Citation: Liu Yuan, Li Taotao, Ling Chuxuan, Chen Zhu, Deng Yan, He Nongyue. Electrochemical sensor for Cd²⁺ and Pb²⁺ detection based on nano-porous pseudo carbon paste electrode[J]. Chinese Chemical Letters, ;2019, 30(12): 2211-2215. doi: 10.1016/j.cclet.2019.05.020 shu

Electrochemical sensor for Cd²⁺ and Pb²⁺ detection based on nano-porous pseudo carbon paste electrode

Liu Yuan ^a,b ,
Li Taotao ^c ,
Ling Chuxuan ^d ,
Chen Zhu ^a,b ,
Deng Yan ^a,b,*, ,
He Nongyue ^a,b,*,

a.
State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China
b.
Hunan Key Laboratory of Biomedical Nanomaterials and Devices, Hunan University of Technology, Zhuzhou 412007, China
c.
Hunan Provincial Key Lab of Dark Tea and Jin-Hua, School of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, China
d.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

hndengyan@126.com

nyhe1958@163.com

Received Date: 19 April 2019
Revised Date: 6 May 2019
Accepted Date: 7 May 2019
Available Online: 8 December 2019

Figures(6)

An electrochemical sensor based on self-made nano-porous pseudo carbon paste electrode (nano-PPCPE) has been successfully developed, and used to detect Cd²⁺ and Pb²⁺. The experimental results showed that the electrochemical performance of nano PPCPE is evidently better than both glassy carbon electrode(GCE) and pure carbon paste electrode (CPE). Then the prepared nano-PPCPE was applied to detect Cd²⁺ and Pb²⁺ in standard solution, the results showed that the electrodes can quantitatively detect trace Cd²⁺ and Pb²⁺, which has great significance in electrochemical analysis and detection. The linear ranges between the target ions concentration and the DPASV current were from 0.1-3.0 μmol/L, 0.05-4.0 μmol/L for Cd²⁺ and Pb²⁺, respectively. And the detection limits were 0.0780 μmol/L and 0.0292 μmol/L, respectively. Moreover, the preparation of the nano-PPCPE is cheap, simple and has important practical value.
- Nano-porous pseudo carbon paste electrode (nano-PPCPE),
- Cadmium ions,
- Lead ions,
- Sensor,
- Detection
1. [1]
  J. Li, D. Yang, X. Zhu, et al., Nanosci. Nanotechnol. Lett. 9 (2017) 1363-1367. doi: 10.1166/nnl.2017.2451
2. [2]
  X. Liu, Y. Qin, G. Xing, et al., Nanosci. Nanotechnol. Lett. 9 (2017) 989-997. doi: 10.1166/nnl.2017.2424
3. [3]
  W. Lei, J. Nanosci. Nanotechnol. 18 (2018) 7349-7354. doi: 10.1166/jnn.2018.16054
4. [4]
  J. Li, D. Yang, X. Zhu, et al., Nanosci. Nanotechnol. Lett. 9 (2017) 1023-1027. doi: 10.1166/nnl.2017.2427
5. [5]
  M.G. Gang, R.B.V. Chalapathy, J. Kim, et al., Nanosci. Nanotechnol. Lett. 10 (2018) 503-511. doi: 10.1166/nnl.2018.2687
6. [6]
  A.K. Patra, B. Biplab, B. Asim, J. Nanosci. Nanotechnol. 18 (2018) 256-263. doi: 10.1166/jnn.2018.14555
7. [7]
  J.C.L. Sousa, M.G. Vivas, B.R.C. Vale, et al., J. Nanosci. Nanotechnol. 18 (2018) 651-658. doi: 10.1166/jnn.2018.13932
8. [8]
  H.D. Vu, L.H. Nguyen, T.D. Nguyen, et al., Ionics 21 (2015) 571-578. doi: 10.1007/s11581-014-1199-8
9. [9]
  W. Wang, Y. Cai, B. Li, et al., Chin. Chem. Lett. 29 (2018) 111-114. doi: 10.1016/j.cclet.2017.05.009
10. [10]
  P.J. Mafa, A.O. Idris, N. Mabuba, et al., Talanta 153 (2016) 99-106. doi: 10.1016/j.talanta.2016.03.003
11. [11]
  Y. Yang, Y. Zhang, J. Shen, et al., Chin. Chem. Lett. 27 (2016) 891-895. doi: 10.1016/j.cclet.2016.01.060
12. [12]
  Y. Liu, Y. Deng, H. Dong, et al., Sci. China Chem. 60 (2017) 329-337. doi: 10.1007/s11426-016-0253-2
