Citation: Li Zhongping, Han Chunxiao. Palladium nanoflowers supported on amino-fullerene as novel catalyst for reduction of 4-nitrophenol[J]. Chinese Chemical Letters, ;2020, 31(3): 818-820. doi: 10.1016/j.cclet.2019.06.047 shu

Palladium nanoflowers supported on amino-fullerene as novel catalyst for reduction of 4-nitrophenol

Li Zhongping ^*, ,
Han Chunxiao

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

zl104@sxu.edu.cn

Received Date: 7 June 2019
Revised Date: 24 June 2019
Accepted Date: 25 June 2019
Available Online: 25 June 2019

Figures(3)

In this study, we report the synthesis of novel palladium nanoflowers (Pd NFs) on amino-functionalized fullerene (C₆₀-NH₂) by hydrothermal self-assembly growth using ethylenediamine (EA) as a functional reagent. The successful formation of Pd nanoflowers supported amino-functionalized fullerene (C₆₀-NH₂/Pd NFs) is evidenced by UV-vis and powder X-ray diffraction (XRD). The morphology of Pd NFs over the C₆₀-NH₂ surface has been investigated by high-resolution transmission electron microscopy (TEM) and Fourier-transform infrared (FT-IR) techniques. The supported Pd nanoflowers (Pd NFs/C₆₀-NH₂) exhibit remarkably superior catalytic activity toward the reduction of 4-nitrophenol (4-NP). It exhibits remarkable UV-vis spectra response from 4-nitrophenol to 4-aminophenol (4-AP) (99% in 2.0 min) with a turnover frequency of 12.35 min^-1. Its excellent catalytic stability and durability offer the promising application in catalysis.
- Palladium nanoflowers,
- Self-assembly,
- 4-Nitrophenol,
- Amino-functionalized fullerene,
- Catalyst
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