Citation: Zhu Ailing, Guo Yingying, Liu Guangliang, Song Maoyong, Liang Yong, Cai Yong, Yin Yongguang. Hydroxyl radical formation upon dark oxidation of reduced iron minerals: Effects of iron species and environmental factors[J]. Chinese Chemical Letters, ;2019, 30(12): 2241-2244. doi: 10.1016/j.cclet.2019.09.003 shu

Hydroxyl radical formation upon dark oxidation of reduced iron minerals: Effects of iron species and environmental factors

Zhu Ailing ^a,b ,
Guo Yingying ^b,c ,
Liu Guangliang ^a,d ,
Song Maoyong ^b,c ,
Liang Yong ^a ,
Cai Yong ^b,c,d ,
Yin Yongguang ^a,b,c,*,

a.
Institute of Environment and Health, Jianghan University, Wuhan 430056, China
b.
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
c.
Laboratory of Environmental Nanotechnology and Health Effect, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
d.
Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, United States

ygyin@rcees.ac.cn

Received Date: 31 July 2019
Revised Date: 30 August 2019
Accepted Date: 2 September 2019
Available Online: 3 December 2019

Figures(4)

Dark formation of hydroxyl radical upon oxidation of reduced iron minerals plays an important role in the degradation and transformation of organic and inorganic pollutants. Herein, we compared the hydroxyl radical formation from various reduced iron minerals at different redox conditions. ^·OH production was generally observed from the oxidation of reduced iron minerals, following the order:mackinawite (FeS) > reduced nontronite (iron-bearing smectite clay) > pyrite (FeS₂) > siderite (FeCO₃). Structural Fe²⁺ and dissolved O₂ play critical roles in ^·OH production from reduced iron minerals. ^·OH production increases with decreasing pH, and Cl^- has little effect on this process. More importantly, dissolved organic matter significantly enhances ^·OH production, especially under O₂ purging, highlighting the importance of this process in ambient environments. This sunlight-independent pathway in which ^·OH forms during oxidation of reduced iron minerals is helpful for understanding the degradation and transformation of various inorganic and organic pollutants in the redox-fluctuation environments.
- Reduced iron minerals,
- Hydroxyl radical,
- Dark oxidation,
- Mackinawite,
- Dissolved organic matter
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