Citation: Jiang Fangling, Peng Hao, Li Cheng, Fu Haiying, Wu Guozhong. Temperature-dependent structural changes of[Bmim]FeCl₄ magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure[J]. Chinese Chemical Letters, ;2020, 31(3): 801-804. doi: 10.1016/j.cclet.2019.05.028 shu

Temperature-dependent structural changes of[Bmim]FeCl₄ magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure

Jiang Fangling ^a,*, ,
Peng Hao ^b ,
Li Cheng ^b ,
Fu Haiying ^b ,
Wu Guozhong ^b,*,

a.
Shanghai Jiao Tong University, Institute of Fuel Cells, Shanghai 200240, China
b.
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China

jiangfangling33@163.com

wuguozhong@sinap.ac.cn

Received Date: 26 April 2019
Revised Date: 13 May 2019
Accepted Date: 16 May 2019
Available Online: 16 May 2019

Figures(2)

The temperature-dependent structural changes in 1-butyl-3-methylimidazolium tetrafluoride ([Bmim]FeCl₄) magnetic ionic liquid (MIL) were investigated by using in-situ X-ray absorption fine structure (XAFS) combined with Raman spectroscopy and DFTcalculations. XAFS results revealed that the coordination number and bond length of Fe-Cl in the anion of[Bmim]FeCl₄ MIL decreased with increments in temperature. These results directly reflected the dissociation of tetrahedral structure[FeCl₄]^-, and the formation of bridge-chain[Fe₂Cl₅]⁺, and[FeCl₂]⁺ species in the anion of[Bmim]FeCl₄ MIL. These behaviors indicated that[FeCl₄]^- dissociation was endothermic, and was promoted by increased temperature. The results obtained through XAFS were in agreement with those obtained through Raman spectroscopy and DFT calculations.
- Magnetic ionic liquids,
- Temperature-dependent,
- Structure,
- Change,
- XAFS
1. [1]
  T. Welton, Chem. Rev. 99(1999) 2071-2083. doi: 10.1021/cr980032t
2. [2]
  E. Santos, J. Albo, A. Irabien, RSC Adv. 4(2014) 40008-40018. doi: 10.1039/C4RA05156D
3. [3]
  A. Branco, L.C. Branco, F. Pina, Chem. Commun. 47(2011) 2300-2302. doi: 10.1039/C0CC03892J
4. [4]
  S.A. Sakal, Y.Z. Lu, X.C. Jiang, et al., J. Chem. Eng. Data 59(2014) 533-539. doi: 10.1021/je400076x
5. [5]
  K.D. Clark, O. Nacham, H.L. Yu, et al., Anal. Chem. 87(2015) 1552-1559. doi: 10.1021/ac504260t
6. [6]
  S. Hayashi, H.O. Hamaguchi, Chem. Lett. 33(2004) 1590-1591. doi: 10.1246/cl.2004.1590
7. [7]
  Y. Yoshid, J. Fujii, K. Muroi, et al., Synthetic Met. 153(2005) 421-424. doi: 10.1016/j.synthmet.2005.07.321
8. [8]
  N.H. Ko, J.S. Lee, E.S. Huh, et al., Energy Fuel. 22(2008) 1687-1690. doi: 10.1021/ef7007369
9. [9]
  S.D. Sun, X.L. Li, J. Am. Oil. Chem. Soc. 93(2016) 757-764. doi: 10.1007/s11746-016-2826-5
10. [10]
  C.I. Daniel, F.V. Chavez, G. Feio, et al., J. Phys. Chem. B 117(2013) 11877-11884. doi: 10.1021/jp4078536
11. [11]
  C.I. Daniel, F.V. Chavez, C.A.M. Portugal, et al., J. Phys. Chem. B 119(2015) 11740-11747. doi: 10.1021/acs.jpcb.5b04772
12. [12]
  A. Garcia-Saiz, I. de Pedro, J.A. Blanco, et al., J. Phys. Chem. B 117(2013) 3198-3206. doi: 10.1021/jp3114623
13. [13]
  J. Dupont, J. Braz. Chem. Soc. 15(2014) 341-350. doi: 10.1590/S0103-50532004000300002
