Citation: Fan Siqi, Wang Yue, Li Zhuoshi, Zeng Zhuang, Guo Shaoxia, Huang Shouying, Ma Xinbin. Carbon layer-coated ordered mesoporous silica supported Co-based catalysts for higher alcohol synthesis: The role of carbon source[J]. Chinese Chemical Letters, ;2020, 31(2): 525-529. doi: 10.1016/j.cclet.2019.04.070 shu

Carbon layer-coated ordered mesoporous silica supported Co-based catalysts for higher alcohol synthesis: The role of carbon source

Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Centre of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

yuewang@tju.edu.cn

Received Date: 2 April 2019
Revised Date: 27 April 2019
Accepted Date: 29 April 2019
Available Online: 29 April 2019

Figures(3)

Surface chemical properties of supports have an important influence on active sites and their catalytic behavior. Here, we fabricated a series of cobalt-based catalysts supported by carbon layer-coated ordered mesoporous silica (OMS) composites for higher alcohol synthesis (HAS). The carbon layers were derived from different sources and uniformly coated on the porous surface of OMS. Combined with the characterization results of carbonized catalysts, it is demonstrated that the carbon layer-coated supports significantly enhanced the metal dispersion and increased the ratio of Co²⁺ to Co⁰ sites, which further increased the CO conversion and alcohols selectivity. Moreover, it is found that the catalytic activity changed in line with the amount of defects and surface oxygenic groups of carbon layers, which resulted from the different carbon sources. The highest space time yield of C₂₊OH was 27.5 mmol g_cat^-1 h^-1) obtained by the catalyst coated with glucose-derived carbon layer. But the carbon source is not the key factor influencing the distribution of Co-Co²⁺ dual sites and shows little effect on selectivity in HAS. These results may guide for further design of carbon supported catalysts.
- Syngas,
- Higher alcohols,
- Cobalt-based catalysts,
- Carbon layer-coated support,
- Carbon source
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