Citation: Qin Yingnan, Sun Yingjun, Li Yingjie, Li Chun, Wang Lei, Guo Shaojun. MOF derived Co₃O₄/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H₂O₂ and glucose[J]. Chinese Chemical Letters, ;2020, 31(3): 774-778. doi: 10.1016/j.cclet.2019.09.016 shu

MOF derived Co₃O₄/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H₂O₂ and glucose

Qin Yingnan ^a,b ,
Sun Yingjun ^a,b ,
Li Yingjie ^b ,
Li Chun ^b ,
Wang Lei ^a,*, ,
Guo Shaojun ^b,*,

a.
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
b.
Department of Materials Science and Engineering, Department of Biomedical Engineering, College of Engineering, Peking University, Beijing 100871, China

inorchemwl@126.com

guosj@pku.edu.cn

Received Date: 12 June 2019
Revised Date: 4 September 2019
Accepted Date: 9 September 2019
Available Online: 11 September 2019

Figures(4)

Developing enzyme-free sensors with high sensitivity and selectivity for H₂O₂ and glucose is highly desirable for biological science. Especially, it is attractive to exploit noble-metal-free nanomaterials with large surface area and good conductivity as highly active and selective catalysts for molecular detection in enzyme-free sensors. Herein, we successfully fabricate hollow frameworks of Co₃O₄/N-doped carbon nanotubes (Co₃O₄/NCNTs) hybrids by the pyrolysis of metal-organic frameworks followed by calcination in the air. The as-prepared novel hollow Co₃O₄/NCNTs hybrids exhibit excellent electrochemical performance for H₂O₂ reduction in neutral solutions and glucose oxidation in alkaline solutions. As sensor electrode, the Co₃O₄/NCNTs show excellent non-enzymatic sensing ability towards H₂O₂ response with a sensitivity of 87.40 μA (mmol/L)^-1 cm^-2, a linear range of 5.00 μmol/L-11.00 mmol/L, and a detection limitation of 1 μmol/L in H₂O₂ detection, and a good glucose detection performance with 5 μmol/L. These excellent electrochemical performances endow the hollow Co₃O₄/NCNTs as promising alternative to enzymes in the biological applications.
- ZIF-67,
- Co₃O₄/NCNTs hybrids,
- Enzyme-free sensor,
- H₂O₂,
- Glucose
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沈阳化工大学材料科学与工程学院沈阳 110142

MOF derived Co3O4/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H2O2 and glucose

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通讯作者: 陈斌, bchen63@163.com

MOF derived Co₃O₄/N-doped carbon nanotubes hybrids as efficient catalysts for sensitive detection of H₂O₂ and glucose