Citation: He Yinghui, Liu Yingjun, Guo Fan, Pang Kai, Fang Bo, Wang Ya, Chang Dan, Xu Zhen, Gao Chao. Dynamic dispersion stability of graphene oxide with metal ions[J]. Chinese Chemical Letters, ;2020, 31(6): 1625-1629. doi: 10.1016/j.cclet.2019.10.010 shu

Dynamic dispersion stability of graphene oxide with metal ions

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Zhejiang University, Hangzhou 310027, China

zhenxu@zju.edu.cn

xuzhen199@163.com

chaogao@zju.edu.cn

Received Date: 8 August 2019
Revised Date: 30 September 2019
Accepted Date: 10 October 2019
Available Online: 18 October 2019

Figures(5)

Graphene oxide (GO), an important chemical precursor of graphene, can stably disperse in aqueous surrounding and undergo aggregation as metal cations introduced. The usual instability of GO with ions is caused by the shielding effect of ions and crosslinking between GO and ions. However, the dynamic stability of GO under ions exchange still remains unclear. Here, we investigated the dynamic dispersion stability of GO with metal ions and observed a redispersion behavior in concentrated Fe³⁺ solution, other than permanent aggregation. The exchange with Fe³⁺ ions drives the reversion of zeta (ζ) potential and enables the redispersion to individual GO-Fe³⁺ complex sheets, following a dynamic electric double layer (EDL) mechanism. It is found that the specifically strong electrostatic shielding effect and coordination attraction between Fe³⁺ and functional oxygen groups allows the selective redispersion of GO in concentrated Fe³⁺ solution. The revealed dynamic dispersion stability complements our understanding on the dispersive stability of GO and can be utilized to fabricate graphene-metal hybrids for rich applications.
- Graphene oxide,
- Metal ions,
- Redispersion,
- Ion exchange,
- Electric double layer,
- Electrostatic shielding effect,
- Coordination
1. [1]
  D.R. Dreyer, S. Park, C.W. Bielawski, R.S. Ruoff, Chem. Soc. Rev. 39(2010) 228-240. doi: 10.1039/B917103G
2. [2]
  J. Kim, L.J. Cote, J. Huang, Acc. Chem. Res. 45(2012) 1356-1364. doi: 10.1021/ar300047s
3. [3]
  Z. Liu, Z. Xu, X. Hu, C. Gao, Macromolecules 46(2013) 6931-6941. doi: 10.1021/ma400681v
4. [4]
  Z. Weng, Z. Xu, C. Gao, Sci. China Chem. 57(2014) 605-614. doi: 10.1007/s11426-013-5060-0
5. [5]
  A.M. Dimiev, J.M. Tour, ACS Nano 8(2014) 3060-3068. doi: 10.1021/nn500606a
6. [6]
  S. Yang, C. Chen, Y. Chen, et al., ChemPlusChem 80(2015) 480-484. doi: 10.1002/cplu.201402284
7. [7]
  C.N. Yeh, K. Raidongia, J. Shao, Q.H. Yang, J. Huang, Nat. Chem. 7(2014) 166-170.
8. [8]
  B.J. Hong, O.C. Compton, Z. An, I. Eryazici, S.B.T. Nguyen, ACS Nano 6(2012) 63-73. doi: 10.1021/nn202355p
9. [9]
  M. Zhang, L. Huang, J. Chen, C. Li, G. Shi, Adv. Mater. 26(2014) 7588-7592. doi: 10.1002/adma.201403322
10. [10]
  F. Guo, X. Zheng, C. Liang, et al., ACS Nano 13(2019) 5549-5558. doi: 10.1021/acsnano.9b00428
11. [11]
  J. Zhang, F. Zhang, H. Yang, et al., Langmuir 26(2010) 6083-6085. doi: 10.1021/la904014z
12. [12]
