Citation: Wen Caiying, Zhu Tianjiao, Li Xingyu, Li Huifeng, Huang Xianqiang, Sun Genban. Nanostructured Ni/Ti₃C₂T_x MXene hybrid as cathode for lithium-oxygen battery[J]. Chinese Chemical Letters, ;2020, 31(4): 1000-1003. doi: 10.1016/j.cclet.2019.09.028 shu

Nanostructured Ni/Ti₃C₂T_x MXene hybrid as cathode for lithium-oxygen battery

a.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China
b.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China

lihuifeng@bnu.edu.cn

Received Date: 25 July 2019
Revised Date: 6 September 2019
Accepted Date: 9 September 2019
Available Online: 18 September 2019

Figures(4)

Ti₃C₂ belongs to MXenes family, which is a new two-dimensional material and has been applied in many fields. With simple method of hydrothermal and high temperature calcination, nanostructured Ni/Ti₃C₂T_x hybrid was synthesized. The stable layer structure of Ti₃C₂ MXene providing high surface area as well as excellent electronic conductivity are beneficial for deposition and decomposition of discharge product Li₂O₂. Furthermore, possessing special catalytic activity, Ni nanoparticles with size of about 20 nm could accelerate Li₂O₂ breaking down. Taking advantage of two kinds of materials, Ni/Ti₃C₂T_x hybrid as cathode of Li-O₂ battery can achieve a maximal specific capacity of 20, 264 mAh/g in 100 mA/g and 10, 699 mAh/g in 500 mA/g at the first cycle. This work confirms that the prepared Ni/Ti₃C₂T_x hybrid exhibiting better cycling stability points out a new guideline to improve the electrochemical performance of lithium-oxygen batteries.
- MXene,
- Nickel,
- Two-dimensional material,
- Electronic conductivity,
- Lithium-oxygen battery
1. [1]
  G. Girishkumar, B. McCloskey, A.C. Luntz, S. Swanson, W. Wilcke, J. Phy. Chem. Lett. 1(2010) 2193-2203. doi: 10.1021/jz1005384
2. [2]
  L. Grande, E. Paillard, J. Hassoun, et al., Adv. Mater. 27(2015) 784-800. doi: 10.1002/adma.201403064
3. [3]
  J. Lu, L. Li, J.B. Park, et al., Chem. Rev. 114(2014) 5611-5640. doi: 10.1021/cr400573b
4. [4]
  L. Wang, Y. Zhang, Z. Liu, L. Guo, Z. Peng, Green Energy Environ. 2 (2017)186-203. doi: 10.1016/j.gee.2017.06.004
5. [5]
  C. Liu, R. Younesi, C.W. Tai, et al., J. Mater. Chem. A Mater. Energy Sustain. 4(2016) 9767-9773. doi: 10.1039/C5TA10690G
6. [6]
  M.M.O. Thotiyl, S.A. Freunberger, Z. Peng, P.G. Bruce, J. Am. Chem. Soc. 135(2013) 494-500. doi: 10.1021/ja310258x
7. [7]
  M. M. O. Thotiyl, S. A. Freunberger, Z. Peng, et al., Nat. Mater. 12 (2013)1049-1055.
8. [8]
  C. Wang, Z. Xie, Z. Zhou, Appl. Mater. 7(2019) 040701. doi: 10.1063/1.5091444
9. [9]
  N.K. Chaudhari, H. Jin, B. Kim, et al., J. Mater. Chem. A Mater. Energy Sustain. 5(2017) 24564-24579. doi: 10.1039/C7TA09094C
10. [10]
  M. Naguib, V. N. Mochalin, M. W. Barsoum, Y. Gogotsi, Adv. Mater. 26(2014)992-1005. doi: 10.1002/adma.201304138
11. [11]
  V.M.H. Ng, H. Huang, K. Zhou, et al., J. Mater. Chem. A Mater. Energy Sustain. 5(2017) 3039-3068. doi: 10.1039/C6TA06772G
12. [12]
  Y.T. Liu, P. Zhang, N. Sun, et al., Adv. Mater. 30(2018) 1707334.
13. [13]
