Citation: Sun Shuxian, Han Fuqin, Wu Xiaoliang, Fan Zhuangjun. One-step synthesis of biomass derived O, N-codoped hierarchical porous carbon with high surface area for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(9): 2235-2238. doi: 10.1016/j.cclet.2019.11.023 shu

One-step synthesis of biomass derived O, N-codoped hierarchical porous carbon with high surface area for supercapacitors

Sun Shuxian ^a ,
Han Fuqin ^a ,
Wu Xiaoliang ^a,*, ,
Fan Zhuangjun ^b,*,

a.
College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China
b.
College of Material Science and Engineering, China University of Petroleum, Qingdao 266580, China

wuxiaoliang90@163.com

fanzhj666@163.com

Received Date: 25 September 2019
Revised Date: 12 November 2019
Accepted Date: 13 November 2019
Available Online: 15 November 2019

Figures(4)

We report a convenient method to synthesize O, N-codoped hierarchical porous carbon by one-step carbonization of the mixture of KHCO₃, urea and alginic acid. Benefiting from KHCO₃ and urea synergistic effect, the obtained O, N-codoped hierarchical porous carbon (NPC-700) material has a well-developed interconnected porous framework with ultrahigh specific surface area (2846 m²/g) and massive heteroatoms functional groups. Consequence, such porous carbon displays high specific capacitance (324 F/g at 1 A/g), excellent rate performance (212 F/g at 30 A/g) and good electrochemical stabilization in 6 mol/L KOH solution. More importantly, the assembled NPC-700//NPC-700 symmetrical supercapacitor can achieve a high energy density of 18.8 Wh/kg and good electrochemical stabilization in 1 mol/L Na₂SO₄ solution. This process opens up a new way to design heteroatoms-doped hierarchical porous carbon derived from biomass materials for supercapacitors.
- Alginic acid,
- Urea,
- KHCO₃,
- Supercapacitors,
- Hierarchical porous carbon
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