Citation: Qin Yingnan, Sun Yingjun, Li Yingjie, Li Chun, Wang Lei, Guo Shaojun. MOF derived Co₃O₄/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H₂O₂ and glucose[J]. Chinese Chemical Letters, ;2020, 31(3): 774-778. doi: 10.1016/j.cclet.2019.09.016 shu

MOF derived Co₃O₄/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H₂O₂ and glucose

Qin Yingnan ^a,b ,
Sun Yingjun ^a,b ,
Li Yingjie ^b ,
Li Chun ^b ,
Wang Lei ^a,*, ,
Guo Shaojun ^b,*,

a.
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
b.
Department of Materials Science and Engineering, Department of Biomedical Engineering, College of Engineering, Peking University, Beijing 100871, China

inorchemwl@126.com

guosj@pku.edu.cn

Received Date: 12 June 2019
Revised Date: 4 September 2019
Accepted Date: 9 September 2019
Available Online: 11 September 2019

Figures(4)

Developing enzyme-free sensors with high sensitivity and selectivity for H₂O₂ and glucose is highly desirable for biological science. Especially, it is attractive to exploit noble-metal-free nanomaterials with large surface area and good conductivity as highly active and selective catalysts for molecular detection in enzyme-free sensors. Herein, we successfully fabricate hollow frameworks of Co₃O₄/N-doped carbon nanotubes (Co₃O₄/NCNTs) hybrids by the pyrolysis of metal-organic frameworks followed by calcination in the air. The as-prepared novel hollow Co₃O₄/NCNTs hybrids exhibit excellent electrochemical performance for H₂O₂ reduction in neutral solutions and glucose oxidation in alkaline solutions. As sensor electrode, the Co₃O₄/NCNTs show excellent non-enzymatic sensing ability towards H₂O₂ response with a sensitivity of 87.40 μA (mmol/L)^-1 cm^-2, a linear range of 5.00 μmol/L-11.00 mmol/L, and a detection limitation of 1 μmol/L in H₂O₂ detection, and a good glucose detection performance with 5 μmol/L. These excellent electrochemical performances endow the hollow Co₃O₄/NCNTs as promising alternative to enzymes in the biological applications.
- ZIF-67,
- Co₃O₄/NCNTs hybrids,
- Enzyme-free sensor,
- H₂O₂,
- Glucose
1. [1]
  J.S. Chung, S.H. Hur, Sens. Actuators B-Chem. 223(2016) 76-82. doi: 10.1016/j.snb.2015.09.009
2. [2]
  Meng, Y. Wen, L. Dai, et al., Sens. Actuators B-Chem. 260(2018) 852-860. doi: 10.1016/j.snb.2018.01.109
3. [3]
  H. Heidari, E. Habibi, Microchim. Acta 183(2016) 2259-2266. doi: 10.1007/s00604-016-1862-z
4. [4]
  Y. Sun, M. Luo, Y. Qin, et al., ACS Appl. Mater. Interfaces 9(2017) 34715-34721. doi: 10.1021/acsami.7b11758
5. [5]
  J. Mu, L. Zhang, M. Zhao, et al., ACS Appl. Mater. Interfaces 6(2014) 7090-7098. doi: 10.1021/am406033q
6. [6]
  B. Dou, J. Yang, R. Yuan, et al., Anal. Chem. 90(2018) 5945-5950. doi: 10.1021/acs.analchem.8b00894
7. [7]
  H. Cheng, L. Zhang, J. He, et al., Anal. Chem. 88(2016) 5489-5497. doi: 10.1021/acs.analchem.6b00975
8. [8]
  L. Tian, G. He, Y. Cai, et al., Nanotechnology 29(2018) 075502. doi: 10.1088/1361-6528/aaa1d2
9. [9]
  Y. Su, B. Luo, J.Z. Zhang, Anal. Chem. 88(2016) 1617-1624. doi: 10.1021/acs.analchem.5b03396
10. [10]
  C. Gao, H. Zhu, J. Chen, et al., Chin. Chem. Lett. 28(2017) 1006-1012. doi: 10.1016/j.cclet.2017.02.011
11. [11]
  M. Song, J. Wang, B. Chen, et al., Anal. Chem. 89(2017) 11537-11544. doi: 10.1021/acs.analchem.7b02831
12. [12]
  A. Amirjani, M. Bagheri, M. Heydari, et al., Sens. Actuators B-Chem. 227(2016) 373-382. doi: 10.1016/j.snb.2015.12.062
13. [13]
  C. Chen, X. Hong, T. Xu, et al., Synthetic Met. 212(2016) 123-130. doi: 10.1016/j.synthmet.2015.12.012
14. [14]
  H. Quan, C. Zuo, T. Li, et al., Electrochim. Acta 176(2015) 893-897. doi: 10.1016/j.electacta.2015.07.086
15. [15]
  C. Chen, R. Ran, Z. Yang, et al., Sens. Actuators B-Chem. 256(2018) 63-70. doi: 10.1016/j.snb.2017.10.067
