Citation: Xin Yu, Peng Sheng, Chen Junxing, Yang Zujin, Zhang Jianyong. Continuous flow synthesis of porous materials[J]. Chinese Chemical Letters, ;2020, 31(6): 1448-1461. doi: 10.1016/j.cclet.2019.09.054 shu

Continuous flow synthesis of porous materials

MOE Laboratory of Polymeric Composite and Functional Materials, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China

zhjyong@mail.sysu.edu.cn

Received Date: 27 July 2019
Revised Date: 28 September 2019
Accepted Date: 30 September 2019
Available Online: 3 October 2019

Figures(22)

Porous materials play an important role in chemical catalysis, separation and other industrial applications. High-efficiency preparation of porous materials has become an active research area. Conventional synthesis of porous materials has been dominated by one-pot solution processing conditions carried out by bulk mixing under conventional electric heating via hydrothermal, solvothermal or ionothermal reactions where high temperatures and pressures are the standard. Continuous flow synthesis has many key advantages in terms of efficient mass and heat transfer, precise control of residence times, improved opportunities for automation and feedback control of synthesis, scaling-up reactions and improved safety parameters compared to above mentioned conventional batch scale synthetic methods. In this review, continuous flow synthesis of various crystalline porous materials such as metal-organic frameworks (MOFs), covalent-organic frameworks (COFs), porous organic cages and zeolites is discussed. Combination of microfluidic methods with other techniques are also shown including various heating ways and various methods of substrate adding.
- Porous materials,
- Continuous flow,
- Metal-organic frameworks,
- Zeolites,
- Covalent-organic frameworks
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