Citation: Bao Wen-Hu, Wang Zheng, Tang Xiao, Zhang Yun-Fu, Tan Jia-Xi, Zhu Qin, Cao Zhong, Lin Ying-Wu, He Wei-Min. Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran[J]. Chinese Chemical Letters, ;2019, 30(12): 2259-2262. doi: 10.1016/j.cclet.2019.06.052 shu

Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran

Bao Wen-Hu ^a,1 ,
Wang Zheng ^a,1 ,
Tang Xiao ^a ,
Zhang Yun-Fu ^a ,
Tan Jia-Xi ^a,c ,
Zhu Qin ^b ,
Cao Zhong ^b ,
Lin Ying-Wu ^d ,
He Wei-Min ^a,*,

a.
Department of Chemistry, Hunan University of Science and Engineering, Yongzhou 425100, China
b.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China
c.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
d.
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

weiminhe2016@yeah.net

Received Date: 3 June 2019
Revised Date: 23 June 2019
Accepted Date: 27 June 2019
Available Online: 28 December 2019

Figures(5)

A simple and clean protocol for the synthesis of various alkyl and (hetero)aryl S-thiocarbamates was established. The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a green reaction medium, the avoidance of phosphorus-containing reductant, and the generation of harmless water and nitrogen as the sideproducts have given the present method atom-economy and environmental friendliness.
- Green chemistry,
- Hydroxide,
- Biomass,
- S-Thiocarbamates,
- 2-Methyltetrahydrofuran
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