14. [14]
  Y. Yoshida, G.Z. Saito, J. Mater. Chem. 16(2006) 1254-1262. doi: 10.1039/b515391c
15. [15]
  Y. Yoshida, A. Otsuka, G. Saito, et al., Chem. Soc. Jpn. 78(2005) 1921-1928. doi: 10.1246/bcsj.78.1921
16. [16]
  A. Garcia-Saiz, P. Migowski, O. Vallcorba, et al., Chem. Eur. J. 20(2014) 72-76. doi: 10.1002/chem.201303602
17. [17]
  Y.C. Pei, Y. Cao, Y.J. Huang, et al., Sci China-Chem. 59(2016) 587-593. doi: 10.1007/s11426-016-5577-0
18. [18]
  E. Santos, J. Albo, A. Rosatella, et al., J. Chem. Technol. Biot. 89(2014) 866-871. doi: 10.1002/jctb.4323
19. [19]
  M.M. Cruz, R.P. Borges, M. Godinho, et al., Fluid Phase Equilibr. 350(2013) 43-50. doi: 10.1016/j.fluid.2013.03.001
20. [20]
  I. de Pedro, D.P. Rojas, J. Albo, et al., J. Phys. -Condens. Mat. 22(2010).
21. [21]
  B.D. James, S.M. Juraja, J. Liesegang, et al., Inorg. Chim. Acta 312(2001) 88-92. doi: 10.1016/S0020-1693(00)00328-5
22. [22]
  C.S.M. Partiti, H.R. Rechenberg, Hyperfine Interact. 70(1992) 1075-1078. doi: 10.1007/BF02397515
23. [23]
  R.H. Herber, I. Nowik, M.E. Kostner, et al., Int. J. Mol. Sci.12(2011) 6397-6406. doi: 10.3390/ijms12106397
24. [24]
  Y. Zou, H.J. Xu, G.Z. Wu, et al., J. Phys. Chem. B 113(2009) 2066-2070. doi: 10.1021/jp809788u
25. [25]
  F.L. Jiang, C. Li, H.Y. Fu, et al., J. Phys. Chem. C 119(2015) 22724-22731. doi: 10.1021/acs.jpcc.5b07325
26. [26]
  A.J. Carmichael, C. Hardacre, J.D. Holbrey, et al., Anal. Chem. 71(1999) 4572-4574. doi: 10.1021/ac990332q
27. [27]
  J.J. Rehr, R.C. Albers, Rev. Mod. Phys. 72(2000) 621-654. doi: 10.1103/RevModPhys.72.621
28. [28]
  C. Lee, W.T. Yang, R.G. Parr, Phys. Rev. B 17(1998) 785-789. doi: 10.1103/PhysRevB.37.785
29. [29]
  P.J. Hay, W.R. Wadt, J. Chem. Phys. 82(1985) 270-284. doi: 10.1063/1.448799
30. [30]
  M.J. Frisch, G.W. Trucks, H.B. Schlegel, et al., Gaussian 09, Revision C.01 Wallingford CT, 2009.
31. [31]
  H. Wang, R.Y. Yan, Z.X. Li, et al., Catal. Commun. 11(2011) 763-767. doi: 10.1016/j.catcom.2010.02.011
32. [32]
  M.S. Sitze, E.R. Schreiter, E.V. Patterson, et al., Inorg. Chem. 40(2001) 2298-2304. doi: 10.1021/ic001042r
33. [33]
  J.Z. Yang, W.G. Xu, Q.G. Zhang, et al., J. Chem. Thermodyn. 35(2003) 1855-1860. doi: 10.1016/j.jct.2003.07.002
34. [34]
  G.N. Papatheodorou, G.A. Voyiatzis, Chem. Phys. Lett. 303(1999) 151-156. doi: 10.1016/S0009-2614(99)00213-4
35. [35]
  R.G. Shulman, Y. Yafet, P. Eisenberger, et al., Proc. Natl. Acad. Sci. U. S. A. 73(1976) 1384-1388. doi: 10.1073/pnas.73.5.1384
36. [36]
  T.E. Westre, P. Kennepohl, J.G. DeWitt, et al., J. Am. Chem. Soc.119(1997) 6297-6314. doi: 10.1021/ja964352a
37. [37]
  R.A. Blair, W.A. Goddard, Phys. Rev. B 22(1980) 2767-2776. doi: 10.1103/PhysRevB.22.2767
38. [38]
  M. Wilke, F. Farges, P.E. Petit, et al., Am. Mineral. 86(2001) 714-730. doi: 10.2138/am-2001-5-612
39. [39]
  C. Li, Y.X. Wang, X.J. Guo, et al., J. Phys. Chem. C 118(2014) 3140-3144. doi: 10.1021/jp4115942
1. [1]
