Citation: Yuan Chaowei, Cui Wen, Sun Yanjuan, Wang Jiadong, Chen Ruimin, Zhang Jin, Zhang Yuxin, Dong Fan. Inhibition of the toxic byproduct during photocatalytic NO oxidation via La doping in ZnO[J]. Chinese Chemical Letters, ;2020, 31(3): 751-754. doi: 10.1016/j.cclet.2019.09.033 shu

Inhibition of the toxic byproduct during photocatalytic NO oxidation via La doping in ZnO

Yuan Chaowei ^a ,
Cui Wen ^b,c ,
Sun Yanjuan ^a,b,*, ,
Wang Jiadong ^a ,
Chen Ruimin ^a ,
Zhang Jin ^a ,
Zhang Yuxin ^d ,
Dong Fan ^a,b,*,

a.
Chongqing Key Laboratory of Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China
b.
Research Center for Environmental Science & Technology, Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, China
c.
The Center of New Energy Materials and Technology, School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China
d.
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China

syhsyj@163.com

dfctbu@126.com

Received Date: 23 July 2019
Revised Date: 15 September 2019
Accepted Date: 17 September 2019
Available Online: 18 September 2019

Figures(6)

It is of a great challenge to develop semiconductor photocatalysts with potential possibilities to simultaneously enhance photocatalytic efficiency and inhibit generation of toxic intermediates. In this study, we developed a facile method to induce the La doping and cationic vacancie (V_Zn) on ZnO for the highly efficient complete NO oxidation. The photocatalytic NO removal efficiency increases from 36.2% to 53.6%. Most importantly, a significant suppressed NO₂ production also has been realized. According to the DFTcalculations, ESR spectra and in situ FTIR spectra, the introduction of La³⁺ induce the redistribution of charge carriers in La-ZnO, which promote the production of·O₂^- and lead to the formation of V_Zn for the formation of·OH, contributing to the complete oxidation of NO to nitrate. Besides, the conversion pathway of photocatalytic NO oxidation has been elaborated. This work paves a new way to simultaneously realize the photocatalytic pollutants removal and the inhibition of toxic intermediates generation for efficient and safe air purification.
- Photocatalytic NO oxidation,
- Toxic byproduct,
- Reactive oxygen species,
- ZnO,
- Cationic vacancie
1. [1]
  L.S.R. Brickus, J.N. Cardoso, F.R.D. Neto, et al., Environ. Sci. Technol. 32(1998) 3485-3490. doi: 10.1021/es980336x
2. [2]
  M.X. Ran, P. Chen, J.R. Li, et al., Chin. Chem. Lett. 30(2019) 875-880. doi: 10.1016/j.cclet.2019.03.016
3. [3]
  S.C. Yan, R. Xu, J.L. Hu, et al., Environ. Sci. Technol. 47(2013) 11562-11568. doi: 10.1021/es4025595
4. [4]
  K.C. Taylor, Catal. Rev. 35(1993) 475-481.
5. [5]
  F. Dong, Z.Y. Wang, Y.H. Li, et al., Environ. Sci. Technol. 48(2014) 10345-10353. doi: 10.1021/es502290f
6. [6]
  Y. Huang, P.G. Wang, Z.Y. Wang, et al., Appl. Catal. B 240(2019) 122-131. doi: 10.1016/j.apcatb.2018.08.078
7. [7]
  Z.Y. Wang, Y. Huang, M.J. Chen, et al., ACS Appl. Mater. Interfaces 11(2019) 10651-10662. doi: 10.1021/acsami.8b21987
8. [8]
  M.J. Chen, Y. Huang, J. Yao, et al., Appl. Surf. Sci. 430(2018) 137-144. doi: 10.1016/j.apsusc.2017.06.056
9. [9]
  Y.F. Lu, Y. Huang, J.J. Cao, et al., J. Mater. Chem. A:Mater. Energy Sustain. 7(2019) 15782-15793. doi: 10.1039/C9TA03504D
10. [10]
  I. Heo, M.K. Kim, S. Sung, et al., Environ. Sci. Technol. 47(2013) 3657-3664. doi: 10.1021/es304188k
11. [11]
  Q.B. Guo, T.H. Sun, Y.L. Wang, et al., Environ. Sci. Technol. 47(2013) 9514-9522. doi: 10.1021/es401013f
12. [12]
  W.S. Epling, L.E. Campbell, A. Yezerets, et al., Catal. Rev. 46(2004) 163-245. doi: 10.1081/CR-200031932
13. [13]
  K.C.H. wan, Q. Gongshin, D. Kevin, et al., Science 327(2010) 1624-1627. doi: 10.1126/science.1184087
14. [14]
  Z.H. Ai, W.K. Ho, S.C. Lee, et al., Environ. Sci. Technol. 43(2009) 4143-4150. doi: 10.1021/es9004366
15. [15]
  Y. Huang, W.K. Ho, S.C. Lee, et al., Langmuir 24(2008) 3510-3516. doi: 10.1021/la703333z
16. [16]
