Citation: Liu Nan, Chen Peng-Zhong, Wang Jian-Xin, Niu Li-Ya, Yang Qing-Zheng. Difluoroboron β-diketonate dye with intense red/near-infrared fluorescence in solutions and solid states[J]. Chinese Chemical Letters, ;2019, 30(11): 1939-1941. doi: 10.1016/j.cclet.2019.04.058 shu

Difluoroboron β-diketonate dye with intense red/near-infrared fluorescence in solutions and solid states

Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China

niuly@bnu.edu.cn

Received Date: 26 March 2019
Revised Date: 9 April 2019
Accepted Date: 22 April 2019
Available Online: 23 November 2019

Figures(6)

Difluoroboron β-diketonate (BF₂bdk) complexes have attracted much attention due to their outstanding photophysical properties. However, BF₂bdk with near-infrared fluorescence usually suffer from emission quenching in solid state due to the π-π stacking in aggregation. Herein, we report a BF₂bdk dye exhibiting donor-acceptor (D-A) structure with the difluoroboron moiety acting as the electron acceptor and the aminonaphthalene as the electron donor. It processes intense molar extinction coefficient, large Stokes shift and strong fluorescence in red/NIR region in both solution and aggregations. It was used for NIR imaging in living cells.
- Difluoroboron β-diketonate,
- Near-infrared,
- Solid state emission,
- Bioimaging
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