Citation: Wang Chunhai, Huang Xiaoling, Liu Xueting, Gao Suqian, Zhao Bin, Yang Shangdong. Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates[J]. Chinese Chemical Letters, ;2020, 31(3): 677-680. doi: 10.1016/j.cclet.2019.08.011 shu

Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates

a.
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
b.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

yangshd@lzu.edu.cn

Received Date: 5 June 2019
Revised Date: 23 July 2019
Accepted Date: 8 August 2019
Available Online: 10 August 2019

Figures(7)

Hydroxyphosphoric acids display the unique biological activities, and they have some attractive prospects as clinical drug moleculars. Herein, a new approach for the synthesis of γ-oxo-phosphonates (the precursor of hydroxyphosphoric acid) has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process. Most important, this transformation is avoid of the external oxidants, and occurs very well under the sunlight irradiation, meanwhile the γ-oxo-phosphonate was easily derivatized to obtain γ-hydroxyphosphoric acid, thus highlights the synthesis value of this method.
- Photo catalysis,
- Phosphorus radical,
- Semipinacol rearragement,
- γ-Oxo-phosphonate
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