  G.Q. Zhu, S.P. Li, J.Z. Gao, et al., Appl. Surf. Sci. 493(2019) 913-925. doi: 10.1016/j.apsusc.2019.07.119
17. [17]
  J.Y. Li, P. Yan, K. Li, et al., J. Mater. Chem. A:Mater. Energy Sustain. 7(2019) 17014-17021. doi: 10.1039/C9TA05112K
18. [18]
  W. Cui, J.Y. Li, F. Dong, et al., Environ. Sci. Technol. 51(2017) 10682-10690. doi: 10.1021/acs.est.7b00974
19. [19]
  X. Li, T. Chen, H. Lin, et al., Sci. Bull. (Beijing) 63(2018) 219-227. doi: 10.1016/j.scib.2017.12.016
20. [20]
  B. Dong, T. Liu, C. Li, et al., Chin. Chem. Lett. 29(2018) 671-680. doi: 10.1016/j.cclet.2017.12.002
21. [21]
  M. Green, A.T. Tran, et al., Int. J. Green Nanotechnol. Mater. Sci. Eng. 1(2019) 48-59.
22. [22]
  H.J. Yu, Y.F. Zhao, C. Zhou, et al., J. Mater. Chem. A:Mater. Energy Sustain. 2(2014) 3344-3351. doi: 10.1039/c3ta14108j
23. [23]
  S. Luan, D. Qu, L. An, et al., Sci. Bull. (Beijing) 63(2018) 683-690. doi: 10.1016/j.scib.2018.04.002
24. [24]
  H. Li, H. Shang, X. Cao, et al., Environ. Sci. Technol. 52(2018) 8659-8665. doi: 10.1021/acs.est.8b01849
25. [25]
  W.C. Wang, G.M. Cool, N. Kapur, et al., Science 337(2012) 832-835. doi: 10.1126/science.1225091
26. [26]
  J.Y. Li, W. Cui, Y.J. Sun, et al., J. Mater. Chem. A:Mater. Energy Sustain. 5(2017) 9358-9364. doi: 10.1039/C7TA02183F
27. [27]
  Y. Wang, X.C. Wang, M. Antonietti, et al., Angew. Chem. 2(2012) 68-89.
28. [28]
  J.L. Zhang, Y.M. Wu, M.Y. Xing, et al., Energy Environ. Sci. 3(2010) 715-726. doi: 10.1039/b927575d
29. [29]
  X.B. Chen, S.H. Shen, L.J. Guo, et al., Chem. Rev. 110(2010) 6503-6570. doi: 10.1021/cr1001645
30. [30]
  J. Lasek, Y.H. Yu, J.C.S. Wu, et al., J. Photochem. Photobiol. C:Photochem. Rev.14(2013) 29-52. doi: 10.1016/j.jphotochemrev.2012.08.002
31. [31]
  F. Dong, Z.Y. Wang, Y.H. Li, et al., Environ. Sci. Technol. 48(2014) 10345-10353. doi: 10.1021/es502290f
32. [32]
  Y. Nosaka, A.Y. Nosaka, Chem. Rev. 117(2017) 11302-11336. doi: 10.1021/acs.chemrev.7b00161
33. [33]
  M. Samadi, M. Zirak, A. Naseri, et al., Thin Solid Films 605(2016) 2-19. doi: 10.1016/j.tsf.2015.12.064
34. [34]
  M.H. Li, Y.W. Chen, T.S. Lin, et al., ACS Catal. 8(2018) 6862-6869. doi: 10.1021/acscatal.8b01282
35. [35]
  J.J. Macías-Sánchez, L. Hinojosa-Reyes, A. Caballero-Quintero, et al., Photochem. Photobiol. Sci. 14(2015) 536-542. doi: 10.1039/C4PP00273C
36. [36]
  P.W. Huo, J.Z. Li, Z.F. Ye, et al., Chin. Chem. Lett. 28(2017) 2256-2262.
37. [37]
  N.T. Hanh, N.L.M. Tri, D.V. Thuan, et al., J. Photochem. Photobiol. A:Chem. 382(2019)111923. doi: 10.1016/j.jphotochem.2019.111923
38. [38]
  S. Wang, B.C. Zhu, M.J. Liu, et al., Appl. Catal. B 243(2019) 19-26. doi: 10.1016/j.apcatb.2018.10.019
39. [39]
  S.G. Ullattil, P. Periyat, B. Naufal, et al., Ind. Eng. Chem. Res. 55(2016) 6413-6421. doi: 10.1021/acs.iecr.6b01030
40. [40]
  M. Guo, P. Diao, S.M. Gai, et al., Chin. Chem. Lett. 15(2004) 1113-1116.
41. [41]
  V.H.T. Thi, B.K. Lee, Mater. Res. Bull. 96(2017) 171-182. doi: 10.1016/j.materresbull.2017.04.028
42. [42]
  M.D. McCluskey, S.J. Jokela, J. Appl. Phys. 106(2009) 071101. doi: 10.1063/1.3216464
43. [43]
  M.H. Li, Y.W. Chen, X.Y. Liu, et al., ACS Catal. 6(2015) 115-122.
44. [44]
  K. Hadjiivanov, H. Knözinger, Phys. Chem. Chem. Phys. 2(2000) 2803-2806. doi: 10.1039/b002065f
45. [45]
  J.C.S. Wu, Y.T. Cheng, J. Catal. 237(2006) 393-404. doi: 10.1016/j.jcat.2005.11.023
46. [46]
  Q. Wu, R.V.D. Krol, J. Am. Chem. Soc. 134(2012) 9369-9375. doi: 10.1021/ja302246b
47. [47]
  K. Hadjiivanov, V. Bushev, M. Kantcheva, et al., Langmuir 10(1994) 464-471. doi: 10.1021/la00014a021
48. [48]
  T.J. Toops, D.B. Smith, W.P. Partridge, et al., Appl. Catal. B 58(2005) 245-254. doi: 10.1016/j.apcatb.2004.10.021
49. [49]
  W. Cui, L. Chen, J. Li, et al., Appl. Catal. B 253(2019) 293-299. doi: 10.1016/j.apcatb.2019.04.070
50. [50]
  X. Li, W. Zhang, W. Cui, et al., Chem. Eng. J. 370(2019) 1366-1375. doi: 10.1016/j.cej.2019.04.003
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