Citation: Liu Kai-Jian, Zeng Tang-Yu, Zeng Jia-Le, Gong Shao-Feng, He Jun-Yi, Lin Ying-Wu, Tan Jia-Xi, Cao Zhong, He Wei-Min. Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid under neat conditions[J]. Chinese Chemical Letters, ;2019, 30(12): 2304-2308. doi: 10.1016/j.cclet.2019.10.031 shu

Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid under neat conditions

a.
Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, China
b.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, China
c.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, China
d.
School of Chemistry and Chemical Engineering, University of South China, Hengyang, China

weiminhe2016@yeah.net

Received Date: 18 September 2019
Revised Date: 4 October 2019
Accepted Date: 25 October 2019
Available Online: 31 December 2019

Figures(8)

An eco-friendly and economical route for the oxidation of 5-hydroxymethylfurfural (HMF) to 2, 5-furandicarboxylic acid (FDCA) with atmospheric dioxygen as the sole oxidant under acid-, base-, metal-, and external initiator-free conditions in minimal solvent was reported. In the present reaction, the 1, 2-diethoxyethylane has a dual role:reaction medium and free-radical initiator. The FDCA easily crystallizes during the reaction and was simple purified via recrystallization to provide the pure FDCA.
- 5-Hydroxymethylfurfural,
- 2, 5-Furandicarboxylic acid,
- Base-free,
- External initiator-free,
- Dioxygen
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