian, Han Fuqin, Wu Xiaoliang, Fan Zhuangjun. One-step synthesis of biomass derived O, N-codoped hierarchical porous carbon with high surface area for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(9): 2235-2238. doi: 10.1016/j.cclet.2019.11.023 shu

One-step synthesis of biomass derived O, N-codoped hierarchical porous carbon with high surface area for supercapacitors

Sun Shuxian ^a ,
Han Fuqin ^a ,
Wu Xiaoliang ^a,*, ,
Fan Zhuangjun ^b,*,

a.
College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China
b.
College of Material Science and Engineering, China University of Petroleum, Qingdao 266580, China

wuxiaoliang90@163.com

fanzhj666@163.com

Received Date: 25 September 2019
Revised Date: 12 November 2019
Accepted Date: 13 November 2019
Available Online: 15 November 2019

Figures(4)

We report a convenient method to synthesize O, N-codoped hierarchical porous carbon by one-step carbonization of the mixture of KHCO₃, urea and alginic acid. Benefiting from KHCO₃ and urea synergistic effect, the obtained O, N-codoped hierarchical porous carbon (NPC-700) material has a well-developed interconnected porous framework with ultrahigh specific surface area (2846 m²/g) and massive heteroatoms functional groups. Consequence, such porous carbon displays high specific capacitance (324 F/g at 1 A/g), excellent rate performance (212 F/g at 30 A/g) and good electrochemical stabilization in 6 mol/L KOH solution. More importantly, the assembled NPC-700//NPC-700 symmetrical supercapacitor can achieve a high energy density of 18.8 Wh/kg and good electrochemical stabilization in 1 mol/L Na₂SO₄ solution. This process opens up a new way to design heteroatoms-doped hierarchical porous carbon derived from biomass materials for supercapacitors.
- Alginic acid,
- Urea,
- KHCO₃,
- Supercapacitors,
- Hierarchical porous carbon
1. [1]
  Q. Wang, J. Yan, Z. Fan, Energy Environ. Sci. 9(2016) 729-762. doi: 10.1039/C5EE03109E
2. [2]
  D.W. Xiao, Q.Y. Dou, L. Zhang, et al., Adv. Funct. Mater. (2019) 1904136.
3. [3]
  M. Yang, Z. Zhou, Adv. Sci. 4(2017) 1600408. doi: 10.1002/advs.201600408
4. [4]
  L. Peng, Y. Liang, J. Huang, et al., ACS Sustain. Chem. Eng. 7(2019) 10393-10402. doi: 10.1021/acssuschemeng.9b00477
5. [5]
  S. Yang, S. Wang, X. Liu, L. Li, Carbon 147(2019) 540-549. doi: 10.1016/j.carbon.2019.03.023
6. [6]
  L. Qie, W. Chen, H. Xu, et al., Energy Environ. Sci. 6(2013) 2497-2504. doi: 10.1039/c3ee41638k
7. [7]
  X. Wu, B. Ding, C. Zhang, et al., Carbon 153(2019) 225-233. doi: 10.1016/j.carbon.2019.07.020
8. [8]
  T. Liu, F. Zhang, Y. Song, Y. Li, J. Mater. Chem. A 5(2017) 17705-17733. doi: 10.1039/C7TA05646J
9. [9]
  D. Guo, L. Zhang, X. Song, et al., New J. Chem. 42(2018) 8478-8484. doi: 10.1039/C8NJ00515J
10. [10]
  N. Sun, Z. Li, X. Zhang, et al., ACS Sustain. Chem. Eng. 7(2019) 8735-8743. doi: 10.1021/acssuschemeng.9b00635
11. [11]
  X. Hu, Y. Wang, B. Ding, et al., J. Alloys. Compd. 785(2019) 110-116. doi: 10.1016/j.jallcom.2019.01.160
12. [12]
  G. Zhao, C. Chen, D. Yu, et al., Nano Energy 47(2018) 547-555. doi: 10.1016/j.nanoen.2018.03.016
13. [13]
  W. Zhou, S. Lei, S. Sun, et al., J. Power Sources 402(2018) 203-212. doi: 10.1016/j.jpowsour.2018.09.044
14. [14]
  B. Ding, D. Guo, Y. Wang, et al., J. Power Sources 398(2018) 113-119. doi: 10.1016/j.jpowsour.2018.07.063
15. [15]
  Y. Li, Y. Liang, H. Hu, et al., Carbon 152(2019) 120-127. doi: 10.1016/j.carbon.2019.06.001
16. [16]
  C. Long, J. Zhuang, Y. Xiao, et al., J. Power Sources 310(2016) 145-153. doi: 10.1016/j.jpowsour.2016.01.052
17. [17]
  B. Liu, Y. Liu, H. Chen, et al., J. Power Sources 314(2017) 309-317.
18. [18]
  Y. Wang, B. Ding, D. Guo, et al., Microporous Mesoporous Mater. 282(2019) 114-120. doi: 10.1016/j.micromeso.2019.03.031
19. [19]
  C. Chang, H. Wang, Y. Zhang, et al., ACS Sustain.Chem.Eng. 7(2019) 10763-10772. doi: 10.1021/acssuschemeng.9b01455
20. [20]
  W. Yang, W. Yang, L. Kong, et al., Carbon 127(2018) 557-567. doi: 10.1016/j.carbon.2017.11.050
21. [21]
  Q. Wang, J. Yan, T. Wei, et al., Carbon 60(2013) 481-487. doi: 10.1016/j.carbon.2013.04.067
22. [22]
  H. Peng, G. Ma, K. Sun, et al., Electrochim. Acta 190(2016) 862-871. doi: 10.1016/j.electacta.2015.12.195
23. [23]
  Q. Wang, J. Yan, Y. Wang, et al., Carbon 52(2013) 209-218. doi: 10.1016/j.carbon.2012.09.022
24. [24]
  Y. Cheng, B. Li, Y. Huang, et al., Appl. Surf. Sci. 439(2018) 712-723. doi: 10.1016/j.apsusc.2018.01.006
25. [25]
  Z. Liu, D. Fu, F. Liu, et al., Carbon 70(2014) 295-307. doi: 10.1016/j.carbon.2014.01.011
26. [26]
  S. Zuo, J. Chen, W. Liu, et al., Carbon 129(2018) 199-206. doi: 10.1016/j.carbon.2017.12.018
27. [27]
  Z. Wang, Y. Tan, Y. Yang, et al., J. Power Sources 378(2018) 499-510. doi: 10.1016/j.jpowsour.2017.12.076
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