  Y. Shao, J. Wang, H. Wu, et al., Electroanal. 22(2010) 1027-1036. doi: 10.1002/elan.200900571
13. [13]
  T. Huang, X. Chu, S. Cai, et al., Energy Storage Mater. 17(2019) 349-357. doi: 10.1016/j.ensm.2018.07.001
14. [14]
  K.S. Kim, Y. Zhao, H. Jang, et al., Nature 457(2009) 706-710. doi: 10.1038/nature07719
15. [15]
  X. Sun, Z. Liu, K. Welsher, et al., Nano Res. 1(2008) 203-212. doi: 10.1007/s12274-008-8021-8
16. [16]
  B. Tian, C. Wang, S. Zhang, L. Feng, Z. Liu, ACS Nano 5(2011) 7000-7009. doi: 10.1021/nn201560b
17. [17]
  Z. Xu, H. Sun, X. Zhao, C. Gao, Adv. Mater. 25(2013) 188-193. doi: 10.1002/adma.201203448
18. [18]
  S. Park, K.S. Lee, G. Bozoklu, et al., ACS Nano 2(2008) 572-578. doi: 10.1021/nn700349a
19. [19]
  P.Y. Chen, M. Liu, T.M. Valentin, et al., ACS Nano 10(2016) 10869-10879. doi: 10.1021/acsnano.6b05179
20. [20]
  N. Zhang, H. Qiu, Y. Si, W. Wang, J. Gao, Carbon 49(2011) 827-837. doi: 10.1016/j.carbon.2010.10.024
21. [21]
  L.J. Cote, F. Kim, J. Huang, J. Am. Chem. Soc. 131(2009) 1043-1049. doi: 10.1021/ja806262m
22. [22]
  D. Li, M.B. Müller, S. Gilje, R.B. Kaner, G.G. Wallace, Nat. Nanotechnol. 3(2008) 101-105.
23. [23]
  K. Yang, B. Chen, X. Zhu, B. Xing, Environ. Sci. Technol. 50(2016) 11066-11075. doi: 10.1021/acs.est.6b04235
24. [24]
  L. Wu, L. Liu, B. Gao, et al., Langmuir 29(2013) 15174-15181. doi: 10.1021/la404134x
25. [25]
  Y. Gao, X. Ren, X. Tan, et al., J. Hazard. Mater. 335(2017) 56-65. doi: 10.1016/j.jhazmat.2017.04.027
26. [26]
  X. Ren, J. Li, X. Tan, et al., Environ. Sci. Technol. 48(2014) 5493-5500. doi: 10.1021/es404996b
27. [27]
  X. Wang, H. Bai, G. Shi, J. Am. Chem. Soc. 133(2011) 6338-6342. doi: 10.1021/ja200218y
28. [28]
  I. Chowdhury, N.D. Mansukhani, L.M. Guiney, M.C. Hersam, D. Bouchard, Environ. Sci. Technol. 49(2015) 10886-10893. doi: 10.1021/acs.est.5b01866
29. [29]
  M. Wang, Y. Niu, J. Zhou, et al., Nanoscale 8(2016) 14587-14592. doi: 10.1039/C6NR03503E
30. [30]
  M. Sano, J. Okamura, S. Shinkai, Langmuir 17(2001) 7172-7173. doi: 10.1021/la010698+
31. [31]
  T. Jimbo, M. Higa, N. Minoura, A. Tanioka, Macromolecules 31(1998) 63-68.
32. [32]
  B. Konkena, S. Vasudevan, J. Phys. Chem. Lett. 3(2012) 867-872. doi: 10.1021/jz300236w
33. [33]
  K.A. Huynh, K.L. Chen, Environ. Sci. Technol. 45(2011) 5564-5571. doi: 10.1021/es200157h
34. [34]
  T. Cao, G. Trefalt, M. Borkovec, Langmuir 34(2018) 14368-14377. doi: 10.1021/acs.langmuir.8b03191
35. [35]
  Y. Li, M. Girard, M. Shen, J.A. Millan, M. Olvera de la Cruz, Proc. Natl. Acad. Sci. U. S. A. 114(2017) 11838-11843. doi: 10.1073/pnas.1713168114
36. [36]
  R. Liu, X. Zhu, B. Chen, Sci. Rep. 7(2017) 1-11. doi: 10.1038/s41598-016-0028-x
37. [37]
  H.P. Cong, X.C. Ren, P. Wang, S.H. Yu, ACS Nano 6(2012) 2693-2703. doi: 10.1021/nn300082k
38. [38]
  M.D. Sánchez, P. Chen, T. Reinecke, M. Muhler, W. Xia, ChemCatChem 4(2012) 1997-2004. doi: 10.1002/cctc.201200286
39. [39]
  M. Liu, P.Y. Chen, R.H. Hurt, Adv. Mater. 30(2018) 1-8.
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