16. [16]
  C.L. Yang, X.H. Zhang, G. Lan, et al., Chin. Chem. Lett. 25(2014) 496-500. doi: 10.1016/j.cclet.2014.02.001
17. [17]
  Kong, Z. Ren, N. Zheng, et al., Nano Res. 8(2015) 469-480. doi: 10.1007/s12274-014-0617-6
18. [18]
  J. Huang, Y. Zhu, H. Zhong, et al., ACS Appl. Mater. Interfaces 6(2014) 7055-7062. doi: 10.1021/am501799w
19. [19]
  J. Yang, H. Xiang, L. Shuai, et al., Anal. Chim. Acta 708(2011) 44-51. doi: 10.1016/j.aca.2011.09.039
20. [20]
  C. Zhang, L. Li, J. Ju, et al., Electrochim. Acta 210(2016) 181-189. doi: 10.1016/j.electacta.2016.05.151
21. [21]
  H. Dai, Y. Chen, X. Niu, et al., Biosens. Bioelectron. 118(2018) 36-43. doi: 10.1016/j.bios.2018.07.022
22. [22]
  X. Feng, Y. Zhang, J. Song, et al., Electroanalysis 27(2015) 353-359. doi: 10.1002/elan.201400481
23. [23]
  B.Y. Xia, Y. Yan, N. Li, et al., Nat. Energy 1(2016) 15006. doi: 10.1038/nenergy.2015.6
24. [24]
  G.J.H. Melvin, Q.Q. Ni, Y. Suzuki, et al., J. Mater. Sci. 49(2014) 5199-5207. doi: 10.1007/s10853-014-8229-9
1. [1]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
2. [2]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
3. [3]
  Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
4. [4]
  Jun Jiang , Tong Guo , Wuxin Bai , Mingliang Liu , Shujun Liu , Zhijie Qi , Jingwen Sun , Shugang Pan , Aleksandr L. Vasiliev , Zhiyuan Ma , Xin Wang , Junwu Zhu , Yongsheng Fu . Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(4): 108565-. doi: 10.1016/j.cclet.2023.108565
5. [5]
  Xiaodan Wang , Yingnan Liu , Zhibin Liu , Zhongjian Li , Tao Zhang , Yi Cheng , Lecheng Lei , Bin Yang , Yang Hou . Highly efficient electrosynthesis of H₂O₂ in acidic electrolyte on metal-free heteroatoms co-doped carbon nanosheets and simultaneously promoting Fenton process. Chinese Chemical Letters, 2024, 35(7): 108926-. doi: 10.1016/j.cclet.2023.108926
6. [6]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
7. [7]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
8. [8]
  Yunkang Tong , Haiqiao Huang , Haolan Li , Mingle Li , Wen Sun , Jianjun Du , Jiangli Fan , Lei Wang , Bin Liu , Xiaoqiang Chen , Xiaojun Peng . Cooperative bond scission by HRP/H₂O₂ for targeted prodrug activation. Chinese Chemical Letters, 2024, 35(12): 109663-. doi: 10.1016/j.cclet.2024.109663
9. [9]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
10. [10]
  Sikai Wu , Xuefei Wang , Huogen Yu . Hydroxyl-enriched hydrous tin dioxide-coated BiVO4 with boosted photocatalytic H2O2 production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100457-100457. doi: 10.1016/j.cjsc.2024.100457
11. [11]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
12. [12]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
13. [13]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
14. [14]
  Hao Lv , Zhi Li , Peng Yin , Ping Wan , Mingshan Zhu . Recent progress on non-metallic carbon nitride for the photosynthesis of H₂O₂: Mechanism, modification and in-situ applications. Chinese Chemical Letters, 2025, 36(1): 110457-. doi: 10.1016/j.cclet.2024.110457
15. [15]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
16. [16]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
17. [17]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
18. [18]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
19. [19]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
20. [20]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(871)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

MOF derived Co3O4/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H2O2 and glucose

Metrics

通讯作者: 陈斌, bchen63@163.com

MOF derived Co₃O₄/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H₂O₂ and glucose