Citation: Zhang Da, Chen Luming, Yao Yaochun, Liang Feng, Qu Tao, Ma Wenhui, Yang Bing, Dai Yongnian, Lei Yong. A novel approach to synthesize porous graphene by the transformation and deoxidation of oxygen-containing functional groups[J]. Chinese Chemical Letters, ;2019, 30(12): 2313-2317. doi: 10.1016/j.cclet.2019.05.047 shu

A novel approach to synthesize porous graphene by the transformation and deoxidation of oxygen-containing functional groups

Zhang Da ^a,1 ,
Chen Luming ^a,1 ,
Yao Yaochun ^a ,
Liang Feng ^a,b,*, ,
Qu Tao ^a,b ,
Ma Wenhui ^a ,
Yang Bing ^a ,
Dai Yongnian ^a ,
Lei Yong ^c

a.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
b.
State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
c.
Institute of Physics & IMN Macro Nanos(ZIK), Ilmenau University of Technology, Ilmenau 98693, Germany

liangfeng@kmust.edu.cn

Received Date: 15 March 2019
Revised Date: 23 April 2019
Accepted Date: 22 May 2019
Available Online: 24 December 2019

Figures(4)

In this study, impurity-free porous graphene (PG) with intrinsic pore structure was synthesized through a facile acid-alkali etching-assisted sonication approach. The pore structure appears on the surface of graphene sheets due to intrinsic defects of graphene. The PG possessed an extremely high specific surface area of 2184 m²/g, the size of~5 μm and layer numbers of 3-8. Additionally, PG contained micropores and mesopores simultaneously, with an average pore diameter of approximately 3 nm. The effects of acid, alkali, and ultrasound treatment on PG preparation were elucidated by transmission electron microscopy and fourier transform infrared spectroscopy. First, in an acidic solution, oxygen-containing functional groups (hydroxyls, carboxyl, and epoxides) were formed due to the hydrolysis of sulfate and continuous transformations of these functional groups on graphene oxide. Second, under the synergistic effects of alkali and ultrasound treatment, PG was obtained due to the loss of carboxyl and epoxide groups. A new route for preparing PG was provided by the proposed method.
- Hydrolysis,
- Deoxidation,
- Ultrasound,
- Oxygen-containing functional group,
- Porous graphene
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