13. [13]
  L. Wang, Q. You, S. Yao, et al., J. Biobased Mater. Bioenergy 12 (2018) 266-270. doi: 10.1166/jbmb.2018.1771
14. [14]
  Y. Huang, S. Li, S. Yu, et al., J. Biobased Mater. Bioenergy 12 (2018) 425-431. doi: 10.1166/jbmb.2018.1791
15. [15]
  Z. Yuan, J. Yang, H. Zhou, et al., Nanosci. Nanotechnol. Lett. 10 (2018) 982-987. doi: 10.1166/nnl.2018.2736
16. [16]
  Q. Chen, M. Kang, Z. Liu, et al., J. Biobased Mater. Bioenergy 11 (2017) 356-363. doi: 10.1166/jbmb.2017.1676
17. [17]
  X. Zeng, L. Wu, W. Li, et al., J. Biobased Mater. Bioenergy 11 (2017) 154-158. doi: 10.1166/jbmb.2017.1649
18. [18]
  K.D. Bhatt, D.J. Vyas, B.A. Makwana, et al., Chin. Chem. Lett. 27 (2016) 731-737. doi: 10.1016/j.cclet.2016.01.012
19. [19]
  H. Dai, N. Wang, D. Wang, et al., Chem. Eng. J. 299 (2016) 150-155. doi: 10.1016/j.cej.2016.04.083
20. [20]
  M. Roushani, A. Valipour, Z. Saedi, Sensor. Actuat. B -Chem. 233 (2016) 419-425. doi: 10.1016/j.snb.2016.04.106
21. [21]
  A. Zahid, A. Shah, F.J. Iftikhar, et al., Electrochim. Acta 235 (2017) 72-78. doi: 10.1016/j.electacta.2017.03.120
22. [22]
  P.S. Adarakatti, A. Siddaramanna, P. Malingappa, Anal. Methods 11 (2019) 813-820. doi: 10.1039/C8AY02648C
23. [23]
  S.A. Kitte, S.P. Li, A. Nsabimana, et al., Talanta 191 (2019) 485-490. doi: 10.1016/j.talanta.2018.08.066
24. [24]
  N. Rahbar, Z. Ramezani, J. Ghanavati., Chin. Chem. Lett. 27 (2016) 837-842. doi: 10.1016/j.cclet.2016.04.017
25. [25]
  Y. Zheng, C. Li, X. Ding, et al., Chin. Chem. Lett. 28 (2017) 1473-1478. doi: 10.1016/j.cclet.2017.03.014
26. [26]
  V. Antunovic, M. Ilic, R. Baosic, et al., PLoS One 14 (2019)e0210904. doi: 10.1371/journal.pone.0210904
27. [27]
  Y. Lai, C. Zhang, Y. Deng, et al., Chin. Chem. Lett. 30 (2019) 160-162. doi: 10.1016/j.cclet.2018.07.011
28. [28]
  Y. Yao, H. Wu, J. Ping, Food Chem. 274 (2019) 8-15. doi: 10.1016/j.foodchem.2018.08.110
29. [29]
  G. Yang, Y. Lai, Z. Xiao, et al., Chin. Chem. Lett. 29 (2018) 1857-1860. doi: 10.1016/j.cclet.2018.11.030
30. [30]
  L. Xu, N. He, J. Du, et al., Anal. Chim. Acta 634 (2009) 49-53. doi: 10.1016/j.aca.2008.12.029
31. [31]
  L. Xu, J. Du, Y. Deng, et al., J. Biomed. Nanotechnol. 8 (2012) 1006-1011. doi: 10.1166/jbn.2012.1456
32. [32]
  L. Xu, J. Du, Y. Deng, et al., Electrochem. Commun. 12 (2010) 1329-1332. doi: 10.1016/j.elecom.2010.07.012
33. [33]
  N. He, L. Xu, J. Du, et al., Sens. Lett. 9 (2011) 199-205. doi: 10.1166/sl.2011.1449
34. [34]
  L. Xu, J. Du, N. He, et al., J. Nanosci. Nanotechnol. 9 (2009) 2698-2703. doi: 10.1166/jnn.2009.dk09
35. [35]
  L. Xu, J. Du, Y. Deng, et al., Adv. Sci. Lett. 4 (2011) 104-107. doi: 10.1166/asl.2011.1180
36. [36]
  Y. Deng, W. Wang, L. Zhang, et al., J. Biomed. Nanotechnol. 9 (2013) 318-321. doi: 10.1166/jbn.2013.1487
37. [37]
  X. Xiao, K. Liu, W. Wang, et al., J. Bionanosci. 8 (2014) 133-136. doi: 10.1166/jbns.2014.1210
38. [38]
  Y. Liu, K. Liu, H. Dong, et al., Nanosci. Nanotechnol. Lett. 8 (2016) 785-790. doi: 10.1166/nnl.2016.2264
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical sensor for Cd2+ and Pb2+ detection based on nano-porous pseudo carbon paste electrode

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通讯作者: 陈斌, bchen63@163.com

Electrochemical sensor for Cd²⁺ and Pb²⁺ detection based on nano-porous pseudo carbon paste electrode