Citation: Xue Yuan, Liu Jinbao, Xie Maiying, Chen Fengfei, Zhou Mingan, Lin Hualin, Zhang Fan, Liu Shizhou, Wu Zhiqiao, Han Sheng. Effects of the chemical structure of surfactants on the stability of naphthenic oil-based metalworking fluids[J]. Chinese Chemical Letters, ;2020, 31(2): 345-348. doi: 10.1016/j.cclet.2019.06.031 shu

Effects of the chemical structure of surfactants on the stability of naphthenic oil-based metalworking fluids

Xue Yuan ^a ,
Liu Jinbao ^b ,
Xie Maiying ^a ,
Chen Fengfei ^a ,
Zhou Mingan ^a ,
Lin Hualin ^a ,
Zhang Fan ^a ,
Liu Shizhou ^c ,
Wu Zhiqiao ^a,*, ,
Han Sheng ^a,*,

a.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
b.
Department of Science and Technology, Shanghai Urban Construction Vocational College, Shanghai 201415, China
c.
College of Chemistry and Chemical Engineering, Shanxi Datong University, Datong 037009, China

qiaoqiaoyizu@163.com

hansheng654321@sina.com

Received Date: 20 May 2019
Revised Date: 9 June 2019
Accepted Date: 18 June 2019
Available Online: 19 June 2019

Figures(3)

In this study, various nonionic surfactants (NS) with different ethylene oxide (EO) numbers and tail lengths and its binary blends with anionic surfactants (AS) were used as emulsifiers for naphthenic oil to form the microemulsion metalworking fluids (MWFs), and the effects of them on the stability of the emulsion system were investigated by formulation triangle method. The results indicated that binary complex surfactants of NS and AS as emulsifiers exhibited better emulsifying effect than that of single NS. NS with different EO numbers and tail lengths presented various emulsifying effects. NS (EO = 10) exhibited the greatest number of stable formulations, especially the TX-10, but no linear relationship existed between the number of stable formulations and the tail length of NS. In addition, aromatic primary alcohol ethoxylate (APAE) series surfactants containing benzene groups similar to the cycloalkanes in the naphthenic oil so that presented the best emulsifying affect and the greatest number of stable formulations. The co-surfactant of sodium dodecyl benzene sulfonate (SDBS) binary blends with NS exerted the best synergistic effect, and the stable formulations numbers were ranged from 5 to 7, next sodium stearate (SS) comes last followed by sodium dodecyl sulfate (SDS-1) and sodium dodecyl sulfonate (SDS-2).
- Metal working fluid,
- Emulsion stability,
- Emulsifying effects,
- Stable formulations,
- Naphthenic oil
1. [1]
  C. Cheng, D. Phipps, R.M. Alkhaddar, Water Environ. J. 20 (2006) 227-232. doi: 10.1111/j.1747-6593.2005.00010.x
2. [2]
  J.P. Byers, Metalworking Fluids, CRC Press, Boca Raton, Florida, 2017.
3. [3]
  J.M. Benito, G. Ríos, E. Ortea, et al., Desalination 147 (2002) 5-10. doi: 10.1016/S0011-9164(02)00563-5
4. [4]
  H.M. Mobarak, E.N. Mohamad, H.H. Masjuki, et al., Renew. Sustain. Energy Rev. 33 (2014) 34-43. doi: 10.1016/j.rser.2014.01.062
5. [5]
  H.S. Abdalla, W. Baines, G. McIntyre, et al., Int. J. Adv. Manuf. Technol. 34 (2007) 21-33. doi: 10.1007/s00170-006-0585-4
6. [6]
  S. Ma, K. Kim, J. Huh, S. Lee, Y. Hong, Sep. Purif. Technol. 199 (2018) 289-297. doi: 10.1016/j.seppur.2018.02.005
7. [7]
  J.B. Zimmerman, A.F. Clarens, K.F. Hayes, et al., Environ. Sci. Technol. 37 (2003) 5278-5288. doi: 10.1021/es034437t
8. [8]
  E. Brinksmeier, D. Meyer, A.G. Huesmann-Cordes, et al., CIRP Ann. Manuf. Technol. 64 (2015) 605-628. doi: 10.1016/j.cirp.2015.05.003
9. [9]
  A.G. Naumov, V.N. Latyshev, V.S. Radnyuk, et al., J. Frict. Wear 36 (2015) 184-188. doi: 10.3103/S1068366615020129
10. [10]
  Y.M. Shashidhara, S.R. Jayaram, Tribol. Int. 43 (2010) 1073-1081. doi: 10.1016/j.triboint.2009.12.065
11. [11]
  R. Padmini, P.V. Krishna, G.K.M. Rao, Tribol. Int. 94 (2016) 490-501. doi: 10.1016/j.triboint.2015.10.006
12. [12]
  R. Katna, K. Singh, N. Agrawal, et al., Mater. Manuf. Process. 32 (2017) 1522-1527. doi: 10.1080/10426914.2017.1328119
13. [13]
  M. Nejadmansouri, S.M.H. Hosseini, M. Niakosari, et al., Colloids Surf. A: Physicochem. Eng. Asp. 506 (2016) 821-832. doi: 10.1016/j.colsurfa.2016.07.075
14. [14]
  N. Canter, Tribol. Lubrication Technol. 61 (2005) 10.
15. [15]
  S.A. Lawal, I.A. Choudhury, Y. Nukman, Int. J. Mach. Tools Manuf. 52 (2012) 1-12. doi: 10.1016/j.ijmachtools.2011.09.003
16. [16]
  H. Cohen, E.M. White, J. Occup. Environ. Hyg. 3 (2016) 501-507.
17. [17]
  A.F. Clarens, J.B. Zimmerman, G.A. Keoleian, et al., Environ. Sci. Technol. 42 (2008) 8534-8540. doi: 10.1021/es800791z
18. [18]
  J. Sharma, B.S. Sidhu, J. Clean. Prod. 66 (2014) 619-623. doi: 10.1016/j.jclepro.2013.11.042
19. [19]
  B.J. Bremmer, L. Plonsker, Bio-Based Lubricants: A Market Opportunity Study Update, Omni-Tech International Ltd., 2008.
20. [20]
  P. Bhowmik, U. Kumar, G. Arora, et al., J. Mater. Sci. Mech. Eng. 2 (2015) 1-5.
21. [21]
  S.A. Lawal, I.A. Choudhury, Y. Nukman, Int. J. Mach. Tools Manuf. 52 (2012) 1-12. doi: 10.1016/j.ijmachtools.2011.09.003
22. [22]
  Y. Wang, C. Li, Y. Zhang, et al., J. Clean. Prod. 127 (2016) 487-499. doi: 10.1016/j.jclepro.2016.03.121
23. [23]
  J.M. Benito, A. Cambiella, A. Lobo, et al., Clean Technol. Environ. 12 (2010) 31-41. doi: 10.1007/s10098-009-0219-2
24. [24]
  T.C.G. Kibbey, K.F. Hayes, J. Colloid Interface Sci. 197 (1998) 210-220. doi: 10.1006/jcis.1997.5257
25. [25]
  J. Weiss, J.N. Coupland, D. Brathwaite, et al., Colloids Surf. A: Physicochem. Eng. Asp. 121 (1997) 53-60. doi: 10.1016/S0927-7757(96)03742-9
1. [1]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
2. [2]
  Xiaomeng Hu , Jie Yu , Lijie Sun , Linfeng Zhang , Wei Zhou , Dongpeng Yan , Xinrui Wang . Synthesis of an AVB@ZnTi-LDH composite with synergistically enhance UV blocking activity and high stability for potential application in sunscreen formulations. Chinese Chemical Letters, 2024, 35(11): 109466-. doi: 10.1016/j.cclet.2023.109466
3. [3]
  Qiaojia GUO , Junkai CAI , Chunying DUAN . Effects of anions on the structural regulation of Zn-salen-modified metal-organic cage. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2203-2211. doi: 10.11862/CJIC.20240209
4. [4]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
5. [5]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
6. [6]
  Haobo Wang , Fei Wang , Yong Liu , Zhongxiu Liu , Yingjie Miao , Wanhong Zhang , Guangxin Wang , Jiangtao Ji , Qiaobao Zhang . Emerging natural clay-based materials for stable and dendrite-free lithium metal anodes: A review. Chinese Chemical Letters, 2025, 36(2): 109589-. doi: 10.1016/j.cclet.2024.109589
7. [7]
  Xin Chen , Meng Zhao , Yan-Yuan Jia . Stable Eu(III)-based metal-organic framework for fluorescence sensing of benzaldehyde and its analogues. Chinese Journal of Structural Chemistry, 2025, 44(3): 100445-100445. doi: 10.1016/j.cjsc.2024.100445
8. [8]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
9. [9]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
10. [10]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
11. [11]
  Yixuan Wang , Jiexin Li , Zhihao Shang , Chengcheng Feng , Jianmin Gu , Maosheng Ye , Ran Zhao , Danna Liu , Jingxin Meng , Shutao Wang . Wettability-driven synergistic resistance of scale and oil on robust superamphiphobic coating. Chinese Chemical Letters, 2024, 35(7): 109623-. doi: 10.1016/j.cclet.2024.109623
12. [12]
  Yujuan Zhao , Zaiwang Zhao . Monolayer mesoporous nanosheets with surface asymmetry via a dual-emulsion-directed monomicelle assembly. Chinese Journal of Structural Chemistry, 2024, 43(2): 100238-100238. doi: 10.1016/j.cjsc.2024.100238
13. [13]
  Tao Tang , Chen Li , Sipu Li , Zhong Qiu , Tianqi Yang , Beirong Ye , Shaojun Shi , Chunyang Wu , Feng Cao , Xinhui Xia , Minghua Chen , Xinqi Liang , Xinping He , Xin Liu , Yongqi Zhang . One-step constructing advanced N-doped carbon@metal nitride as ultra-stable electrocatalysts via urea plasma under room temperature. Chinese Chemical Letters, 2024, 35(11): 109887-. doi: 10.1016/j.cclet.2024.109887
14. [14]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
15. [15]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
16. [16]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
17. [17]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
18. [18]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
19. [19]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
20. [20]
  Kongchuan Wu , Dandan Lu , Jianbin Lin , Ting-Bin Wen , Wei Hao , Kai Tan , Hui-Jun Zhang . Elucidating ligand effects in rhodium(Ⅲ)-catalyzed arene–alkene coupling reactions. Chinese Chemical Letters, 2024, 35(5): 108906-. doi: 10.1016/j.cclet.2023.108906

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1411)
HTML views(209)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142