Citation: Zhang Yanni, Zhao Jianfeng, Zhu Caixia, Bian Lifang, Shi Huifang, Zhang Shiming, Ma Huili, Huang Wei. Regioisomerism effect (RIE) on optimizing ultralong organic phosphorescence lifetimes[J]. Chinese Chemical Letters, ;2019, 30(11): 1974-1978. doi: 10.1016/j.cclet.2019.09.005 shu

Regioisomerism effect (RIE) on optimizing ultralong organic phosphorescence lifetimes

Key Laboratory of Flexible Electronics(KLOFE) & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University(NanjingTech), Nanjing 211816, China

iamjfzhao@njtech.edu.cn

iamsmzhang@njtech.edu.cn

iamhlma@njtech.edu.cn

iamwhuang@njtech.edu.cn

Received Date: 6 June 2019
Revised Date: 13 August 2019
Accepted Date: 4 September 2019
Available Online: 20 November 2019

Figures(5)

Organic phosphorescence materials demonstrate potential optoelectronic applications due to their remarkably ultralong organic phosphorescence (UOP) lifetime and abundant optical characteristics prior to the fluorescence materials. For a better insight into the intrinsic relationship among regioisomeric molecules, crystalline interactions, and phosphorescence properties, three crystalline dicarbazol-9-yl pyrazine-based regioisomers with para-, meta- and ortho-convergent substitutions (p-DCzP, m-DCzP, and o-DCzP) were designed and presented gradually increased UOP lifetimes prolonging from 63.14, 127.93 to 350.46 ms, respectively, due to the regioisomerism effect (RIE) which would be an effective strategy for better understanding of structure-property of UOP materials.
- Regioisomerism effect (RIE),
- Ultralong organic phosphorescence (UOP),
- Crystal engineering,
- H-Aggregation
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