Citation: Xie Shiliang, Gao Xiaotong, Zhou Feng, Wu Haihong, Zhou Jian. Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions[J]. Chinese Chemical Letters, ;2020, 31(2): 324-328. doi: 10.1016/j.cclet.2019.05.060 shu

Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions

Xie Shiliang ^a ,
Gao Xiaotong ^a ,
Zhou Feng ^a,b,*, ,
Wu Haihong ^a,*, ,
Zhou Jian ^a,b,c,*,

a.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, China
b.
Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
c.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

fzhou@chem.ecnu.edu.cn

hhwu@chem.ecnu.edu.cn

jzhou@chem.ecnu.edu.cn

Received Date: 18 March 2019
Revised Date: 22 May 2019
Accepted Date: 29 May 2019
Available Online: 1 June 2019

Figures(2)

An enantioselective carboxylative cyclization of propargylic alcohols and CO₂ was realized under mild conditions, based on a kinetic resolution strategy, which enabled the synthesis of chiral cyclic carbonates and propargylic alcohols with promising yield and enantioselectivity simultaneously.
- Carbon dioxide,
- Kinetic resolution,
- Propargylic alcohols,
- Cyclic carbonates
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