Citation: Zhao Tao, Ren Yuan, Jia Guangyou, Zhao Yuye, Fan Yuchi, Yang Jianping, Zhang Xin, Jiang Wan, Wang Lianjun, Luo Wei. Facile synthesis of mesoporous WO₃@graphene aerogel nanocomposites for low-temperature acetone sensing[J]. Chinese Chemical Letters, ;2019, 30(12): 2032-2038. doi: 10.1016/j.cclet.2019.05.006 shu

Facile synthesis of mesoporous WO₃@graphene aerogel nanocomposites for low-temperature acetone sensing

Zhao Tao ^a ,
Ren Yuan ^b ,
Jia Guangyou ^a ,
Zhao Yuye ^a ,
Fan Yuchi ^c ,
Yang Jianping ^a ,
Zhang Xin ^a ,
Jiang Wan ^a,c,d ,
Wang Lianjun ^a,*, ,
Luo Wei ^a,c,*,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
b.
Department of Chemistry, State Key Laboratory of Molecular Engineering of Polymers, iChEM, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
c.
Institute of Functional Materials, Donghua University, Shanghai 201620, China
d.
School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, China

wanglj@dhu.edu.cn

wluo@dhu.edu.cn

Received Date: 12 April 2019
Revised Date: 30 April 2019
Accepted Date: 6 May 2019
Available Online: 6 December 2019

Figures(5)

Nanocomposites constructed by combining mesoporous metal oxides and graphene have received tremendous attention in wide fields of catalysis, energy storage and conversion, gas sensing and so on. Herein, we present a facile interface-induced co-assembly process to synthesize the mesoporous WO₃@graphene aerogel nanocomposites (denoted as mWO₃@GA), in which graphene aerogel (GA) was used as a macroporous substrate, mesoporous WO₃ was uniformly coated on both sides of graphene sheets through a solvent evaporation-induced self-assembly (EISA) strategy using diblock copolymer poly(ethylene oxide)-b-polystyrene (PEO-b-PS) as a template. The resultant mWO₃@GA nanocomposites possess well-interconnected macroporous graphene networks covered by mesoporous WO₃ layer with a uniform pore size of 19 nm, high surface area of 167 m²/g and large pore volume of 0.26 cm³/g. The gas sensing performance of mWO₃@GA nanocomposites toward acetone and other gases was studied, showing a high selectivity and great response to acetone at low temperature of 150℃, which could be developed as a promising candidate as novel sensors for VOCs detection.
- Mesoporous materials,
- Tungsten oxide,
- Graphene,
- Gas sensing,
- Acetone
1. [1]
  S.J. Kim, S.J. Choi, J.S. Jang, et al., Acc. Chem. Res. 50 (2017) 1587-1596. doi: 10.1021/acs.accounts.7b00047
2. [2]
  Y. Zhao, Z.X. Low, S. Feng, et al., Nanoscale 9 (2017) 5433-5444. doi: 10.1039/C6NR09779K
3. [3]
  V.K. Tomer, S. Duhan, J. Mater. Chem. A 4 (2016) 1033-1043. doi: 10.1039/C5TA08336B
4. [4]
  E. Singh, M. Meyyappan, H.S. Nalwa, ACS Appl. Mater. Interfaces 9 (2017) 34544-34586. doi: 10.1021/acsami.7b07063
5. [5]
  N. Barsan, D. Koziej, U. Weimar, Sens. Actuators B:Chem. 121 (2007) 18-35. doi: 10.1016/j.snb.2006.09.047
6. [6]
  M.H. Sun, S.Z. Huang, L.H. Chen, et al., Chem. Soc. Rev. 45 (2016) 3479-3563. doi: 10.1039/C6CS00135A
7. [7]
  H. Feng, C. Li, T. Li, et al., Sens. Actuators B:Chem. 243 (2017) 704-714. doi: 10.1016/j.snb.2016.12.043
8. [8]
  W.T. Koo, S.J. Choi, S.J. Kim, et al., J. Am. Chem. Soc. 138 (2016) 13431-13437. doi: 10.1021/jacs.6b09167
9. [9]
  J. Li, X. Liu, J. Cui, et al., ACS Appl. Mater. Interfaces 7 (2015) 10108-10114. doi: 10.1021/am508121p
10. [10]
  X. Zhou, Y. Zhu, W. Luo, et al., J. Mater. Chem. A 4 (2016) 15064-15071. doi: 10.1039/C6TA05687C
11. [11]
  X. Xiao, L. Liu, J. Ma, et al., ACS Appl. Mater. Interfaces 10 (2018) 1871-1880. doi: 10.1021/acsami.7b18830
12. [12]
  C. Li, N.S. Colella, J.J. Watkins, ACS Appl. Mater. Interfaces 7 (2015) 13180-13188. doi: 10.1021/acsami.5b03240
13. [13]
  Y. Li, W. Luo, N. Qin, et al., Angew. Chem. Int. Ed. 53 (2014) 9035-9040. doi: 10.1002/anie.201403817
14. [14]
  Y. Zhu, Y. Zhao, J. Ma, et al., J. Am. Chem. Soc. 139 (2017) 10365-10373. doi: 10.1021/jacs.7b04221
15. [15]
  J.H. Ma, Y. Ren, X.R. Zhou, et al., Adv. Funct. Mater. 28 (2018) 1705268. doi: 10.1002/adfm.201705268
16. [16]
  S. Cong, F. Geng, Z. Zhao, Adv. Mater. 28 (2016) 10518-10528. doi: 10.1002/adma.201601109
17. [17]
  Z.F. Huang, J. Song, L. Pan, et al., Adv. Mater. 27 (2015) 5309-5327. doi: 10.1002/adma.201501217
18. [18]
  D.R. Miller, S.A. Akbar, P.A. Morris, Sens. Actuators B:Chem. 204 (2014) 250-272. doi: 10.1016/j.snb.2014.07.074
19. [19]
  D. Sun, Y. Luo, M. Debliquy, C. Zhang, Beilstein J. Nanotechnol. 9 (2018) 2832-2844. doi: 10.3762/bjnano.9.264
20. [20]
  Y. Xia, R. Li, R. Chen, et al., Sensors 18 (2018) 1456. doi: 10.3390/s18051456
21. [21]
  B. Zhang, R.W. Fu, M.Q. Zhang, et al., Sens. Actuators B:Chem. 109 (2005) 323-328. doi: 10.1016/j.snb.2004.12.066
22. [22]
  Y. Tang, Z. Zhao, H. Hu, et al., ACS Appl. Mater. Interfaces7 (2015) 27432-27439. doi: 10.1021/acsami.5b09314
23. [23]
  K.S. Novoselov, A.K. Geim, S.V. Morozov, et al., Science 306 (2004) 666-669. doi: 10.1126/science.1102896
24. [24]
  Y. Xu, G. Shi, X. Duan, Acc. Chem. Res. 48 (2015) 1666-1675. doi: 10.1021/acs.accounts.5b00117
25. [25]
  K. Chen, S. Song, F. Liu, et al., Chem. Soc. Rev. 44 (2015) 6230-6257. doi: 10.1039/C5CS00147A
26. [26]
  J. Zhang, X. Liu, G. Neri, et al., Adv. Mater. 28 (2016) 795-831. doi: 10.1002/adma.201503825
27. [27]
  F. Perreault, A. Fonseca de Faria, M. Elimelech, Chem. Soc. Rev. 44 (2015) 5861-5896. doi: 10.1039/C5CS00021A
28. [28]
  W.J. Yuan, G.Q. Shi J. Mater. Chem. A 1 (2013) 10078-10091. doi: 10.1039/c3ta11774j
29. [29]
  S. Mao, S. Cui, G. Lu, et al., J. Mater. Chem. 22 (2012) 11009-11013. doi: 10.1039/c2jm30378g
30. [30]
  J. Kaur, K. Anand, N. Kohli, et al., Chem. Phys. Lett. 701 (2018) 115-125. doi: 10.1016/j.cplett.2018.04.049
31. [31]
  J. Yang, C. Yu, C. Hu, et al., Adv. Funct. Mater. 28 (2018) 1803272. doi: 10.1002/adfm.201803272
32. [32]
  S. Srivastava, K. Jain, V.N. Singh, et al., Nanotechnology 23 (2012) 205501. doi: 10.1088/0957-4484/23/20/205501
33. [33]
  J. Qin, M. Cao, N. Li, et al., J. Mater. Chem. 21 (2011) 17167-17174. doi: 10.1039/c1jm12692j
34. [34]
  W.S. Hummers, R.E. Offeman, J. Am. Chem. Soc. 80 (1958) 1339. doi: 10.1021/ja01539a017
35. [35]
  Y.H. Deng, T. Yu, Y. Wan, et al., J. Am. Chem. Soc. 129 (2007) 1690-1697. doi: 10.1021/ja067379v
36. [36]
  X. Yuxi, S. Kaixuan, L. Chun, et al., ACS Nano 4 (2010) 4324-4330. doi: 10.1021/nn101187z
37. [37]
  Z.M. Wang, W. Wendong, C. Neil, et al., ACS Nano 4 (2013) 7437-7450.
38. [38]
  C. Li, G. Shi, Adv. Mater. 26 (2014) 3992-4012. doi: 10.1002/adma.201306104
39. [39]
  B.A. De Angelis, M. Schiavello, J. Solid State Chem. 21 (1977) 67-72. doi: 10.1016/0022-4596(77)90145-1
40. [40]
  S.C. Moulzolf, S.A. Ding, R.J. Lad, Sens. Actuators B:Chem. 77 (2001) 375-382. doi: 10.1016/S0925-4005(01)00757-2
41. [41]
  W. Zhu, F. Sun, R. Goei, et al., Appl. Catal. B:Environ. 207 (2017) 93-102. doi: 10.1016/j.apcatb.2017.02.012
42. [42]
  A. Lewera, L. Timperman, A. Roguska, et al., J. Phys. Chem. C 115 (2011) 20153-20159. doi: 10.1021/jp2068446
43. [43]
  H. Aono, E. Traversa, M. Sakamoto, et al., Sens. Actuators B:Chem. 94 (2003) 132-139. doi: 10.1016/S0925-4005(03)00328-9
44. [44]
  S. Stankovich, D.A. Dikin, R.D. Piner, et al., Carbon 45 (2007) 1558-1565. doi: 10.1016/j.carbon.2007.02.034
45. [45]
  Q. Feng, X. Li, J. Wang, Sens. Actuators B:Chem. 243 (2017) 1115-1126. doi: 10.1016/j.snb.2016.12.075
46. [46]
  Y. Zhang, J. Xu, Q. Xiang, et al., J. Phys. Chem. C 113 (2009) 3430-3435. doi: 10.1021/jp8092258
47. [47]
  J. Zhang, H. Lu, C. Yan, et al., Sens. Actuators B:Chem. 264 (2018) 128-138. doi: 10.1016/j.snb.2018.02.026
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Facile synthesis of mesoporous WO3@graphene aerogel nanocomposites for low-temperature acetone sensing

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通讯作者: 陈斌, bchen63@163.com

Facile synthesis of mesoporous WO₃@graphene aerogel nanocomposites for low-temperature acetone sensing