  L. Yu, L. Hu, B. Anasori, et al., ACS Energy Lett. 3(2018) 1597-1603. doi: 10.1021/acsenergylett.8b00718
14. [14]
  Q. Zhao, Q. Zhu, J. Miao, P. Zhang, B. Xu, Nanoscale 11(2019) 8442-8448. doi: 10.1039/C8NR09653H
15. [15]
  X. Zhang, Z. Zhang, Z. Zhou, J. Energy Chem. 27(2018) 73-85. doi: 10.1016/j.jechem.2017.08.004
16. [16]
  D. Ji, S. Peng, D. Safanama, et al., Chem. Mater. 29(2017) 1665-1675. doi: 10.1021/acs.chemmater.6b05056
17. [17]
  M. W. Yuan, R. Wang, W. B. Fu, et al., ACS Appl. Mat. Interfaces 11(2019)11403-11413. doi: 10.1021/acsami.8b21808
18. [18]
  M. Yuan, C. Nan, Y. Yang, et al., ACS Omega 2(2017) 4269-4277. doi: 10.1021/acsomega.7b00497
19. [19]
  M. Yuan, L. Lin, Y. Yang, et al., Nanotechnology 28(2017) 185401. doi: 10.1088/1361-6528/aa66bc
20. [20]
  M. Yuan, Y. Yang, C. Nan, et al., Appl. Surf. Sci. 444(2018) 312-319. doi: 10.1016/j.apsusc.2018.02.267
21. [21]
  Z. Liu, N. Feng, Z. Shen, et al., ChemSusChem 10(2017) 2714-2719. doi: 10.1002/cssc.201700567
22. [22]
  Y.J. Oh, J.H. Kim, S.K. Park, et al., Chem. Eng. J. 351(2018) 886-896. doi: 10.1016/j.cej.2018.06.166
23. [23]
  J. Yan, C.E. Ren, K. Maleski, et al., Adv. Funct. Mater. 27(2017) 1701264. doi: 10.1002/adfm.201701264
24. [24]
  A.P. Grosvenor, M.C. Biesinger, R.S.C. Smart, N.S. McIntyre, Surf. Sci. 600(2006) 1771-1779. doi: 10.1016/j.susc.2006.01.041
25. [25]
  M. Jin, G. Zhang, F. Yu, et al., Phys. Chem. Chem. Phys. 15(2013) 1601-1605. doi: 10.1039/C2CP43357E
26. [26]
  H. Zhang, L. Yu, T. Chen, W. Zhou, X. W. Lou, Adv. Funct. Mater. 28 (2018) 1807086. doi: 10.1002/adfm.201807086
27. [27]
  H. Han, J. Woo, Y.R. Hong, Y.C. Chung, S. Mhin, ACS Appl. Energy Mater. 2(2019) 3999-4007.
28. [28]
  Y.M. Lee, K.M. Nam, E.H. Hwang, et al., J. Phys. Chem. C 118(2014) 10631-10639.
29. [29]
  A. Rozmyslowska-Wojciechowska, E. Karwowska, S. Pozniak, et al., RSC Adv. 9(2019) 4092-4105. doi: 10.1039/C8RA07633B
30. [30]
  J. Halim, K.M. Cook, M. Naguib, et al., Appl. Surf. Sci. 362(2016) 406-417. doi: 10.1016/j.apsusc.2015.11.089
31. [31]
  C. Wang, Y. Zhao, J. Liu, et al., Chem. Commun. 52(2016) 11772-11774. doi: 10.1039/C6CC05349A
32. [32]
  Z. Hou, J. Long, C. Shu, et al., J. Alloys. Compd. 798(2019) 560-567. doi: 10.1016/j.jallcom.2019.05.131
33. [33]
  X. Yang, L. Zhang, F. Zhang, Y. Huang, Y. Chen, ACS Nano 8(2014) 5208-5215. doi: 10.1021/nn501284q
34. [34]
  K. Zhang, Y. Xu, Y. Lu, et al., J. Mater. Chem. A Mater. Energy Sustain. 4(2016) 6404-6410. doi: 10.1039/C6TA01118G
35. [35]
  T. Zhu, X. Li, Y. Zhang, et al., J. Electroanal. Chem. 823(2018) 73-79. doi: 10.1016/j.jelechem.2018.05.032
36. [36]
  X. Li, T. Zhu, C. Wen, et al., Electrochim. Acta 317(2019) 367-374. doi: 10.1016/j.electacta.2019.05.054
37. [37]
  Z. Sun, M. Yuan, L. Lin, et al., ACS Appl. Energy Mater. 2(2019) 4144-4150. doi: 10.1021/acsaem.9b00328
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nanostructured Ni/Ti3C2Tx MXene hybrid as cathode for lithium-oxygen battery

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通讯作者: 陈斌, bchen63@163.com

Nanostructured Ni/Ti₃C₂T_x MXene hybrid as cathode for lithium-oxygen battery