Citation: Song Yanying, Wang Lili, Duan Zheng, Mathey François. Divergent intramolecular reactions between phosphines and alkynes[J]. Chinese Chemical Letters, ;2020, 31(2): 329-332. doi: 10.1016/j.cclet.2019.05.053 shu

Divergent intramolecular reactions between phosphines and alkynes

College of Chemistry and Molecular Engineering, International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China

duanzheng@zzu.edu.cn

Received Date: 29 April 2019
Revised Date: 18 May 2019
Accepted Date: 27 May 2019
Available Online: 28 May 2019

Figures(6)

A divergent intramolecular reaction of phosphine tethered alkyne in protic solvent was developed. This provided a novel and simple access to a large variety of (Z)-alkenylphosphine oxides and phospholane oxides. Our preliminary studies suggested that these divergent reactions are closely related to the reaction condition and molecular structure. A possible mechanism of C-P bond cleavage of a pentacoordinated hydroxyphosphorane intermediate was proposed.
- C-P bond cleavage,
- Phosphine,
- Alkyne,
- Alkenylphosphine,
- Phospholane
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