Citation: Li Gangyuan, Ye Hao, Zhu Fucheng, Geng Yan, Fan Jianzhong, Ma Jianping, Adachi Chihaya, Dong Yu-Bin. Luminescent Cu(Ⅰ) and Ag(Ⅰ) coordination polymers: Fast phosphorescence or thermally activated delayed fluorescence[J]. Chinese Chemical Letters, ;2019, 30(11): 1931-1934. doi: 10.1016/j.cclet.2019.08.006 shu

Luminescent Cu(Ⅰ) and Ag(Ⅰ) coordination polymers: Fast phosphorescence or thermally activated delayed fluorescence

Li Gangyuan ^a ,
Ye Hao ^b ,
Zhu Fucheng ^a ,
Geng Yan ^a,*, ,
Fan Jianzhong ^c ,
Ma Jianping ^a ,
Adachi Chihaya ^b,d,**, ,
Dong Yu-Bin ^a,*,

a.
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Ji'nan 250014, China
b.
Center for Organic Photonics and Electronics Research(OPERA), Kyushu University, Fukuoka 819-0395, Japan
c.
School of Physics and Electronics, Shandong Normal University, Ji'nan 250014, China
d.
Japan Science and Technology Agency ERATO, Adachi Molecular Exciton Engineering Project, International Institute for Carbon Neutral Energy Research(WPI-IbCNER), Kyushu University, Fukuoka 819-0395, Japan

^**

gengyan@sdnu.edu.cn

adachi@cstf.kyushu-u.ac.jp

yubindong@sdnu.edu.cn

Received Date: 25 June 2019
Revised Date: 29 July 2019
Accepted Date: 30 July 2019
Available Online: 9 November 2019

Figures(4)

By applying two donor-acceptor motif molecules, 5, 10-di(pyridin-4-yl)-5, 10-dihydrophenazine (L1) and 10, 10'-di(pyridin-3-yl)-10H, 10'H-9, 9'-spiroacridine (L2), as ligands and CuI/AgCF₃CO₂ as metal salt, we synthesized three coordination polymers, namely, {Cu₄(L1)₂I₄} (CP1), {Cu(L2)I·CHCl₃} (CP2) and {Ag(L2)CO₂CF₃·CHCl₃} (CP3). X-ray crystallographic analysis revealed that three coordination polymers all feature one-dimensional (1D) linear chains which are consisting of molecular boxlike units. In comparison with low photoluminescence quantum yield (PLQY) of two ligands, three coordination polymers, CP1, CP2 and CP3, present more intense photoluminescence with PLQY of 15%, 46% and 34% at room temperature respectively. The PL emission of CP1 and CP2 at room temperature could be attributed to the fast phosphorescence with lifetime both around 5 μs due to effective intersystem crossing (ISC). Whilst, it is worth noting that CP3 exhibit thermally activated delayed fluorescence (TADF) emission at room temperature.
- Coordination polymers,
- Phosphorescence,
- Thermally activated delayed fluorescence,
- Photoluminescence quantum yield,
- Intersystem crossing
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