Citation: Miao Wei, Zhu Zhaoyang, Li Zhongxin, Hao Erhong, Jiao Lijuan. Novel expanded porphyrinoids with multiple-inner-ring-fusion and/or tunable aromaticity[J]. Chinese Chemical Letters, ;2019, 30(11): 1895-1902. doi: 10.1016/j.cclet.2019.08.016 shu

Novel expanded porphyrinoids with multiple-inner-ring-fusion and/or tunable aromaticity

Laboratory of Functional Molecular Solids, Ministry of Education, School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China

Author Bio:

Prof. Lijuan Jiao received her Bachelor's degree (2000) from Shandong University, China, and obtained her Master's degree (2003) under the supervision of Prof. Guanwu Wang at University of Science and Technology of China (USTC). She then moved to Louisiana State University, U. S. A., and obtained her Ph.D. (2007) under the supervision of Prof. Kevin M. Smith. She joined Anhui Normal University in 2008, and became a full professor (2010) at College of Chemistry and Materials Science. Her research focuses on the development of novel BODIPY and porphyrin related dyes, understanding their photophysical properties and studying their optoelectrical and biological applications. She received a SPP/JPP Young Investigator Award for her research in BODIPY and oligopyrrole chemistry in 2016

jiao421@ahnu.edu.cn

Received Date: 3 July 2019
Revised Date: 29 July 2019
Accepted Date: 13 August 2019
Available Online: 16 November 2019

Figures(8)

Novel expanded porphyrinoids with advanced structure features (such as multiple-inner-ring-fusion) have a wide range of benefits (such as multi-metal coordination and facile tunable aromaticity) not offered by their normal porphyrin analogues, and have found wide applications as sensors, fluorescent probes, novel ligands and functionalized NIR organic dyes in various research fields. However, the structures of these expanded porphyrinoids are scarce due to their limited synthetic accessibility. Herein, we summarized the lately reported efficient synthesis of novel expanded porphyrinoids with multipleinner-ring-fusion (up to six-inner-ring-fusion) and smaragdyrins with tunable aromaticity. Their synthesis is either based on an oxidative ring cyclization on linear/macrocyclic oligopyrroles containing N-confused pyrrole unit(s) or a straightforward double S_NAr reaction on readily available 3, 5-dibromoBODIPY, respectively.
- Porphyrinoids,
- Oligopyrroles,
- BODIPYs,
- Aromaticity,
- Macrocycles
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