Citation: Yan Xuan, Yue Dongting, Guo Chao, Wang Songling, Qian Xufang, Zhao Yixin. Effective removal of chlorinated organic pollutants by bimetallic iron-nickel sulfide activation of peroxydisulfate[J]. Chinese Chemical Letters, ;2020, 31(6): 1535-1539. doi: 10.1016/j.cclet.2019.11.003 shu

Effective removal of chlorinated organic pollutants by bimetallic iron-nickel sulfide activation of peroxydisulfate

School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200242, China

qianxufang@sjtu.edu.cn

yixin.zhao@sjtu.edu.cn

Received Date: 27 September 2019
Revised Date: 16 October 2019
Accepted Date: 4 November 2019
Available Online: 5 November 2019

Figures(4)

Chlorinated organic pollutants (COPs) have caused serious contaminants in soil and groundwater, hence developing methods to remove these pollutants is necessary and urgent. By a simple hydrothermal method, we synthesized the bimetallic iron-nickel sulfide (FeNiS) particles which exhibited excellent catalytic property of COPs removal. FeNiS was chosen as the peroxydisulfate (PDS) activator to removal COPs including 4-chlorophenol (4-CP), 1, 4-dichlorophenol (1, 4-DCP) and 2, 4, 6-trichlorophenol (2, 4, 6-TCP). The results show that FeNiS can efficiently activate PDS to produce sulfate radical (SO₄^·-) which plays major role in the oxidative dechlorination and degradation due to its strong oxidizing property and the ability of producing hydroxyl radicals (^·OH) in the alkaline condition. Meanwhile, the Cl^- abscised from COPs during the dechlorination can turn into the chlorine radicals and enhance the degradation and cause further mineralization of intermediate products. This bimetallic FeNiS catalyst is a promising PDS activator for removal of chlorinated organics.
- Peroxydisulfate oxidation,
- Bimetallic iron-nickel sulfide,
- Chlorinated organic pollutants,
- Sulfate radicals,
- Dechlorination
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