  Yu Hong , Yuqian Jiang , Chenhuan Yuan , Decai Wang , Yimeng Sun , Jian Jiang . Unraveling temperature-dependent supramolecular polymorphism of naphthalimide-substituted benzene-1,3,5-tricarboxamide derivatives. Chinese Chemical Letters, 2024, 35(12): 109909-. doi: 10.1016/j.cclet.2024.109909
2. [2]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
3. [3]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
4. [4]
  Fengshun Wang , Huachao Ji , Zefei Wu , Kang Chen , Wenqi Gao , Chen Wang , Longlu Wang , Jianmei Chen , Dafeng Yan . The advanced development of one-dimensional transition metal dichalcogenide nanotubes: From preparation to application. Chinese Chemical Letters, 2025, 36(5): 109898-. doi: 10.1016/j.cclet.2024.109898
5. [5]
  Qiao Wang , Ziling Jiang , Chuang Yu , Liping Li , Guangshe Li . Research progress of inorganic sodium ion conductors for solid-state batteries. Chinese Chemical Letters, 2025, 36(6): 110006-. doi: 10.1016/j.cclet.2024.110006
6. [6]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2023.100212
7. [7]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
8. [8]
  Hao-Cong Li , Ming Zhang , Qiyan Lv , Kai Sun , Xiao-Lan Chen , Lingbo Qu , Bing Yu . Homogeneous catalysis and heterogeneous separation: Ionic liquids as recyclable photocatalysts for hydroacylation of olefins. Chinese Chemical Letters, 2025, 36(2): 110579-. doi: 10.1016/j.cclet.2024.110579
9. [9]
  Jingyu Shi , Xiaofeng Wu , Yutong Chen , Yi Zhang , Xiangyan Hou , Ruike Lv , Junwei Liu , Mengpei Jiang , Keke Huang , Shouhua Feng . Structure factors dictate the ionic conductivity and chemical stability for cubic garnet-based solid-state electrolyte. Chinese Chemical Letters, 2025, 36(5): 109938-. doi: 10.1016/j.cclet.2024.109938
10. [10]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
11. [11]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
12. [12]
  Dongping Song , Tao Tu . The role of oceanic carbon pumps in Earth’s climate system: Impact and feedback under climate change. Chinese Chemical Letters, 2025, 36(8): 111300-. doi: 10.1016/j.cclet.2025.111300
13. [13]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
14. [14]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
15. [15]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
16. [16]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
17. [17]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
18. [18]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
19. [19]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
20. [20]
  Teng-Yu Huang , Junliang Sun , De-Xian Wang , Qi-Qiang Wang . Recent progress in chiral zeolites: Structure, synthesis, characterization and applications. Chinese Chemical Letters, 2024, 35(12): 109758-. doi: 10.1016/j.cclet.2024.109758

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1553)
HTML views(47)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Temperature-dependent structural changes of[Bmim]FeCl4 magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure

Metrics

通讯作者: 陈斌, bchen63@163.com

Temperature-dependent structural changes of[Bmim]FeCl₄ magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure